
Nitrogen lone pair will act as a base,removing H+ from water leaving behind OH- ion.
Why ?
Because N is a better donor than O.
solution:
Weight of caffeine is W = 0.170 gm.
Volume of water is V= 10 ml
Volume of methylene chloride which extracted caffeine is v= 5ml
No of portions n=3
Distribution co-efficient= 4.6
Total amount of caffeine that can be unextracted is given by
![w_{n}=w\times[\frac{k_{Dx}v}{k_{Dx}v+v}]^n\\w_{3}=0.170[\frac{4.6\times10}{(4.6\times10+5)}]^3\\=0.170[\frac{46}{46+5}]^3\\=0.170[\frac{46}{51}]^3\\=0.170[\frac{97336}{132651}]\\=0.170\times0.734=0.125gms](https://tex.z-dn.net/?f=w_%7Bn%7D%3Dw%5Ctimes%5B%5Cfrac%7Bk_%7BDx%7Dv%7D%7Bk_%7BDx%7Dv%2Bv%7D%5D%5En%5C%5C%3C%2Fp%3E%3Cp%3Ew_%7B3%7D%3D0.170%5B%5Cfrac%7B4.6%5Ctimes10%7D%7B%284.6%5Ctimes10%2B5%29%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B46%2B5%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B51%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B97336%7D%7B132651%7D%5D%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5Ctimes0.734%3D0.125gms)
amount of caffeine un extracted is 0.125gms
amount of caffeine extracted=0.170-0.125
=0.045 gms
<span>People with protanopia are unable to sense any ‘red’ light, people with deuteranopia do not sense ‘green’ light and people with tritanopia cannot sense ‘blue’ light. If a person perceives the color green, then the yellow sensitive nerves must work somewhat effectively since green is a combination of yellow and blue. Red-sensitive nerves are most likely not responding properly for this person. The answer is C.</span>
Answer:
P1 = 2.5ATM
Explanation:
V1 = 28L
T1 = 45°C = (45 + 273.15)K = 318.15K
V2 = 34L
T2 = 35°C = (35 + 273.15)K = 308.15K
P1 = ?
P2 = 2ATM
applying combined gas equation,
P1V1 / T1 = P2V2 / T2
P1*V1*T2 = P2*V2*T1
Solving for P1
P1 = P2*V2*T1 / V1*T2
P1 = (2.0 * 34 * 318.15) / (28 * 308.15)
P1 = 21634.2 / 8628.2
P1 = 2.5ATM
The initial pressure was 2.5ATM
Answer is 74,844 calories