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Katarina [22]
2 years ago
10

Biacetyl, the flavoring that makes margarine taste "just like butter," is extremely stable at room temperature, but at 200°C it

undergoes a first-order breakdown with a half-life of 9.0 min. An industrial flavor-enhancing process requires that a butter-flavored food be heated briefly at 200°C. How long can the food be heated at this temperature and retain 74% of its buttery flavor?
Chemistry
1 answer:
Sholpan [36]2 years ago
4 0

Answer:

3.91 minutes

Explanation:

Given that:

Biacetyl breakdown with a half life of 9.0 min after undergoing first-order reaction;

As we known that the half-life for first order is:

t__{1/2}}= \frac{0.693}{k}

where;

k = constant

The formula can be re-written as:

k = \frac{0.693}{t__{1/2}}

k = \frac{0.693}{9.0 min}

k = 0.077 min^{-1}

Let the initial amount of butter flavor in the food be (N_0) = 100%

Also, the amount of butter flavor retained at 200°C (N_t)= 74%

The rate constant k = 0.077 min^{-1}

To determine how long can the food be heated at this temperature and retain 74% of its buttery flavor; we use the formula:

\frac{N_t}{N_0}= -kt

t = - (\frac{1}{k}*In\frac{N_t}{N_0}  )

Substituting our values; we have:

t = - (\frac{1}{0.077}*In\frac{74}{100}  )

t = 3.91 minutes

∵ The time needed for the food to be heated at this temperature and retain 74% of its buttery flavor is 3.91 minutes

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<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}     .....(1)

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Given mass of hydrogen gas = 10.0 g

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Putting values in equation 1, we get:

\text{Moles of hydrogen gas}=\frac{10.0g}{2g/mol}=5mol

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Given mass of nitrogen gas = 80.0 g

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3 moles of hydrogen gas reacts with 1 mole of nitrogen gas

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As, given amount of nitrogen gas is more than the required amount. So, it is considered as an excess reagent.

Thus, hydrogen gas is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

3 moles of hydrogen gas produces 1 mole of ammonia

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Molar mass of ammonia = 17 g/mol

Moles of ammonia = 1.66 moles

Putting values in equation 1, we get:

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