the balanced chemical equation for the decomposition of H₂O₂ is as follows
2H₂O₂ ---> 2H₂O + O₂
stoichiometry of H₂O₂ to O₂ is 2:1
the number of moles of H₂O₂ decomposed is - 0.250 L x 3.00 mol/L = 0.75 mol
according to stoichiometry the number of O₂ moles is half the number of H₂O₂ moles decomposed
number of moles of O₂ - 0.75 mol / 2 = 0.375 mol
apply the ideal gas law equation to find the volume
PV = nRT
where P - standard pressure - 10⁵ Pa
V - volume
n - number of moles 0.375 mol
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - standard temperature - 273 K
substituting the values in the equation
10⁵ Pa x V = 0.375 mol x 8.314 Jmol⁻¹K⁻¹ x 273 K
V = 8.5 L
volume of O₂ gas is 8.5 L