Answer:
See explanation and image attached
Explanation:
This reaction is known as mercuric ion catalyzed hydration of alkynes.
The first step in the reaction is attack of the mercuric ion on the carbon-carbon triple bond, a bridged intermediate is formed. This bridged intermediate is attacked by water molecule to give an organomercury enol. This undergoes keto-enol tautomerism, proton transfer to the keto group yields an oxonium ion, loss of the mercuric ion now gives equilibrium keto and enol forms of the compound. The keto form is favoured over the enol form.
Answer : The pH of 0.289 M solution of lithium acetate at
is 9.1
Explanation :
First we have to calculate the value of
.
As we know that,

where,
= dissociation constant of an acid = 
= dissociation constant of a base = ?
= dissociation constant of water = 
Now put all the given values in the above expression, we get the dissociation constant of a base.


Now we have to calculate the concentration of hydroxide ion.
Formula used :
![[OH^-]=(K_b\times C)^{\frac{1}{2}}](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D%28K_b%5Ctimes%20C%29%5E%7B%5Cfrac%7B1%7D%7B2%7D%7D)
where,
C is the concentration of solution.
Now put all the given values in this formula, we get:
![[OH^-]=(5.5\times 10^{-10}\times 0.289)^{\frac{1}{2}}](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D%285.5%5Ctimes%2010%5E%7B-10%7D%5Ctimes%200.289%29%5E%7B%5Cfrac%7B1%7D%7B2%7D%7D)
![[OH^-]=1.3\times 10^{-5}M](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D1.3%5Ctimes%2010%5E%7B-5%7DM)
Now we have to calculate the pOH.
![pOH=-\log [OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%20%5BOH%5E-%5D)


Now we have to calculate the pH.

Therefore, the pH of 0.289 M solution of lithium acetate at
is 9.1
Mass of the gas m = 1.66
The calculated temperature T = 273 + 20 = 293
We have to calculate molar mass to determine the gas
Molar Mass = mRT / PV
M = (1.66 x 8.314 x 293) / (101.3 x 1000 x 0.001)
M = 4043.76 / 101.3 = 39.92 g/mol
So this gas has to be Argon Ar based on the molar mass.
Answer:
The half-life varies depending on the isotope.
Half-lives range from fractions of a second to billions of years.
The half-life of a particular isotope is constant.