Answer: The correct answer is "B" two bonding domains(or bonding pairs) or two non bonding domains(or lone pairs)
Explanation:
Molecular geometry/structure is a three dimensional shape of a molecule. It is basically an arrangement of atoms in a molecule.It is determined by the central atom, its surrounding atoms and electron pairs.According to VSEPR theory, there are 5 basic shapes of a molecule: linear, trigonal planar, tetrahedral, trigonal bipyramidal and octahedral.
A)Four bonding domains and zero non bonding domains: shape is tetrahedral and bond angle is 109.5°
B)Two bonding domains and two non bonding domains(lone pairs): shape is bent and bond angle is 104.5°
C)Three bonding domains and one non bonding domain: shape is trigonal pyramidal and bond angle is 107°
D)Two bonding domain and zero non bonding domain: shape is linear and bond angle is 107°
E)Two bonding domain and one non bonding domain: bent shape and bond angle is 120°
F)Three bonding domains and zero nonbonding domain: shape is trigonal planar and bond angle is 120°
Hence Two bonding domains and two non bonding domains have the smallest bond angle.
The chemical formula for the compound can be written as,
CxHyOz
where x is the number of C atoms, y is the number of H atoms, and z is the number of O atoms. The combustion reaction for this compound is,
CxHyOz + O2 --> CO2 + H2O
number of moles of C:
(0.7191 g)(1 mol CO2/44 g of CO2) = 0.0163 mol CO2
This signifies that 0.0163 mole of C and the mass of carbon in the compound,
(0.0163 mols C)(12 g C/ 1 mol C) = 0.196 g C
number of moles H:
(0.1472 g H2O)(1 mol H2O/18 g H2O) = 0.00818 mol H2O
This signifies that there are 0.01635 atoms of H in the compound.
mass of H in the compound = (0.01635 mols H)(1 g of H) = 0.01635 g H
Mass of oxygen in the compound,
0.3870 - (0.196 g C + 0.01635 g H) = 0.1746 g
Moles O in the compound = (0.1746 g O)(1 mol O/16 g O) = 0.0109 mols O
The formula of the compound is,
C0.0163H0.01635O0.0109
Dividing the numbers by the least number,
C3/2H3/2O
The empirical formula of the compound is therefore,
<em> C₃H₃O₂</em>
Answer is 74,844 calories
Answer:
(a) 0.22 mol Cl₂ and 15.4g Cl₂
(b) 2.89.10⁻³ mol O₂ and 0.092g O₂
(c) 8 mol NaNO₃ and 680g NaNO₃
(d) 1,666 mol CO₂ and 73,333 g CO₂
(e) 18.87 CuCO₃ and 2,330g CuCO₃
Explanation:
In most stoichiometry problems there are a few steps that we always need to follow.
- Step 1: Write the balanced equation
- Step 2: Establish the theoretical relationship between the kind of information we have and the one we are looking for. Those relationships can be found in the balanced equation.
- Step 3: Apply conversion factor/s to the data provided in the task based on the relationships we found in the previous step.
(a)
Step 1:
2 Na + Cl₂ ⇄ 2 NaCl
Step 2:
In the balanced equation there are 2 moles of Na, thus 2 x 23g = 46g of Na. <u>46g of Na react with 1 mol of Cl₂</u>. Since the molar mass of Cl₂ is 71g/mol, then <u>46g of Na react with 71g of Cl₂</u>.
Step 3:


(b)
Step 1:
HgO ⇄ Hg + 0.5 O₂
Step 2:
<u>216.5g of HgO</u> form <u>0.5 moles of O₂</u>. <u>216.5g of HgO</u> form <u>16g of O₂</u>.
Step 3:


(c)
Step 1:
NaNO₃ ⇄ NaNO₂ + 0.5 O₂
Step 2:
<u>16g of O₂</u> come from <u>1 mol of NaNO₃</u>. <u>16g of O₂</u> come from <u>85g of NaNO₃</u>.
Step 3:


(d)
Step 1:
C + O₂ ⇄ CO₂
Step 2:
<u>12 g of C</u> form <u>1 mol of CO₂</u>. <u>12 g of C</u> form <u>44g of CO₂</u>.
Step 3:

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(e)
Step 1:
CuCO₃ ⇄ CuO + CO₂
Step 2:
<u>79.5g of CuO</u> come from <u>1 mol of CuCO₃</u>. <u>79.5g of CuO</u> come from <u>123.5g of CuCO₃</u>.
Step 3:

Lets organise the data given in the question
[ClO₂] (m) [OH⁻] (m) initial rate (m/s)
<span>0.060 0.030 0.0248
</span><span> 0.020 0.030 0.00276
</span><span> 0.020 0.090 0.00828
rate equation as follows
rate = k [</span>ClO₂]ᵃ [OH⁻]ᵇ
where k - rate constant
we need to find order with respect to ClO₂ therefore lets take the 2 equations where OH⁻ is constant.
1) 0.00276 = k [0.020]ᵃ[0.030]ᵇ
2) 0.0248 = k [0.060]ᵃ[0.030]ᵇ
divide first equation from the second
0.0248/0.00276 = [0.060/0.020]ᵇ
8.99 = 3ᵇ
8.99 rounded off to 9
9 = 3ᵇ
b = 2
order with respect to ClO₂ is 2