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siniylev [52]
2 years ago
14

A 0.307-g sample of an unknown triprotic acid is titrated to the third equivalence point using 35.2 ml of 0.106 m naoh. calculat

e the molar mass of the acid. question 16 options:
Chemistry
1 answer:
Jet001 [13]2 years ago
6 0
Triprotic acid is a class of Arrhenius acids that are capable of donating three protons per molecule when dissociating in aqueous solutions.  So the chemical reaction as described in the question, at the third equivalence point, can be show as: H3R + 3NaOH ⇒ Na3R + 3H2O, where R is the counter ion of the triprotic acid. Therefore, the ratio between the reacted acid and base at the third equivalence point is 1:3. 
The moles of NaOH is 0.106M*0.0352L = 0.003731 mole.  So the moles of H3R is 0.003731mole/3=0.001244mole.
The molar mass of the acid can be calculated: 0.307g/0.001244mole=247 g/mol.
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In the best Lewis structure for the fulminate ion, CNO–, what is the formal charge on the central nitrogen atom?
Andrews [41]

Answer : The formal charge on the central nitrogen atom is, (+1)

Explanation :

Resonance structure : Resonance structure is an alternating method or way of drawing a Lewis-dot structure for a compound.

Resonance structure is defined as any of two or more possible structures of the compound. These structures have the identical geometry but have different arrangements of the paired electrons. Thus, we can say that the resonating structure are just the way of representing the same molecule.

First we have to determine the Lewis-dot structure of CNO^-.

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

The given molecule is, CNO^-

As we know that carbon has '4' valence electrons, nitrogen has '5' valence electrons and oxygen has '6' valence electrons.

Therefore, the total number of valence electrons in CNO^- = 4 + 5 + 6 + 1= 16

According to Lewis-dot structure, there are 8 number of bonding electrons and 8 number of non-bonding electrons.

Now we have to determine the formal charge for each atom.

Formula for formal charge :

\text{Formal charge}=\text{Valence electrons}-\text{Non-bonding electrons}-\frac{\text{Bonding electrons}}{2}

For structure 1 :

\text{Formal charge on O}=6-6-\frac{2}{2}=-1

\text{Formal charge on C}=4-2-\frac{6}{2}=-1

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 2 :

\text{Formal charge on O}=6-4-\frac{4}{2}=0

\text{Formal charge on C}=4-4-\frac{4}{2}=-2

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

For structure 3 :

\text{Formal charge on O}=6-2-\frac{6}{2}=+1

\text{Formal charge on C}=4-6-\frac{2}{2}=-3

\text{Formal charge on N}=5-0-\frac{8}{2}=+1

The best Lewis-dot structure is, structure 1.

Thus, the formal charge on the central nitrogen atom is, (+1)

3 0
2 years ago
0.15 gm of metallic oxide was dissolved in 100 ml of 0.1 N H2SO4 and 25.8 ml of 0.095N NaOH were used to neutralise the remainin
Mila [183]

Answer:

Explanation:

25.8 ml of .095 N NaOH is needed to neutralise the remaining acid

equivalent of NaOH used = 25.8 x .095 / 1000 = .002451 gm equivalent .

acid remaining = .002451 gm equivalent .

acid initially taken = 100 ml of .1 N  /  1000  = . 01 gm equivalent

acid reacted with metal = .01  -.002451 = .007549 gm equivalent

This must have reacted with same gram equivalent of metal oxide

.007549  gm equivalent = .15 gm of metal oxide

1 gm equivalent = 19.87 gm

equivalent weight of metal = 19.87 - equivalent weight of oxygen

= 19.87 - 8 = 11.87 .

1

7 0
2 years ago
Write a balanced equation for the reaction of nach3coo (also written as nac2h3o2) and hcl. express your answer as a chemical equ
sammy [17]
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4 0
2 years ago
Read 2 more answers
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ra1l [238]

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Explanation:

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- the oxidation state of selenium in SeO3 = Z (let unknown value be Z)

Hence, SeO3 = 0

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8 0
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strojnjashka [21]
SThe  missing   coefficient  for  the  skeleton   equation  below  is  as  follows

skeleton   equation

Cr(s)  +  Fe(No3)2(aq)  ------> Fe (s)   +  Cr(NO3)3  (aq)
the  missing  coefficient  are  is   as  follows

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This  is  obtained   by  making  sure  all  the   molecules  are  balanced  in  both  sides
8 0
2 years ago
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