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Marina CMI [18]
1 year ago
5

Based on the entries in the following table, which element is most commonly bonded to the acidic hydrogen? table some weak acids

in water at 25 ∘c

Chemistry
2 answers:
Studentka2010 [4]1 year ago
7 0
According to picture below, C₆H₅O⁻ is most commonly bonded to the acidic hydrogen, because it has smallest Ka (<span>the acid dissociation constant).
Chemical reaction: C</span>₆H₅OH(aq) ⇄ C₆H₅O⁻(aq) + H⁺(aq).
Ka = [C₆H₅O⁻] · [H⁺] / [C₆H₅OH]. 
Equolibrium concentration of hydrogen ions is very low in water solution of phenol.

saw5 [17]1 year ago
6 0

The Correct is C₆H₅O⁻ : It is the most commonly bonded to the acidic hydrogen , and O2 is the most element bonded to the acidic hydrogen.


The explanation:


According to the table below we can see that the Ka ( the acid dissociation constant) for the Phenol is the smallest one.


when the Ka expression for this chemical reaction:


C₆H₅OH(aq) ⇄ C₆H₅O⁻(aq) + H⁺(aq)


is


Ka = [C₆H₅O⁻] · [H⁺] / [C₆H₅OH]


So, the water solution of the phenol has a very low equilibrium concentration of H ions [H+] , So C₆H₅O⁻ is the element which most commonly bonded to the acidic hydrogen.

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Consider the formation of nitryl fluoride: 2NO2(g)+F2(g)⇌2NO2F(g) The reaction is first order in F2 and second order overall. Wh
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Answer:

Rate = k[NO_{2}][F_{2}]

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Fill in the blanks to complete each statement about the heating of earths surface. Earth takes in thermal energy from the sun in
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A box has a volume of 45m3 and is filled with air held at 25∘C and 3.65atm. What will be the pressure (in atmospheres) if the sa
Marina CMI [18]

Answer:

Given:

  • Initial pressure: 3.65\; \rm atm.
  • Volume was reduced from 45\; \rm m^{3} to 5.0\; \rm m^{3}.
  • Temperature was raised from 25\; ^\circ \rm C to 35\; ^\circ \rm C.

New pressure: approximately 3.4\times 10\; \rm atm (34\; \rm atm.) (Assuming that the gas is an ideal gas.)

Explanation:

Both the volume and the temperature of this gas has changed. Consider the two changes in two separate steps:

  • Reduce the volume of the gas from 45\; \rm m^{3} to 5.0\; \rm m^{3}. Calculate the new pressure, P_1.
  • Raise the temperature of the gas from 25\; ^\circ \rm C to 35\; ^\circ \rm C. Calculate the final pressure, P_2.

By Boyle's Law, the pressure of an ideal gas is inversely proportional to the volume of this gas (assuming constant temperature and that no gas particles escaped or was added.)

For this gas, V_0 = 45\; \rm m^{3} while V_1 = 5.0\; \rm m^{3}.

Let P_0 denote the pressure of this gas before the volume change (P_0 = 3.65\; \rm atm.) Let P_1 denote the pressure of this gas after the volume change (but before changing the temperature.) Apply Boyle's Law to find the ratio between P_1\! and P_0\!:

\displaystyle \frac{P_1}{P_0} = \frac{V_0}{V_1} = \frac{45\; \rm m^{3}}{5.0\; \rm m^{3}} = 9.0.

In other words, because the final volume is (1/9) of the initial volume, the final pressure is 9 times the initial pressure. Therefore:

\displaystyle P_1 = 9.0\times P_0 = 32.85\; \rm atm.

On the other hand, by Amonton's Law, the pressure of an ideal gas is directly proportional to the temperature (in degrees Kelvins) of this gas (assuming constant volume and that no gas particle escaped or was added.)

Convert the unit of the temperature of this gas to degrees Kelvins:

T_1 = (25 + 273.15)\; \rm K = 298.15\; \rm K.

T_2 = (35 + 273.15)\; \rm K = 308.15\; \rm K.

Let P_1 denote the pressure of this gas before this temperature change (P_1 = 32.85\; \rm atm.) Let P_2 denote the pressure of this gas after the temperature change. The volume of this gas is kept constant at V_2 = V_1 = 5.0\; \rm m^{3}.

Apply Amonton's Law to find the ratio between P_2 and P_1:

\displaystyle \frac{P_2}{P_1} = \frac{T_2}{T_1} = \frac{308.16\; \rm K}{298.15\; \rm K}.

Calculate P_2, the final pressure of this gas:

\begin{aligned} P_2 &= \frac{308.15\; \rm K}{298.15\; \rm K} \times P_1 \\ &= \frac{308.15\; \rm K}{298.15\; \rm K} \times 32.85\; \rm atm \approx 3.4 \times 10\; \rm atm\end{aligned}.

In other words, the pressure of this gas after the volume and the temperature changes would be approximately 3.4\times 10\; \rm atm.

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When the pH is adjusted to 1 and H2S is bubbled in, CdS is formed. This is the second precipitate that is filtered off.

After this precipitate has been filtered off and the pH is adjusted to 8, addition of H2S and (NH4)2HPO4 does not lead to the formation of any other precipitate.

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Use the thermodynamic data at 298 k below to determine the ksp for barium carbonate, baco3 at this temperature. substance: ba2+(
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Answer : the correct answer for ksp = 1.59 * 10⁻⁹

Following are the steps to calculate the ksp of reaction

BaCO₃ →Ba ²⁺ + CO₃²⁻ :

Step 1 : To find ΔG° of reaction :

ΔG° of reaction can be calculates by taking difference between ΔG° of products and reactants as :

ΔG° reaction =Sum of ΔG° ( products ) - Sum of Δ G° ( reactants ) .

Given : ΔG° for Ba²⁺ ( product )= -560.7 \frac{KJ}{Mol}

ΔG° for CO₃²⁻ (product ) =- 528.1 \frac{KJ}{Mol}

ΔG° BaCO₃ ( reactant) = –1139 \frac{KJ}{Mol}

Plugging value in formula :

ΔG° for reaction = ( ΔG° of Ba ²⁺ + ΔG° of CO₃²⁻ ) - (ΔG° of BaCO₃ )

⁻ = ( -560.7 \frac{KJ}{Mol} + 528.1 \frac{KJ}{Mol} ) - ( -1139 \frac{KJ}{Mol} )

= ( -1088.8 \frac{KJ}{Mol}) - (-1139 \frac{KJ}{Mol} )

= - 1088.8 \frac{KJ}{Mol} + 1139 \frac{KJ}{Mol}

ΔG° of reaction = 50.2 \frac{KJ}{Mol}

Step 2: To calculate ksp from ΔG° of reaction .

The relation between Ksp and ΔG° is given as :

ΔG° = -RT ln ksp

Where ΔG° = Gibb's Free energy R = gas constant T = Temperature

Ksp = Solubility constant product .

Given : ΔG° of reaction = 50.2 \frac{KJ}{Mol}

T = 298 K R = 8.314 \frac{J}{Mol * K}

Plugging values in formula

50.2 \frac{KJ}{mol}  =  -  8.314 \frac{J}{mol * K} * 298 K * ln  ksp

50.2 \frac{KJ}{mol}  =  - 2477.572 \frac{J}{mol} * ln K

((Converting 2477 \frac{J}{mol}  to \frac{KJ}{mol}

Since , 1 KJ = 1000 J So , 2477 \frac{J}{mol}  * \frac{1 KJ}{1000J}  = 2.477 \frac{KJ}{mol} ))

Dividing both side by - 2.477 \frac{KJ}{mol}

\frac{50.2\frac{KJ}{mol}}{-2.477 \frac{KJ}{mol}} = \frac{-2.477 \frac{KJ}{mol}}{-2.477 \frac{KJ}{mol}} * ln ksp

ln ksp = ln ksp = -20.27 \frac{KJ}{mol}

Removing ln :

ksp = 1. 59 * 10⁻⁹

8 0
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