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Tcecarenko [31]
1 year ago
13

Suppose that a 1.0-L reaction vessel initially contains 1.0 mol of O3 and 1.0 mol of O2. What fraction of the O3 will have react

ed when the rate falls to one-half of its initial value?
Chemistry
1 answer:
NemiM [27]1 year ago
8 0

Answer:

Explanation:

given reaction

                        2O₃        ⇄      3O₂

 initial                1                      1

    final           1-x                   1+ 1.5x

rate of reaction = k  [ O₃ ]² / [ O₂ ]

initial rate = k . 1² / 1 = k

final rate = k (1-x )² / (1+ 1.5x) = k/2

(1-x )² / (1+ 1.5x) = 1/2

2x² - 5.5 x + 1 = 0

x = 0.196

So fraction of ozone reacted = .196

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Hydrochloric acid (75.0 mL of 0.250 M) is added to 225.0 mL of 0.0550 M Ba(OH)2 solution. What is the concentration of the exces
Shalnov [3]

Answer:  The concentration of excess [OH^-] in solution is 0.017 M.

Explanation:

1. Molarity=\frac{moles}{\text {Volume in L}}

moles of HCl=Molarity\times {\text {Volume in L}}=0.250\times 0.075=0.019moles

1 mole of HCl give = 1 mole of H^+

Thus 0.019 moles of HCl give = 0.019 mole of H^+

2. moles of Ba(OH)_2=Molarity\times {\text {Volume in L}}=0.0550\times 0.225=0.012moles

According to stoichiometry:

1 mole of Ba(OH)_2 gives = 2 moles of OH^-

Thus 0.012 moles of Ba(OH)_2 give = 2 \times 0.012=0.024 moles of OH^-

H^++OH^-\rightarrow H_2O

As 1 mole of H^+ neutralize 1 mole of OH^-

0.019 mole of H^+ will neutralize 0.019 mole of OH^-

Thus (0.024-0.019)= 0.005 moles of OH^- will be left.

[OH^-]=\frac{\text {moles left}}{\text {Total volume in L}}=\frac{0.005}{0.3L}=0.017M

Thus molarity of [OH^-] in solution is 0.017 M.

4 0
1 year ago
Read 2 more answers
A small portion of a crystal lattice is sketched below. What is the name of the unit cell of this lattice? Your answer must be a
Nikolay [14]

This is an incomplete question, the given sketch is shown below.

Answer : The name of given unit cell is, FCC (face-centered cubic unit cell)

Explanation :

Unit cell : It is defined as the smallest 3-dimensional portion of a complete space lattice which when repeated over the and again in different directions produces the complete space lattice.

There are three types of unit cell.

  • SCC (simple-centered cubic unit cell)
  • BCC (body-centered cubic unit cell)
  • FCC (face-centered cubic unit cell)

In SCC, the atoms are arranged at the corners.

Z=\frac{1}{8}\times 8=1

The number of atoms of unit cell = Z = 1

In BCC, the atoms are arranged at the corners and the body center.

Z=\frac{1}{8}\times 8+1=2

The number of atoms of unit cell = Z = 2

The given unit cell is, FCC because the atoms are arranged at the corners and the center of the 6 faces.

Z=\frac{1}{8}\times 8+\frac{1}{2}\times 6=4

The number of atoms of unit cell = Z = 4

Thus, the name of given unit cell is, FCC (face-centered cubic unit cell)

7 0
2 years ago
. Calculate the mass of O2 produced if 3.450 g potassium chlorate is completely decomposed by heating in presence of a catalyst
Vesnalui [34]
 <span>2 KClO3(s) → 3 O2(g) + 2 KCl(s) 

</span><span>Note: MnO2 (Manganese Dioxide) is not part of the reaction. A catalyst lowers the activation energy and increases both forward and reverse reactions at equal rates. 
</span>
molar mass of KClO3 = 122.5
Moles of KClO3 =  3.45 / 122.55 = 0.028

Moles of O2 produce = \frac{3}{2} \times 0.028

= 0.042 moles

molar mass of O2 = 32

so, mass of O2 = 32 x 0.042  = 1.35 g



5 0
1 year ago
A new student is planning to use thin layer chromatography (TLC) for his research project. After setting up the apparatus the st
tamaranim1 [39]

Answer:

The open system evaporates the solvent in the solution

Explanation:

An open system is a system in which exchange of materials and energy can occur. If a TLC set up is left open, then the set up constitutes an open system.

During TLC, the sample is dotted on the plate and inserted into a suitable solvent. The solvent moves up the plate and achieves the required separation of the mixture.

Most of these solvents used used TLC are volatile organic compounds. Therefore, if the TLC set up is left open, the solvent will evaporate leading to poor results after running the TLC experiment.

7 0
1 year ago
A sample of 8.5 g nh3 on oxidation produces 4.5 g of no. calculate the percent yield. reaction: 4 nh3 5 o2 → 4 no 6 h2o
AnnZ [28]
<span>30.% Determine the molar mass of NH3 and NO Atomic weight nitrogen = 14.0067 Atomic weight hydrogen = 1.00794 Atomic weight oxygen = 15.999 Molar mass NH3 = 14.0067 + 3 * 1.00794 = 17.03052 g/mol Molar mass NO = 14.0067 + 15.999 = 30.0057 g/mol Moles NH3 = 8.5 / 17.03052 = 0.499103962 mol Moles NO = 4.5 / 30.0057 = 0.149971505 mol Looking at the balanced equation, for every mole of NH3 consumed, you should get one mole of NO. So if we had 100% yield, we should have 0.499103962 moles of NO. But we don't. The percent yield is a simple matter of division by what we did get by what we should get. So 0.149971505 / 0.499103962 = 0.300481497 = 30.0481497% Rounding to 2 significant figures gives 30.% yield.</span>
5 0
2 years ago
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