Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.
The true statements in case Diels-Alder reaction are-
1. An excess of Maleic anhydride is used.
2. The I.R. of the products are indistinguishable.
The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.
There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.
Among the given statements the following statements are true-
1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.
2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).
The statements which are not true for the Diels-Alder reaction:
3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.
4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.
5. The reaction occurs at elevated temperature thus flame is required.
The solubility of NaCl in water at 100 C is 40%, meaning that we can dissolve 40 g NaCl in 100 g water. Assuming that dissolving NaCl does not add any volume to the solution, 600 mL of water is approximately equal to 600 g of water. By ratio and proportion: 40 g NaCl/100 g H2O = x g NaCl/600 g H2O
x = 240 g NaCl
So 240 g of NaCl must be dissolved to form a saturated solution.
The correct answer is Hot water increases the collision rate of molecules, causing the reaction to occur faster.
Explanation:
Temperature is directly related to the kinetic energy or movement of molecules in a substance. In this context, a higher temperature leads to more kinetic energy or more collision between molecules. At the same time, a chemical reaction involves molecules of two or more substances colliding and creating bonds to form new substances. This implies an increase in temperature means molecules colliding faster, new substances forming in a shorter time, and therefore a faster chemical reaction. According to this, the first answer is correct.
Answer:
Amount of Ca(NO3)2 produced = 14.02 g
Explanation:
The given reaction can be depicted as follows:
Ca(OH)2 + 2HNO3 → Ca(NO3)2 + 2H2O
Since it is given that HNO3 is in excess, the limiting reactant is Ca(OH)2
Now, Mass of Ca(OH)2 = 6.33 g
Molar mass of Ca(OH)2 = 74 g/mol
Based on the reaction stoichiometry:
1 mole of Ca(OH)2 forms 1 mole of Ca(NO3)2
Therefore, moles of Ca(NO3)2 produced from the moles of Ca(OH)2 reacted = 0.0855 moles
Molar mass of Ca(NO3)2 = 164 g/mol
Methyl Red, also called C.I. Acid Red 2, is an indicator dye that turns red in acidic solutions.
Phenolphthalein is a sensitive chemical with the formula C20H14O4 (often written as "HIn" in chemistry shorthand notation). Often used in titrations, it turns from colorless in acidic solutions to pink in basic solutions. If the concentration of indicator is particularly strong, it can appear purple. A phenolphtalein turns a bright orange color, in a solution containing a ph below 0.
