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Scilla [17]
2 years ago
3

In Section 3.5, we applied the equations for a particle in a box to the TC electrons in butadiene. This simple model is called t

he free-electron model. Using the same argument, show that the length of hexatriene can be estimated to be 867 pm. Show that the first electronic transition is predicted to occur at 2.8 x 104 cm-1. (Remember that hexatriene has six TC electrons.)
Chemistry
1 answer:
Karolina [17]2 years ago
8 0

Answer: DeltaE = 2.83 * 10^4 cm^-1

Explanation:

hexatriene has six TC (pi) electrons

3 C = C BONDS : 3 * 135 = 405 pm

2 C - C  BONDS : 2 * 154 = 308 pm

also the TWO CARBON ATOMIC RADIUS AT EACH END : 2 * 44 = 154 pm

therefore length of molecule = 405pm + 308pm + 154pm = 867 pm

now

HoMo = E4 and CoMo = E3

DeltaE = E4 - E3 = (4^2h^2 / 8mL^2) - (3^2h^2 / 8mL^2)

DeltaE = 7h^2 / 8mL^2

DeltaE = 7 * (6.62 *10^-35 Js)^2 / ( 8 * 9.1*10^-31 kg * (867*10-12m)^2)

DeltaE = 5.62 * 10^-19 J

( 1J = 5.034 * 10^22 cm^-1)

therefore

DeltaE = 2.83 * 10^4 cm^-1

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OleMash [197]

Answer:- 0.138 M

Solution:- The buffer pH is calculated using Handerson equation:

pH=pKa+log(\frac{base}{acid})

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The acid hase two protons(hydrogen) where as the base has only one proton. So, we could write the equation as:

H_2PO_4^-\rightleftharpoons H^++HPO_4^-^2

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Let's plug in the values in the equation:

7.00=6.86+log(\frac{base}{0.10})

7.00-6.86=log(\frac{base}{0.10})

0.14=log(\frac{base}{0.10})

Taking antilog:

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1.38=\frac{base}{0.10}

On cross multiply:

[base] = 1.38(0.10)

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5 0
2 years ago
How many hydrogen atoms are in 11C2H6
tresset_1 [31]

Answer:

6

Explanation:

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5 0
2 years ago
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svp [43]

Answer:

Ar < Cl - < S2-

Explanation:

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2 years ago
How many grams of (nh4)3po4 are needed to make 0.250 l of 0.150 m (nh4)3po4? hints how many grams of (nh4)3po4 are needed to mak
NeX [460]
<span>There are a number of ways to express concentration of a solution. This includes molarity. Molarity is expressed as the number of moles of solute per volume of the solution. We calculate the mass of the solute by first determining the number of moles needed. And by using the molar mass, we can convert it to units of mass.

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2 years ago
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