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GaryK [48]
2 years ago
13

a) (1 point) Build anthracene, optimize its geometry and examine its structure. Describe its shape. b) (1 point) Measure the C-C

bond lengths in anthracene. How do the bond lengths compare to typical C−C or C=C bond distances? c) (1 point) Build N-maleimide, optimize the geometry and examine the structure. Is the molecule flat?
Chemistry
1 answer:
oksano4ka [1.4K]2 years ago
8 0

Answer:

a) The structure of anthracene is planar with all the pi electrons delocalized in the structure to maintain aromaticity.

b) The C-C bond length in anthracene is about 140 pm with all the bond lengths being similar to each other.

The standard C-C bond length is 154 pm while standard C=C bond is about 134 pm. Therefore the bond length in anthracene is smaller than standard C-C bond length and longer than standard C=C bond length. This can be explained from the fact that the C-C bonds in anthracene has be mixed characteristics of single and double bond because of the delocalization of pi electrons over the whole structure. As a result, they are neither fully single nor fully double bond in nature. Hence the observed bond lengths.

c) This molecule is not flat. The N-atom is sp3 hybridized here and the H-atom attached to N will remain out of plane.

Explanation:

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Magnesium reacts with iron(III) chloride to form magnesium chloride (which can be used in fireproofing wood and in disinfectants
svet-max [94.6K]

Answer:

154.0831 g

Explanation:

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Given: For Mg

Given mass = 41.0 g

Molar mass of Mg = 24.31 g/mol

Moles of Mg = 41.0 g / 24.31 g/mol = 1.6865 moles

Given: For FeCl_3

Given mass = 175 g

Molar mass of FeCl_3 = 162.2 g/mol

Moles of FeCl_3 = 175 g / 162.2 g/mol = 1.0789 moles

According to the given reaction:

3Mg_{(s)}+2FeCl_3_{(s)}\rightarrow 3MgCl_2_{(s)}+2Fe_{(s)}

3 moles of Mg react with 2 moles of FeCl_3

1 mole of Mg react with 2/3 moles of FeCl_3

1.6865 mole of Mg react with (2/3)*1.6865 moles of FeCl_3

Moles of FeCl_3 = 1.1243 moles

Available moles of FeCl_3 = 1.0789 moles

Limiting reagent is the one which is present in small amount. Thus, FeCl_3 is limiting reagent. (1.0789 < 1.1243)

The formation of the product is governed by the limiting reagent. So,

2 moles of FeCl_3 gives 3 moles of magnesium chloride

1 mole of FeCl_3 gives 3/2 moles of magnesium chloride

1.0789 mole of FeCl_3 gives (3/2)*1.0789 moles of magnesium chloride

Moles of magnesium chloride = 1.61835 moles

Molar mass of magnesium chloride = 95.21 g/mol

Mass of magnesium chloride = Moles × Molar mass = 1.61835 × 95.21 g = 154.0831 g

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The gaseous product of a reaction is collected in a 25.0-l container at 27
nataly862011 [7]
To find the number of moles of gas we can use the ideal gas law equation, we dont need to use the mass of gas given as we only have to find the number of moles 
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