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Marysya12 [62]
2 years ago
6

A 52.8-g sample of glucose (a nondissociated, nonvolatile solute with the formula C6H12O6) is dissolved in 158.0 g of water. Wha

t is the vapor pressure of this solution at 100°C?
Chemistry
1 answer:
LUCKY_DIMON [66]2 years ago
7 0
Calculate  the  mole  of  glucose  and  water
 The  moles  of water =158g/18g/mol=8.778 moles
moles of  glucose =52.8g/180g/mol=0.293 moles
determine  the mole  fraction  of  the  solvent
that  is   x solvent = 8.778/ (8.778+0.293)=0.9677
use  the  Raults  law  to  determine  the  vapor  pressure
100  degree  of  water  has   a  vapor  pressure  of  760 mmhg
p solution=(x  solvent) (p^o solvent)
p solution=0.9677 x760 =735.45 mmHg

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Answer : The formal charge on the central nitrogen atom is, (+1)

Explanation :

Resonance structure : Resonance structure is an alternating method or way of drawing a Lewis-dot structure for a compound.

Resonance structure is defined as any of two or more possible structures of the compound. These structures have the identical geometry but have different arrangements of the paired electrons. Thus, we can say that the resonating structure are just the way of representing the same molecule.

First we have to determine the Lewis-dot structure of CNO^-.

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In the Lewis-dot structure the valance electrons are shown by 'dot'.

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Formula for formal charge :

\text{Formal charge}=\text{Valence electrons}-\text{Non-bonding electrons}-\frac{\text{Bonding electrons}}{2}

For structure 1 :

\text{Formal charge on O}=6-6-\frac{2}{2}=-1

\text{Formal charge on C}=4-2-\frac{6}{2}=-1

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 2 :

\text{Formal charge on O}=6-4-\frac{4}{2}=0

\text{Formal charge on C}=4-4-\frac{4}{2}=-2

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 3 :

\text{Formal charge on O}=6-2-\frac{6}{2}=+1

\text{Formal charge on C}=4-6-\frac{2}{2}=-3

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

The best Lewis-dot structure is, structure 1.

Thus, the formal charge on the central nitrogen atom is, (+1)

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