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wolverine [178]
2 years ago
9

Consider the reaction: 2clf3(g) + 2nh3(g) → n2(g) + 6hf(g) + cl2(g) when calculating the δh°rxn, why is the δhf° for n2 not impo

rtant?
Chemistry
1 answer:
Leni [432]2 years ago
8 0

<span>Actually, the heat of reaction hrxn s calculated by taking the sum of the heats of formation of the products minus the sum of the heats of formation of the reactants. However, at heat of formations of pure elements at atmospheric conditions is zero, therefore the hf of N2 is not important since it is zero anyway.</span>

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A 25.0-g sample of ice at -6.5oC is removed from the freezer and allowed to warm until it melts. Given the data below, select al
alukav5142 [94]

Answer:

B, D

Explanation:

The strategy here is to realize that the ice will be taken from -6.5 ºC to OºC where it will melt.

Lets call q₁ the heat required to bring the ice to 0ºc, q₂ the heat required to bring the phase change from solid to liquid.

q₁ is calculated from the expression

q₁ = s x m x ΔT where m is the mass, s the specific heat of ice ( 2.09 J/gºC ) and ΔT  the change in temperature.

q₂ the fusion enthalpy change   is calculated from the expression:

q₂ = C x ΔT

where C is the specific heat for the phase change , in this case named AH  given in kJ/mol.

We are given all the data needed to calculate q₁, q₂ and qtotal ( q₁ + q₂ )

q₁ = 25.0 g x ( 2.09 J/gºC) x ( 0 - ( -6.5 ºC ) )

q₁ = 339.6 J = 0.339 kJ

q₂ = (25 g/ 18 g/mol) x 6.02 kJ/mol = 1.39 x 6.02 kJ = 8.36 kJ

qtotal = 0.339 kJ + 8.36 kJ = 8.70 kJ

with these calculations, we can now proceed to answer the question:

(a) False AH is theheat capacity for the melting.

(b) True as we determined above

(c) False we only have one phase change, from solid (ice) to liquid

(d) True as calculated above

(e) False as determined in our calculations

7 0
2 years ago
list down some examples of solutions that we need to prepare/make in the form of unsaturated and saturated solution​
Vladimir79 [104]

Answer:

1)Carbonated water is saturated with carbon, hence it gives off carbon through bubbles.

2)Adding sugar to water until it no longer dissolves creates a saturated solution.

3)Continuing to dissolve salt in water until it will no longer dissolve creates a saturated solution.

An unsaturated tea and sugar solution would be one into which you could add more sugar and have the sugar still dissolve

5 0
2 years ago
A researcher suspects that the pressure gauge on a 54.3-L gas cylinder containing nitric oxide is broken. An empty gas cylinder
mixer [17]

Answer:

Number of moles nitric acid in the cylinder is 400.539g/mol.

Explanation:

From the given,

Weight of empty gas cylinder W_{1}= 90.0 lb= 40823.3 gramsWeight of full cylinder[tex]W_{2} = 116.5 lb= 52843.511 gramsThe critical temperature = 287 KThe critical pressure 54.3 LMolar mass of nitric acid = [tex]M_{NO} = 30.01 g/mol

Number of moles nitric acid = n_{NO} =?

The mass of nitric acid in the cylinder = W_{NO}=W_{2}-W_{1}

=52843.511-40823.3 =12,020.2g

Number of moles of nitric acid =

\frac{Given\,mass}{Molar\,mass}=\frac{12,020.2}{30}=400.539g/mol

Therefore, number of moles nitric acid in the cylinder is 400.539g/mol.

3 0
2 years ago
The temperature on a distant, undiscovered planet is expressed in degrees B. For example, water boils at 180 ∘ B and freezes at
marin [14]

Answer:

40.3∘C

Explanation:

At planet B;

Water boils = 180∘C

Water freezes = 50∘C

In this planet the temperature difference = 180 - 50 = 130 compared to earth where the temperature difference is; 100 - 0 = 100

This means;

130 ∘C = 100 ∘C

x ∘C = 31 ∘C

x = 31 * 130 / 100

x = 40.3∘C

5 0
2 years ago
The pKs of succinic acid are 4.21 and 5.64. How many grams of monosodium succinate (FW = 140 g/mol) and disodium succinate (FW =
Varvara68 [4.7K]

Answer:

9.744g of monosodium succinate.

4.925g of disodium succinate.

Explanation:

To find pH of the buffer produced by the mixture of monosodium succinate-Disodium succinate is obtained from H-H equation:

pH = pKa + log ([Na₂Suc] / [NaHSuc])

As you want a pH of 5.28 and pKa is 5.64:

5.28 = 5.64 + log ([Na₂Suc] / [NaHSuc])

-0.36 = log ([Na₂Suc] / [NaHSuc])

0.4365 = ([Na₂Suc] / [NaHSuc]) <em>(1)</em>

<em />

As total concentration of the buffer is 100mM = 0.100M:

0.100M = [Na₂Suc] + [NaHSuc] <em>(2)</em>

Replacing (2) in (1):

0.4365 = (0.100M - [NaHSuc] / [NaHSuc])

0.4365 = (0.100M - [NaHSuc] / [NaHSuc])

0.4365 [NaHSuc] = 0.100M - [NaHSuc]

1.4365 [NaHSuc] = 0.100M

[NaHSuc] = 0.0696M

And:

[Na₂Suc] = 0.0304M

As volume of the buffer is 1L:

[NaHSuc] = 0.0696 moles

[Na₂Suc] = 0.0304 moles

Using molar mass of both substances:

Mass of monosodium succinate:

0.0696moles * (140g / 1mol) =<em> 9.744g of monosodium succinate.</em>

Mass of disodium succinate:

0.0304moles * (162g / 1mol) =<em> 4.925g of disodium succinate.</em>

<em></em>

5 0
2 years ago
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