In given data:
maximum absorption wavelength λ = 580 nm = 580 x 10⁻⁹ m
write the equation to find the crystal field splitting energy:
E = hC / λ
Here, E is the crystal field splitting energy, h = 6.63 x 10⁻³⁴ J.sec is Planck's constant and C = 3 x 10⁸ m/sec is speed of light.
substitute in the equation above:
E = (6.64 x 10⁻³⁴ x 3 x 10⁸) / (580 x 10⁻⁹) = 3.43 x 10⁻¹⁹J
This crystal field splitting energy is for 1 ion.
Number of atoms in one mole, NA = 6.023 x 10²³
to calculate the crystal field splitting energy for one mole:
E(total) = E x NA
= (3.43 x 10⁻¹⁹) x (6.023 x 10²³) = 206 kJ/ mole
<span>There
are a number of ways to express concentration of a solution. This includes
molarity. Molarity is expressed as the number of moles of solute per volume of
the solution. We calculate the mass of the solute by first determining the number of moles needed. And by using the molar mass, we can convert it to units of mass.
Moles </span>(nh4)3po4 = 0.250 L (0.150 M) = 0.0375 moles (nh4)3po4
Mass = 0.0375 mol (nh4)3po4 (149.0867 g / mol) = 5.59 g (nh4)3po4
Answer: The rate of disappearance of 
is 
Explanation:
The given chemical reaction is:
The rate of the reaction for disappearance of is given as:
![\text{Rate of disappearance of }NO_2=-\frac{\Delta [NO_2]}{\Delta t}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DNO_2%3D-%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B%5CDelta%20t%7D)
Or,
where,
= final concentration of = 0.00650 M
= initial concentration of = 0.0100 M
= final time = 100 minutes
= initial time = 0 minutes
Putting values in above equation, we get:
Hence, the rate of disappearance of is
Explanation:
When pH of the solution is 11.
![pH=-\log[H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5BH%5E%2B%5D)
![11=-\log[H^+]](https://tex.z-dn.net/?f=11%3D-%5Clog%5BH%5E%2B%5D)
![[H^+]=1\times 10^{-11} M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D1%5Ctimes%2010%5E%7B-11%7D%20M)
..(1)
At pH = 11, the concentration of 
ions is 
.
When the pH of the solution is 6.
![pH=-\log[H^+]'](https://tex.z-dn.net/?f=pH%3D-%5Clog%5BH%5E%2B%5D%27)
![6=-\log[H^+]'](https://tex.z-dn.net/?f=6%3D-%5Clog%5BH%5E%2B%5D%27)
![[H^+]'=1\times 10^{-6} M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%27%3D1%5Ctimes%2010%5E%7B-6%7D%20M)
..(2)
At pH = 6, the concentration of ions is 
.
On dividing (1) by (2).
![\frac{[H^+]}{[H^+]'}=\frac{1\times 10^{-11} M}{1\times 10^{-6}}=1\times 10^{-5}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BH%5E%2B%5D%7D%7B%5BH%5E%2B%5D%27%7D%3D%5Cfrac%7B1%5Ctimes%2010%5E%7B-11%7D%20M%7D%7B1%5Ctimes%2010%5E%7B-6%7D%7D%3D1%5Ctimes%2010%5E%7B-5%7D%20)
The ratio of hydrogen ions in solution of pH equal to 11 to the solution of pH equal to 6 is 
.
Difference between the ions at both pH:
This means that Hydrogen ions in a solution at pH = 7 has 
ions fewer than in a solution at a pH = 6
Hey there:
1 cm³ = 1 mL
D = m / V
7.25 = 12.9 / V
V = 12.9 / 7.25
V = 1.779 cm³
