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Alexus [3.1K]
1 year ago
14

A branched alkane has ________ boiling point relative to the isomeric linear alkane. there are ________ london force interaction

s in the branched alkane
Chemistry
1 answer:
olya-2409 [2.1K]1 year ago
4 0
A branched alkane has HIGHER boiling point relative to the isomeric linear alkane. There are STRONGER london force interactions in the branched alkane.

:-) ;-)
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For the reaction 2N2O5(g) <---> 4NO2(g) + O2(g), the following data were colected:
KonstantinChe [14]

Answer:

a) The reaction is first order, that is, order 1. Option C is correct.

b) The half life of the reaction is 23 minutes. Option B is correct

c) The initial rate of production of NO2 for this reaction is approximately = (3.7 × 10⁻⁴) M/min. Option has been cut off.

Explanation:

First of, we try to obtain the order of the reaction from the data provided.

t (minutes) [N2O5] (mol/L)

0 1.24x10-2

10 0.92x10-2

20 0.68x10-2

30 0.50x10-2

40 0.37x10-2

50 0.28x10-2

70 0.15x10-2

Using a trial and error mode, we try to obtain the order of the reaction. But let's define some terms.

C₀ = Initial concentration of the reactant

C = concentration of the reactant at any time.

k = rate constant

t = time since the reaction started

T(1/2) = half life

We Start from the first guess of zero order.

For a zero order reaction, the general equation is

C₀ - C = kt

k = (C₀ - C)/t

If the reaction is indeed a zero order reaction, the value of k we will obtain will be the same all through the set of data provided.

C₀ = 0.0124 M

At t = 10 minutes, C = 0.0092 M

k = (0.0124 - 0.0092)/10 = 0.00032 M/min

At t = 20 minutes, C = 0.0068 M

k = (0.0124 - 0.0068)/20 = 0.00028 M/min

At t = 30 minutes, C = 0.0050 M

k = (0.0124 - 0.005)/30 = 0.00024 M/min

It's evident the value of k isn't the same for the first 3 trials, hence, the reaction isn't a zero order reaction.

We try first order next, for first order reaction

In (C₀/C) = kt

k = [In (C₀/C)]/t

C₀ = 0.0124 M

At t = 10 minutes, C = 0.0092 M

k = [In (0.0124/0.0092)]/10 = 0.0298 /min

At t = 20 minutes, C = 0.0068 M

k = 0.030 /min

At t = 30 minutes, C = 0.0050 M

k = 0.0303

At t = 40 minutes

k = 0.0302 /min

At t = 50 minutes,

k = 0.0298 /min

At t = 60 minutes,

k = 0.031 /min

This shows that the reaction is indeed first order because all the answers obtained hover around the same value.

The rate constant to be taken will be the average of them all.

Average k = 0.0302 /min.

b) The half life of a first order reaction is related to the rate constant through this relation

T(1/2) = (In 2)/k

T(1/2) = (In 2)/0.0302

T(1/2) = 22.95 minutes = 23 minutes.

c) The initial rate of production of the product at the start of the reaction

Rate = kC (first order)

At the start of the reaction C = C₀ = 0.0124M and k = 0.0302 /min

Rate = 0.0302 × 0.0124 = 0.000374 M/min = (3.74 × 10⁻⁴) M/min

3 0
1 year ago
What is the mass of 0.921 moles of sulfur dioxide gas (SO2)?
Serhud [2]

Answer:

mass = 58.944 g

Explanation:

Given data:

Number of moles of SO₂ = 0.921 mol

Mass of SO₂ = ?

Solution:

Formula:

Number of moles = mass/ molar mass

First of all we will calculate the molar mass.

SO₂ = 32 + 16×2 = 64 g/mol

Now we will put the values in formula.

Number of moles = mass/ molar mass

0.921 mol = mass /64 g/mol

mass = 0.921 mol × 64 g/mol

mass = 58.944 g

8 0
1 year ago
An unknown solid is entirely soluble in water. On addition of dilute HCl, a precipitate forms. After the precipitate is filtered
Karo-lina-s [1.5K]

Answer:

Pb(NO3)2

Cd(NO3)2

Na2SO4

Explanation:

In the first part, addition of HCl leads to the formation of PbCl2 which is poorly soluble in water. This is the first precipitate that is filtered off.

When the pH is adjusted to 1 and H2S is bubbled in, CdS is formed. This is the second precipitate that is filtered off.

After this precipitate has been filtered off and the pH is adjusted to 8, addition of H2S and (NH4)2HPO4 does not lead to the formation of any other precipitate.

The yellow flame colour indicates the presence of Na^+ which must come from the presence of Na2SO4.

5 0
1 year ago
The mass of radium-226 in a sample is found to have decreased from 45.00g to 5.625g in a period of 4800 years.From this informat
yan [13]

Answer:

Half life = 1600 years

Explanation:

Given data:

Total mass of sample = 45.00 g

Mass remain = 5.625 g

Time period = 4800 years

Half life of radium-226 = ?

Solution:

First of all we will calculate the number of half lives passes,

At time zero 45.00 g

At first half life = 45.00 g/ 2= 22.5 g

At 2nd half life = 22.5 g/ 2 = 11.25 g

At 3rd half life = 11.25 g/ 2= 5.625 g

Half life:

Half life = Time elapsed / number of half lives

Half life = 4800 years / 3

Half life = 1600 years

4 0
1 year ago
An object at 20∘C absorbs 25.0 J of heat. What is the change in entropy ΔS of the object? Express your answer numerically in jou
nevsk [136]

Question:

Part D) An object at 20∘C absorbs 25.0 J of heat. What is the change in entropy ΔS of the object? Express your answer numerically in joules per kelvin.

Part E) An object at 500 K dissipates 25.0 kJ of heat into the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin.

Part F) An object at 400 K absorbs 25.0 kJ of heat from the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin.

Part G) Two objects form a closed system. One object, which is at 400 K, absorbs 25.0 kJ of heat from the other object,which is at 500 K. What is the net change in entropy ΔSsys of the system? Assume that the temperatures of the objects do not change appreciably in the process. Express your answer numerically in joules per kelvin.

Answer:

D) 85 J/K

E) - 50 J/K

F) 62.5 J/K

G) 12.5 J/K

Explanation:

Let's make use of the entropy equation: ΔS = \frac{Q}{T}

Part D)

Given:

T = 20°C = 20 +273 = 293K

Q = 25.0 kJ

Entropy change will be:

ΔS = \frac{25*1000}{293}

= 85 J/K

Part E)

Given:

T = 500K

Q = -25.0 kJ

Entropy change will be:

ΔS = \frac{-25*1000}{500}

= - 50 J/K

Part F)

Given:

T = 400K

Q = 25.0 kJ

Entropy change will be:

ΔS = \frac{25*1000}{400}

= 62.5 J/K

Part G:

Given:

T1 = 400K

T2 = 500K

Q = 25.0 kJ

The net entropy change will be:

ΔS = (\frac{25*1000}{400}) + (\frac{-25*1000}{500}

= 12.5 J/K

7 0
1 year ago
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