Suppose that a 1.0-L reaction vessel initially contains 1.0 mol of O3 and 1.0 mol of O2. What fraction of the O3 will have react
1 answer:
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The structures of the isomers and the m/z values of their peaks are not given in the question. The complete question is provided in the attachment
Answer:
Compound 2 (2,5-dimethylhexane) will not have the peaks at 29 and 85 m/z
Explanation:
The fragmentation of molecules by electron ionization of mass spectrometer occurs according to Stevenson's Rule, which states that "The most probable fragmentation is the one that leaves the positive charge on the fragment with the lowest ionization energy". This is much like the Markovnikov's Rule in organic chemistry which has predicted the formation of most stable carbocation and the addition of hydrogen halide to it.
The mass spectra of compound 1 (2,4-dimethylhexane) will contain all the m/z values mentioned in the question. Each peak indicate towards homologous series of fragmentation product of the compound 1. The first peak can be attributed to ethyl carbocation (m/z = 29), with the increase of 14 units the next peak indicates towards propyl carbocation (m/z = 43) and onwards until molecular ion peak of 114 m/z.
Compound 2 (2,5-dimethylhexane) structure shows that the cleavage of C-C bond will not yield a stable ethyl and hexyl carbocation. Hence, no peaks will be observed at 29 and 85 m/z. The absence of these two peaks can be used to distinguish one isomer from the other.
The new volume at standard pressure of 1 atm is 21294 liters.
Explanation:
Data given:
Initial volume of the gas V1 = 338 liters
initial pressure on the gas P1 = 63 atm
standard pressure as P2 = 1 atm
Final volume at standard pressure V2 =?
The data given shows that Boyle's law equation is to used:
P1V1 = P2V2
rearranging the equation to calculate V2,
V2 =
Putting the values in the equation:
V2 =
= 21294 L
as the pressure on the gas is reduced to 1 atm the volume of the gas increased incredibly to 21294 litres.
Answer:
Explanation:
first write the equilibrium equaion ,
⇄
assuming degree of dissociation =1/10;
and initial concentraion of =c;
At equlibrium ;
concentration of
is very small so
can be neglected
and equation is;
=
composiion ;