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garik1379 [7]
2 years ago
15

Consider the following chemical reaction: CO (g) + 2H2(g) ↔ CH3OH(g) At equilibrium in a particular experiment, the concentratio

ns of CO and H2 were 0.15 M and0.36 M,respectively. What is the equilibrium concentration of CH3OH? The value of Keq for this reaction is 14.5 at the temperature of the experiment.
Chemistry
1 answer:
AlexFokin [52]2 years ago
6 0

Answer:

The equilibrium concentration of CH₃OH is 0.28 M

Explanation:

For the reaction: CO (g) + 2H₂(g) ↔ CH₃OH(g)

The equilibrium constant (Keq) is given for the following expresion:

Keq= \frac{(CH3OH)}{(CO) x (H2)^{2}} =14.5

Where (CH3OH), (CO) and (H2) are the molar concentrations of each product or reactant.

We have:

(CH3OH)= ?

(CO)= 0.15 M

(H2)= 0.36 M

So, we only have to replace the concentrations in the equilibrium constant expression to obtain the missing concentration we need:

14.5= \frac{(CH_{3}OH) }{(0.15 M) x (0.36 M) ^{2} }

14.5 x (0.15 M) x (0.36)^{2} = (CH₃OH)

0.2818 M = (CH₃OH)

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Answer:

a. electrophilic aromatic substitution

b. nucleophilic aromatic substitution

c. nucleophilic aromatic substitution

d. electrophilic aromatic substitution

e. nucleophilic aromatic substitution

f. electrophilic aromatic substitution

Explanation:

Electrophilic aromatic substitution is a type of chemical reaction where a hydrogen atom or a functional group that is attached to the aromatic ring is replaced by an electrophile. Electrophilic aromatic substitutions can be classified into five classes: 1-Halogenation: is the replacement of one or more hydrogen (H) atoms in an organic compound by a halogen such as, for example, bromine (bromination), chlorine (chlorination), etc; 2- Nitration: the replacement of H with a nitrate group (NO2); 3-Sulfonation: the replacement of H with a bisulfite (SO3H); 4-Friedel-CraftsAlkylation: the replacement of H with an alkyl group (R), and 5-Friedel-Crafts Acylation: the replacement of H with an acyl group (RCO). For example, the Benzene undergoes electrophilic substitution to produce a wide range of chemical compounds (chlorobenzene, nitrobenzene, benzene sulfonic acid, etc).

A nucleophilic aromatic substitution is a type of chemical reaction where an electron-rich nucleophile displaces a leaving group (for example, a halide on the aromatic ring). There are six types of nucleophilic substitution mechanisms: 1-the SNAr (addition-elimination) mechanism, whose name is due to the Hughes-Ingold symbol ''SN' and a unimolecular mechanism; 2-the SN1 reaction that produces diazonium salts 3-the benzyne mechanism that produce highly reactive species (including benzyne) derived from the aromatic ring by the replacement of two substituents; 4-the free radical SRN1 mechanism where a substituent on the aromatic ring is displaced by a nucleophile with the formation of intermediary free radical species; 5-the ANRORC (Addition of the Nucleophile, Ring Opening, and Ring Closure) mechanism, involved in reactions of metal amide nucleophiles and substituted pyrimidines; and 6-the Vicarious nucleophilic substitution, where a nucleophile displaces an H atom on the aromatic ring but without leaving groups (such as, for example, halogen substituents).

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Be sure to answer all parts. Draw the structure of a compound of molecular formula C4H8O that has a signal in its 13C NMR spectr
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Answer:

The possible structures are ketone and aldehyde.

Explanation:

Number of double bonds of the given compound is calculated using the below formula.

N_{db}=N_{c}+1-\frac{N_{H}+N_{Br}-N_{N}}{2}

N_{db}=Number of double bonds

N_{c} = Number of carbon atoms

N_{H} = Number of hydrogen atoms

N_{N} = Number of nitrogen atoms

The number of double bonds in the given formula - C_{4}H_{8}O

N_{db}= 4+1-\frac{8+0-0}{2}=1

The number of double bonds in the compound is one.

Therefore, probable structures is as follows.

(In attachment)

The structures I and III are ruled out from the probable structures because the signal in 13C-NMR appears at greater than 160 ppm.

alkene compounds I and II shows signal less than 140 ppm.

Hence, the probable structures III and IV are given as follows.

The carbonyl of structure I appear at 202 and ketone group of IV appears at 208 in 13C, which are greater than 160.

Hence, the molecular formula of the compound C_{4}H_{8}O having possible structure in which the signal appears at greater than 160 ppm are shown aw follows.

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When a 1.00 L sample of water from the surface of the Dead Sea (which is more than 400 meters below sea level and much saltier t
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Answer:

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Explanation:

Data obtained from the question include:

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Number of mole of MgCl2 =?

Number of mole = Mass /Molar Mass

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