Answer;
The total pressure is 1.107 atm.
Explanation;
The total pressure is the sum of the pressures of the three gases in the flask
Pressure (total) = 0.215 atm + 0.066 atm + 0.826 atm = 1.107 atm
= 1.107 atm.
The answer to your question is a
The lower the pKa<span> of a Bronsted acid, the more easily it gives up its proton. The </span>higher<span> the </span>pKa<span> of a Bronsted acid, the more tightly the proton is held, and the less easily the proton is given up.
Here we need the highest pKa, so we need to see which compound will less likely to give proton or hydrogen ion.
</span><span>Now, all Nitrogen contains a lone pair. But HALOGEN groups( F, Cl, only) being electronegative than NITROGEN [electronegativity of N=3, F=4 and Cl=3], pulls electron pair towards itself.
</span>
The more the lone pair of nitrogen is pulled, the more strong bond between N and H will become, which means less likely to give hydrogen ion.
means high Pka
C) option is the answer because it has 3 F very close to N.
Boyle's law of ideal gas: This law states that the volume of a gas is inversely proportional to its pressure at a constant temperature. Acc to this law we can write the relation of pressure and volume as:

That means:

From that equation we can calculate Volume of gas at a certain pressure:
P₁=Initial pressure
V₁=Initial volume
P₂=Final pressure
V₂= Final volume
Here P₁, initial pressure is given as 85.0 kPa
V₁, initial volume is given as 525 mL
P₂, final pressure is 65.0 kPa

so,
V_{2}=85\times 525\div 65
=686 mL
Volume of gas will be 686 mL.
Explanation:
It is known that efficiency is denoted by
.
The given data is as follows.
= 0.82,
= (21 + 273) K = 294 K
= 200 kPa,
= 1000 kPa
Therefore, calculate the final temperature as follows.
0.82 =
= 1633 K
Final temperature in degree celsius =
= 
Now, we will calculate the entropy as follows.

For 1 mole, 
It is known that for
the value of
= 0.028 kJ/mol.
Therefore, putting the given values into the above formula as follows.

= 
= 0.0346 kJ/mol
or, = 34.6 J/mol (as 1 kJ = 1000 J)
Therefore, entropy change of ammonia is 34.6 J/mol.