20. Which of the following statements regarding subshell filling order for a neutral atom is/are CORRECT? 1. Electrons are assig
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Here, the three different notation of the p-orbital in different sub-level have to generate
The value of azimuthal quantum number (l) for -p orbital is 1. We know that the magnetic quantum number depends upon the value of l, which are -l to +l.
Thus for p-orbital the possible magnetic quantum numbers are- -1, 0, +1. So there will be three orbitals for p orbitals, which are designated as ,
and
in space.
The three p-orbital can be distinguish by the quantum numbers as-
For 2p orbitals (principal quantum number is 2)
1) n = 2, l = 1, m = -1
2) n = 2, l = 1, m = 0
3) n = 2, l = 1, m = +1
Thus the notation of different p-orbitals in the sub level are determined.
Mass of water released =
×
= 33.45 g
The rate of Formation of Carbocation mainly depends on two factors'
1) Stability of Carbocation:
The ease of formation of Carbocation mainly depends upon the ionization of substrate. If the forming carbocation id tertiary then it is more stable and hence readily formed as compared to secondary and primary.
2) Ease of detaching of Leaving Group:
The more readily and easily the leaving group leaves the more readily the carbocation is formed and vice versa. In given scenario the carbocation formed is tertiary in all three cases, the difference comes in the leaving group. So, among these three substrates the one containing Iodo group will easily dissociate to form tertiary carbocation because due to its large size Iodine easily leaves the substrate, secondly Chlorine is a good leaving group compared to Fluoride. Hence the order of rate of formation of carbocation is,
R-I > R-Cl > R-F
B > C > A
1) Stability of Carbocation:
The ease of formation of Carbocation mainly depends upon the ionization of substrate. If the forming carbocation id tertiary then it is more stable and hence readily formed as compared to secondary and primary.
2) Ease of detaching of Leaving Group:
The more readily and easily the leaving group leaves the more readily the carbocation is formed and vice versa. In given scenario the carbocation formed is tertiary in all three cases, the difference comes in the leaving group. So, among these three substrates the one containing Iodo group will easily dissociate to form tertiary carbocation because due to its large size Iodine easily leaves the substrate, secondly Chlorine is a good leaving group compared to Fluoride. Hence the order of rate of formation of carbocation is,
R-I > R-Cl > R-F
B > C > A