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Mnenie [13.5K]
2 years ago
9

Which of the following conditions will ensure that a chemical reaction will definitely proceed in the forward direction, toward

products?a. ΔH>0b. ΔS>ΔH/Tc. ΔSsys>0d. ΔSsurr>ΔSsyse. ΔH<0
Chemistry
1 answer:
Grace [21]2 years ago
4 0

Answer:

When ΔS > ΔH/ T, then the reaction will proceed forward

Explanation:

  • The entity that determines the whether a reaction will occur on its own in the forward direction (Spontaneity or Feasibility) is Gibb's free energy.
  • Gibb's free energy is the energy available to do work. It is denoted as 'G'. It cannot be easily measured. The change (ΔG) can only be measured.  ΔG = ΔH - TΔS

when ΔG is positive, The reaction is not spontaneous (reaction will not occur on its own)

When ΔG is negative, The reaction is spontaneous (reaction will occur on its own)

When ΔG is zero, the reaction is in equilibrium

Option A and E are not correct. ΔH (Enthalpy) cannot determine spontaneity

Option C and D cannot alone determine spontaneity of reaction

For reaction to be spontaneous, TΔS > ΔH

Therefore, ΔS > ΔH/T

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2 I Think

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The graph is not given in the question, so, the required graph is attached below:

Answer:

According to the graph, the relationship between the density of the sugar solution and the concentration of the sugar solution is directly proportional to each other as they both are increasing exponentially.

The graph shows that, the density of sugar solution will increase with the increase in concentration of sugar in the solution.

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How many electrons are transferred in the given redox reaction?<br><br> Zn+2AgNO3⟶2Ag+Zn(NO3)2
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Answer:

2 electrons are transfered in this reaction.

Explanation:

Oxidation is a reaction where an atom, ion, or molecule loses electrons, while reduction corresponds to the electron gain of an atom, ion, or molecule.

In an oxidation-reduction reaction two simultaneous processes take place, oxidation and reduction.

So, oxidation-reduction (redox) reactions involve the transfer of electrons between chemical species. They are also called electron transfer reactions since the particle that is exchanged is the electron.

In this case:

Zn(s) ⇒ Zn²⁺(aq) + 2 e⁻

2 Ag⁺  (aq) + 2 e⁻ ⇒ 2 Ag(s)

So, zinc metal loses two electrons to form the zinc(II) ions, while the two silver ions each gain one  electron to form two silver metal atoms.

Then, Zn is a reducing agent (The reducing agent is the one that provides the electrons, oxidizing itself), AgNO3 is an oxidizing agent (The oxidizing agent is the one that traps the electrons, reducing itself).

Finally, you can see that <u><em>2 electrons are transfered in this reaction.</em></u>

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It takes energy to ionize any atom. It takes progressively more and more energy for each successive electron that is removed and
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Removal of Third Electron

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Sulfurous acid is a diprotic acid with the following acid-ionization constants: Ka1 = 1.4x10−2, Ka2 = 6.5x10−8 If you have a 1.0
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Answer:

pH = 7.1581

Explanation:

The equilibrium of NaHSO₃ with Na₂SO₃ is:

HSO₃⁻ ⇄ SO₃²⁻ + H⁺

<em>Where K of equilibrium is the Ka2: 6.5x10⁻⁸</em>

HSO₃⁺ reacts with NaOH, thus:

HSO₃⁻ + NaOH → SO₃²⁻ + H₂O + Na⁺

As the buffer is of 1.0L, initial moles of HSO₃⁻ and SO₃²⁻ are:

HSO₃⁻: 0.252 moles

SO₃²⁻: 0.139 moles

Based on the reaction of NaOH, moles added of NaOH are subtracting moles of HSO₃⁻ and producing SO₃²⁻. The moles added are:

0.0500L ₓ (1mol /L): 0.050 moles of NaOH.

Thus, final moles of both compounds are:

HSO₃⁻: 0.252 moles - 0.050 moles = 0.202 moles

SO₃²⁻: 0.139 moles + 0.050 moles = 0.189 moles

Using H-H equation for the HSO₃⁻ // SO₃²⁻ buffer:

pH = pka + log [SO₃²⁻] / [HSO₃⁻]

Where pKa is - log Ka = 7.187

Replacing:

pH = 7.187 + log [0.189] / [0.202]

<h3>pH = 7.1581</h3>

4 0
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