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babymother [125]
1 year ago
11

Given that the rate constant is 4.0×10−4 m−1 s−1 at 25.0 ∘c and that the rate constant is 2.6×10−3 m−1 s−1 at 42.4 ∘c, what is t

he activation energy in kilojoules per mole? express your answer to three significant figures and include the appropriate units.
Chemistry
1 answer:
stepladder [879]1 year ago
4 0
So here's how you find the answer:

Given: (rate constants)

K₁ = 4.0 x 10⁻⁴ M⁻¹s⁻¹.
T₁ = 25.0 C = 293 K.
k₂ = 2.6 x10⁻³ M⁻¹s⁻¹.
T₂ = 42.4 C = 315.4 K.
R = 8,314 J/K·mol.

Use the equation:

ln(k₁/k₂) = Ea/R (1/T₂ - 1/T₁).

Transpose:

Ea = R·T₁·T₂ / (T₁ - T₂) · ln(k₁/k₂)

Substitute within the given transposed equation:

<span>Ea = 8,314 J/K·mol · 293 K · 315.4 K ÷ (293 K - 315.4 K) · ln (4.0 x 10⁻⁴ M⁻¹s⁻¹/ 2.6 x 10⁻³ M⁻¹s⁻¹).
</span>
Continuing the solution we get:

<span>Ea = 768315 J·K/mol ÷ (-22,4 K) * (-1.87)
</span>
The value of EA is:

<span>Ea = 64140.58 J/mol ÷ 1000 J/kJ = 64.140 kJ/mol.</span>


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Select the statement(s) that explain(s) the relationship between the arrangement of elements by size and first ionization energy
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c. A full s subshell is able to shield a newly filled p subshell from the nucleus, making the first electron in a p subshell easy to remove.

Explanation:

From the given options, a full s-sublevel is able to shield a newly filled p-subshell from the nucleus thereby making the first electron in a p-subshell easy to remove is correct.

What is ionization energy?

Ionization energy is a measure of the readiness of an atom to lose an electron.

First ionization energy is the energy required to remove the most loosely held electron in the gas phase.

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  • The larger an atom becomes the lesser the ionization energy needed to remove the first electron from its outermost shell.

Electron - electron repulsion occurs when two electrons in the same sub-level repels one another.

Shielding effect is the ability of the inner electrons to protect the outer electrons from the pull of the nuclear charge.

In option C, a s-subshell has a greater shielding effect than the p,d and f sub-shell in that order.

A newly introduced electron in the p-sublevel will be loosely held and easier to remove.

Learn more:

First ionization energy brainly.com/question/2153804

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8 0
2 years ago
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Daniel Harris has always enjoyed eating tuna fish. Unfortunately, a study of the mercury content of canned tuna in 2010 found th
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Hydrochloric acid (75.0 mL of 0.250 M) is added to 225.0 mL of 0.0550 M Ba(OH)2 solution. What is the concentration of the exces
Shalnov [3]

Answer:  The concentration of excess [OH^-] in solution is 0.017 M.

Explanation:

1. Molarity=\frac{moles}{\text {Volume in L}}

moles of HCl=Molarity\times {\text {Volume in L}}=0.250\times 0.075=0.019moles

1 mole of HCl give = 1 mole of H^+

Thus 0.019 moles of HCl give = 0.019 mole of H^+

2. moles of Ba(OH)_2=Molarity\times {\text {Volume in L}}=0.0550\times 0.225=0.012moles

According to stoichiometry:

1 mole of Ba(OH)_2 gives = 2 moles of OH^-

Thus 0.012 moles of Ba(OH)_2 give = 2 \times 0.012=0.024 moles of OH^-

H^++OH^-\rightarrow H_2O

As 1 mole of H^+ neutralize 1 mole of OH^-

0.019 mole of H^+ will neutralize 0.019 mole of OH^-

Thus (0.024-0.019)= 0.005 moles of OH^- will be left.

[OH^-]=\frac{\text {moles left}}{\text {Total volume in L}}=\frac{0.005}{0.3L}=0.017M

Thus molarity of [OH^-] in solution is 0.017 M.

4 0
1 year ago
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