Answer: a. 79.6 s
b. 44.3 s
c. 191 s
Explanation:
Expression for rate law for first order kinetics is given by:
where,
k = rate constant
t = age of sample
a = let initial amount of the reactant
a - x = amount left after decay process
a) for completion of half life:
Half life is the amount of time taken by a radioactive material to decay to half of its original value.
b) for completion of 32% of reaction
c) for completion of 81 % of reaction
Answer:
(a) Constitutional Isomers
(b) Constitutional Isomers
Explanation:
Constitutional isomers are also known with the name Structural Isomers. These are the compounds which have same chemical formula but differ in arrangement of atoms i.e. structure.
Both the compounds <em>cis-1,3-dibromocyclohexane</em> and <em>trans-1,4-dibromocyclohexane</em> have the same chemical formula
but have different structure as shown in the image below.
In the second case the compounds <em>2,3-dimethylhexane</em> and <em>2,3,3-trimethylpentane</em>, both have same chemical formula
but have different structures which is shown in the image below.
Thus it is clear that in both the groups (a) and (b) the given compounds are Constitutional Isomers.
The Molecule of Sodium Formate along with Formal Charges (in blue) and lone pair electrons (in red) is attached below.
Sodium Formate is an ionic compound made up of a positive part (Sodium Ion) and a polyatomic anion (Formate).
Nomenclature:
In ionic compounds the positive part is named first. As sodium ion is the positive part hence, it is named first followed by the negative part i.e. formate.
Name of Formate:
Formate ion has been derived from formic acid ( the simplest carboxylic acid). When carboxylic acids looses the acidic proton of -COOH, they are converted into Carboxylate ions.
E.g.
HCOOH (formic acid) → HCOO⁻ (formate) + H⁺
H₃CCOOH (acetic acid) → H₃CCOO⁻ (acetate) + H⁺
Formal Charges:
Formal charges are calculated using following formula,
F.C = [# of Valence e⁻] - [e⁻ in lone pairs + 1/2 # of bonding electrons]
For Oxygen:
F.C = [6] - [6 + 2/2]
F.C = [6] - [6 + 1]
F.C = 6 - 7
F.C = -1
For Sodium:
F.C = [1] - [0 + 0/2]
F.C = [1] - [0]
F.C = 1 - 0
F.C = +1