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bagirrra123 [75]
1 year ago
6

Which of the following compounds has the highest pKa value? A)CCl3CH2NH2

Chemistry
1 answer:
Rudik [331]1 year ago
3 0
The lower the pKa<span> of a Bronsted acid, the more easily it gives up its proton. The </span>higher<span> the </span>pKa<span> of a Bronsted acid, the more tightly the proton is held, and the less easily the proton is given up.

Here we need the highest pKa, so we need to see which compound  will less likely to give proton or hydrogen ion.

</span><span>Now, all Nitrogen contains a lone pair. But HALOGEN groups( F, Cl, only) being electronegative than NITROGEN [electronegativity of N=3, F=4 and Cl=3], pulls electron pair towards itself. 
</span>
The more the lone pair of nitrogen is pulled, the more strong bond between N and H will become, which means less likely to give hydrogen ion.
means high Pka

C) option is the answer because it has 3 F very close to N.
You might be interested in
How many liters of gas will be in the closed reaction flask when 36.0L of ethane (C2H6) is allowed to react with 105.0L of oxyge
Ivan

Answer:- Volume of the gas in the flask after the reaction is 156.0 L.

Solution:-  The balanced equation for the combustion of ethane is:

2C_2H_6(g)+7O_2(g)\rightarrow 4CO_2(g)+6H_2O(g)

From the balanced equation, ethane and oxygen react in 2:7 mol ratio or 2:7 volume ratio as we are assuming ideal behavior.

Let's see if any one of them is limiting by calculating the required volume of one for the other. Let's say we calculate required volume of oxygen for given 36.0 L of ethane as:

36.0LC_2H_6(\frac{7LO_2}{2LC_2H_6})

= 126 L O_2

126 L of oxygen are required to react completely with 36.0 L of ethane but only 105.0 L of oxygen are available, It means oxygen is limiting reactant.

let's calculate the volumes of each product gas formed for 105.0 L of oxygen as:

105.0LO_2(\frac{4LCO_2}{7L O_2})

= 60.0 L CO_2

Similarly, let's calculate the volume of water vapors formed:

105.0L O_2(\frac{6L H_2O}{7L O_2})

= 90.0 L H_2O

Since ethane is present in excess, the remaining volume of it would also be present in the flask.

Let's first calculate how many liters of it were used to react with 105.0 L of oxygen and then subtract them from given volume of ethane to know it's remaining volume:

105.0LO_2(\frac{2LC_2H_6}{7LO_2})

= 30.0 L C_2H_6

Excess volume of ethane = 36.0 L - 30.0 L = 6.0 L

Total volume of gas in the flask after reaction = 6.0 L + 60.0 L + 90.0 L = 156.0 L

Hence. the answer is 156.0 L.

5 0
1 year ago
A certain radioactive atom has 90 protons and 142 neutrons. If this atom undergoes alpha decay, what is the mass number of the d
Hatshy [7]

Answer: the mass number of the daugther atom is 232,


Explanation:


1) Alpha (α) decay is a nuclear reaction in which a nucleus (parent's nucleus) emits an alpha (α) particle and leads to a different atom (daughter atom).


2) The alpha (α) particle is a nucleus of helium atom, i,e, a nucleus with two protons and two neutrons. The symbol used for the α particles is <em>⁴₂He</em>, where the superscript 4 indicates the mass number (2 protons + 2 neutrons = mass number 4), and the subscript 2 indicates the atomic number (number of protons).


3) Then, to determine the mass number of the daughter atom you just need to do a mass number balance:


mass number of the parent atom = mass number of the daugther atom + mass number of the α particle.


The mass number of the radioactive (parent) atom is 90 protons + 142 neutrons = 232.


∴ 232 = x + 4 ⇒ x = 232 - 4 = 228 ← answer.


The full equation may help you to have a wider vision of the problem:


²³²₉₀ X → ⁴₂ He + ²²⁸₈₈ Y

Note this:

  • 232 = 4 + 228 (this is a mass number balance)
  • 90 = 2 + 88 (this is an atomic number balance)
  • X is the parent atom, and Y is the daughter atom
  • You can use a periodic table to determine the identity of the unknown atoms (using the atomic numbers).
5 0
2 years ago
Read 2 more answers
A sodium atom has an electron configuration of 1s22s22p63s1.if the sodium atom becomes ionized, its new electron configuration w
dezoksy [38]

Answer:

Neon

Explanation:

1s² 2s² 2p⁶ 3s¹ or [Ne]  3s¹

The outer most shell is the 3s¹.

For this atom to achieve stability, if it loses the electron in the 3s shell, it would resemble an inert element with a complete octet configuration. Therefore, the atom would be like:

                   1s² 2s² 2p⁶ which is the configuration of Ne

8 0
2 years ago
After swimming in the pool on a very hot day, Sarah had a glass of ice water. Over time, the water on her skin evaporated, and t
Art [367]

I am sure the answer is A

7 0
1 year ago
Read 2 more answers
The Michaelis‑Menten equation models the hyperbolic relationship between [S] and the initial reaction rate V 0 V0 for an enzyme‑
ipn [44]

Answer:

The Michaelis‑Menten equation is given as

v₀ = Kcat X [E₀] X [S] / (Km + [S])

where,

Kcat is the experimental rate constant of the reaction; [s] is the substrate concentration and

Km is the Michaelis‑Menten constant.

Explanation:

See attached image for a detailed explanation

3 0
2 years ago
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