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timofeeve [1]
2 years ago
6

Barbiturates, including "truth serums" seen in movies like Meet the Fockers and sedatives that may have led to the untimely deat

h of Jimi Hendrix, are often synthesized using what type of reaction sequence involving two consecutive enolate alkylations

Chemistry
1 answer:
Naya [18.7K]2 years ago
8 0

Answer:

Explanation:

Diethyl malonate is more acidic than monocarbonyl compounds (pKa=13) due to their alpha hydrogens being attached to two carbonyl groups. Thus, the <u>malonic ester is easily converted to its enolate ion by reaction with sodium ethoxide in ethanol</u>. The product of the alkylation of the malonic ester leaves a <u>hydrogen atom acid in an alpha position</u>, so the alkylation process can be repeated a second time to produce a dialkylated malonic ester.

In this case, when urea is treated with diethyl malonate in the presence of sodium ethoxide base,<u> the second alkylation step occurs intramolecularly</u> to generate a cyclic product, barbituric acid.

You might be interested in
At 10.°C, 20.g of oxygen gas exerts a pressure of 2.1atm in a rigid, 7.0L cylinder. Assuming ideal behavior, if the temperature
Alja [10]

Answer:

Final pressure = 2.3225 atm

Amontons’s law states that

At constant volume and number of molecules, the pressure of a given mass of gas is directly proportional to its temperature

Explanation:

Temperature causes increased excitement of gas molecules increasing the number of collisions with the walls of the container which is sensed as increase in pressure

Amontons’s law: P/T = Constant at constant V and n

That is P1/T1 = P2/T2

Where temperature is given in Kelvin

Hence T1 of 10°C = 273.15 + 10 = 283.15K

Also temperature T2 of 40°C = 313.15 K

Hence

P2 = (P1/T1)×T2 = (2.1/283.15)×313.15 = 2.3225 atm

3 0
2 years ago
What is the overall charge of the compound frbr
sammy [17]

Answer:

Zero  

Explanation:

FrBr is an ionic compound .

Fr is in Group 1. Br is in Group 17.

The charges on the ions are +1 and -1, respectively.

The compound consists of Fr⁺Br⁻ ions.

However, there are equal numbers of + and - charges, so

The overall charge of the compound is zero.

5 0
2 years ago
Cacodyl, which has an intolerable garlicky odor and is used in the manufacture of cacodylic acid, a cotton herbicide, has a mass
Papessa [141]

Answer:

The molecular formula of cacodyl is C₄H₁₂As₂.

Explanation:

<u>Let's assume we have 1 mol of cacodyl</u>, in that case we'd have 209.96 g of cacodyl and the<u> following masses of its components</u>:

  • 209.96 g * 22.88/100 = 48.04 g C
  • 209.96 g * 5.76/100 = 12.09 g H
  • 209.96 g * 71.36/100 = 149.83 g As

Now we convert those masses into moles:

  • 48.04 g C ÷ 12 g/mol = 4.00 mol C
  • 12.09 g H ÷ 1 g/mol = 12.09 mol H
  • 149.83 g As ÷ 74.92 g/mol = 2.00 mol As

Those amounts of moles represent the amount of each component in 1 mol of cacodyl, thus, the molecular formula of cacodyl is C₄H₁₂As₂.

3 0
1 year ago
Según la Organización Mundial de la Salud, el nitrato de plata ( densidad = 4.35 g/cc ) es una sustancia con propiedades cáustic
OlgaM077 [116]

Answer:

737.52 mL de agua

Explanation:

En este caso solo debes usar la expresión de molaridad de una solución la cual es:

M = moles / V

Donde:

V: Volumen de solución.

Como queremos saber la cantidad de agua, queremos saber en otras palabras cual es la cantidad de solvente que se utilizó para preparar los 800 mL de disolución.

Una disolución se prepara con un soluto y solvente. El soluto lo tenemos, que es el nitrato de plata. Con la expresión de arriba, calculamos los moles de soluto, y luego su masa. Posteriormente, calculamos el volumen con la densidad, y finalmente podremos calcular el solvente de esta forma:

V ste = Vsol - Vsto

Primero calcularemos los moles de soluto:

moles = M * V

moles = 2 * 0.800 = 1.6 moles

Con estos moles, se calcula la masa usando el peso molecular reportado que es 169.87 g/mol:

m = moles * PM

m = 1.6 * 169.87 = 271.792 g

Ahora usando el valor de la densidad, calcularemos el volumen de soluto empleado:

d = m/V

V = m/d

V = 271.792 / 4.35

V = 62.48 mL

Finalmente, la cantidad de agua necesaria es:

V agua = 800 - 62.48

V agua = 737.52 mL

8 0
2 years ago
a.) The diameter of a uranium atom is 3.50 Å . Express the radius of a uranium atom in both meters and nanometers. b.) How many
Svetradugi [14.3K]

Answer:

Th answer to your question is:

a)  3.5 x10⁻¹⁰ meters; 0.35 nm

b) 6857142.86 atoms

c) Volume = 2.06 x 10⁻²³ cm³

Explanation:

a) data

Uranium atoms = 3.5A°

meters

           1 A° ----------------  1 x 10 ⁻¹⁰ m

         3.5A° ---------------  x

 x = 3.5(1 x10⁻¹⁰)/ 1 = 3.5 x10⁻¹⁰ meters

          1 A° ------------------ 0.1 nm

        3.5 A° ---------------- 0.35 nm

b) 2.4 mm

Divide 2,40 mm / uranium diameter

But, first convert 3,5A° to mm   = 3.5 x 10⁻⁷ mm

# of uranium atoms = 2.4 / 3.5 x 10⁻⁷ = 6857142.86

c) volume in cubic cm

Convert 3.5A° to cm  = 3.5 x 10⁻⁸

Volume = 4/3 πr³ = (4/3) (3.14)(1.7 x10⁻⁸)³

Volume = 2.06 x 10⁻²³ cm³

6 0
2 years ago
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