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insens350 [35]
2 years ago
7

Why does 4.03/0.0000035 = 1.2 x 106, instead of a different number of significant figures?

Chemistry
1 answer:
jasenka [17]2 years ago
4 0

Explanations:- As per the significant figures rule, In multiplication and division, we go with least number of sig figs.

4.03 has three sig figs where as 0.0000035 has two sig figs only, The zeros in this number are not sig figs as they are just holding the place values. As the least number of sig figs here is two, the answer needs to be reported with two sig figs only.

\frac{4.03}{0.0000035}=1.2*10^6



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Which two solutions, when mixed together, will undergo a double replacement reaction and form a white, solid substance
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Which two solutions, when mixed together, will undergo a double replacement reaction and form a white, solid substance?


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2 is the answer because AgCl is formed and that is a white ppt.

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If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th
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Answer:

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be  the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

 [Pb²⁺] =   s

Then [I⁻] = 2s

K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} =  4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of  }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

B)

The Concentration of Pb²⁺  in water is calculated as :

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}

\mathbf{s} =\sqrt[3]{1.75*10^{-9}}

\mathbf{s} =\mathbf{1.21*10^{-3}  \ mol/L }

The Concentration of Pb²⁺  in 1.0 mol·L⁻¹ NaI

\mathbf{PbCl{_2}}  \leftrightharpoons    \ \ \ \ \ \ \  \mathbf{Pb^{2+}}   \ \ \ \  \ +   \ \  \ \ \ \ \ \mathbf{2 I^-}

                             \ \ \ \ \ \ \  \ \   \ \  \ \ \ \ \ \ \  \mathbf0}   \ \ \ \  \ \ \ \ \ \   \ \ \ \ \ \mathbf{1.0}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{+2x}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{1.0+2x}

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K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \  m/L

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the  common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

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A chemist combined chloroform (CHCl3) and acetone (C3H6O) to create a solution where the mole fraction of chloroform is 0.187. T
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Answer:

\large \boxed{\text{c = 2.50 mol/L; b = 3.96 mol/kg }}

Explanation:

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Let's call chloroform C and acetone A.

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Assume 0.187 mol of C.

That takes care of that.

(b) Litres of solution

Then we have 0.813 mol of A.

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\text{Mass of C} = \text{0.187 mol C} \times \dfrac{\text{119.38 g C}}{\text{1 mol C}} = \text{22.32 g C}\\\\\text{Mass of A} = \text{0.813 mol A} \times \dfrac{\text{58.08 g A}}{\text{1 mol A}} = \text{47.22 g A}

(ii) Volume of each component

\text{Vol. of C} = \text{22.32 g C} \times \dfrac{\text{1 mL C}}{\text{1.48 g C}} = \text{15.08 mL C}\\\\\text{Vol. of A} = \text{47.22 g A} \times \dfrac{\text{1 mL A}}{\text{0.791 g A}} = \text{59.70 mL A}

(iii) Volume of solution

If there is no change of volume on mixing.

V = 15.08 mL + 59.70 mL = 74.78 mL

(c) Molar concentration of C

c = \dfrac{\text{0.187 mol}}{\text{0.07478 L}} = \textbf{2.50 mol/L }\\\\\text{ The molar concentration of chloroform is $\large \boxed{\textbf{2.50 mol/L}}$}

2. Molal concentration of C

Molal concentration = moles of solute/kilograms of solvent

Moles of C = 0.187 mol

Mass of A = 47.22 g = 0.047 22 kg

\text{b} = \dfrac{\text{0.187 mol}}{\text{0.047 22 kg}} = \textbf{3.96 mol/kg }\\\\\text{The molal concentration of chloroform is $\large \boxed{\textbf{3.96 mol/kg}}$}

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Answer:

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