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Phoenix [80]
2 years ago
15

Be sure to answer all parts. Which product(s) form(s) at each electrode in the aqueous electrolysis of the following salts? Sele

ct as many as apply. (a) FeI2 Cathode: Anode: I− (aq) I2 (s) Fe (s) Fe2+ (aq) I− (aq) I2 (s) Fe (s) Fe2+ (aq) (b) K3PO4 Cathode: Anode: O2 (g) H2 (g) H+ (aq) OH− (aq) O2 (g) H2 (g) H+ (aq) OH− (aq)
Chemistry
1 answer:
zlopas [31]2 years ago
4 0

Answer:

FeI2

Anode

Fe^2+

Cathode

I2

K3PO4

Anode

H^+ and K^+

Cathode

H2

Explanation:

In electrolysis, there are two electrodes present, the cathode and the anode. The anode is the positive electrode. This is where oxidation occurs and positive ions are formed. Species give up a electrons at the anode and the electrons travel towards the cathode.

At the cathode (negative electrode where reduction occurs), species accept electrons according to their position in the electrochemical series. In the case of K3PO4, both hydrogen and potassium ions arrive at the cathode but hydrogen in preferentially discharged due to the position of the two ions in the electrochemical series.

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Which of the compounds above are strong enough acids to react almost completely with a hydroxide ion (pka of h2o = 15.74) or wit
luda_lava [24]

The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Further explanation </em></h3>

In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)

Acids and bases according to Bronsted-Lowry

Acid = donor (donor) proton (H + ion)

Base = proton (receiver) acceptor (H + ion)

If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.

From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.

The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant

Can be formulated:

K acid-base reaction = Ka acid on the left : K acid on the right.

or:

pK = acid pKa on the left - pKa acid on the right

K = equilibrium constant for acid-base reactions

pK = -log K;

K~=~10^{-pK}

K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.

There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:

pyridinium pKa = 5.25

acetone pKa = 19.3

butan-2-one pKa = 19

Let's look at the K value of each possible reaction:

pka H₂O = 15.74, pka of H₂CO₃ = 6.37)

  • 1. C₅H₆N pyridinium

* with OH⁻

C₅H₆N + OH- ---> C₅H₅N- + H₂O

pK = pKa pyridinium - pKa H₂O

pK = 5.25 - 15.74

pK = -10.49

K~=~10^{4.9}

K values> 1 indicate the reaction can take place

* with HCO3⁻

C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃

pK = 5.25 - 6.37

pK = -1.12

K`=~10^{1.12]

Reaction can take place

  • 2. Acetone C₃H₆O

* with OH-

C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O

pK = 19.3 - 15.74

pK = 3.56

K~=~10^{ -3.56}

Reaction does not happen

* with HCO₃-

C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃

pK = 19.3 - 6.37

pK = 12.93

K`=~10 ^{-12.93}

Reaction does not happen

  • 3. butan-2-one C₄H₇O

* with OH-

C₄H₇O + OH- ---> C₄H₆O- + H₂O

pK = 19 - 15.74

pK = 3.26

K~=~10^{-3.26}

Reaction does not happen

* with HCO₃⁻

C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃

pK = 19 - 6.37

pK = 12.63

K~=~ 10^{-12.63}

Reaction does not happen

So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Learn more </em></h3>

the lowest ph

brainly.com/question/9875355

the concentrations at equilibrium.

brainly.com/question/8918040

the ph of a solution

brainly.com/question/9560687

Keywords : acid base reaction, the equilibrium constant

5 0
2 years ago
Read 2 more answers
What type of chemical reaction is this? Cl2(g) + 2KBr(aq) - 2KCl(aq) + Br2(l)
Sindrei [870]
C. Single-replacement

Chlorine replaces Bromine in KBr.
7 0
2 years ago
The ph of a solution that contains 0.818 m acetic acid (ka = 1.76 x 10-5) and 0.172 m sodium acetate is __________.
crimeas [40]
PH is calculated using <span>Handerson- Hasselbalch equation,

                                      pH  =  pKa  +  log [conjugate base] / [acid]

Conjugate Base  =  Acetate (CH</span>₃COO⁻)
Acid                    =  Acetic acid (CH₃COOH)
So,
                                      pH  =  pKa  +  log [acetate] / [acetic acid]

We are having conc. of acid and acetate but missing with pKa,
pKa is calculated as,

                                     pKa  =  -log Ka
Putting value of Ka,
                                     pKa  =  -log 1.76 × 10⁻⁵

                                     pKa  =  4.75
Now,
Putting all values in eq. 1,
                     
                                     pH  =  4.75 + log [0.172] / [0.818]

                                     pH  =  4.072
4 0
2 years ago
At this point Ron is slightly confused, this isn’t surprising. However, Hermione is doing rather well with them. This also isn’t
Zigmanuir [339]

Answer:

\boxed{\text{0.780 atm}}

Explanation:

Hermione is pretty smart. She realizes that, according to Dalton's Law of Partial Pressures, each gas exerts its pressure independently of the others, as if the others weren't even there.

She shows Ron how to use the Ideal Gas Law to solve the problem.

pV = nRT

She collects the data:

V = 1.00 L; n = 0.0319 mol; T = 25.0 °C

She reminds him to convert the temperature to kelvins

T = (25.0 +273.15) K = 298.15 K

Then she shows him how to do the calculation.

p \times \text{1.00 L} = \text{0.0319 mol} \times \text{L}\cdot\text{atm}\cdot\text{0.082 06 K}^{-1}\text{mol}^{-1} \times \text{298.15 K}\\\\1.00p = \text{0.7805 atm}\\\\p = \textbf{0.780 atm}\\\\\text{The partial pressure of the nitrogen is } \boxed{\textbf{0.780 atm}}

Isn't she smart?

4 0
2 years ago
Air is transferred from a 75 L tank where the pressure is 125 psi and the temperture is 288 k to a tire with a volume of 6.1 L a
aniked [119]
<h3><u>Answer</u>;</h3>

 = 4.68 K

<h3><u>Explanation</u>;</h3>

According to the combined gas law;

P1V1/T1 = P2V2/T2

Given; P1 = 125 Psi

V1 = 75 L

T1 = 288 K

P2 = 25 PSI

V2 =6.1 L

Therefore;

T2 = P2V2T1/P1V1

    = (25×6.1 ×288)/(125×75)

    = 4.6848

    = 4.68 K

4 0
2 years ago
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