Answer:
Here's what I get.
Explanation:
The frequency of a vibration depends on the strength of the bond (the force constant).
The stronger the bond, the more energy is needed for the vibration, so the frequency (f) and the wavenumber increase.
Acetophenone
Resonance interactions with the aromatic ring give the C=O bond in acetophenone a mix of single- and double-bond character, and the bond frequency = 1685 cm⁻¹.
p-Aminoacetophenone
The +R effect of the amino group increases the single-bond character of the C=O bond. The bond lengthens, so it becomes weaker.
The vibrational energy decreases, so wavenumber decreases to 1652 cm⁻¹.
p-Nitroacetophenone
The nitro group puts a partial positive charge on C-1. The -I effect withdraws electrons from the acetyl group.
As electron density moves toward C-1, the double bond character of the C=O group increases.
The bond length decreases, so the bond becomes stronger, and wavenumber increases to 1693 cm¹.
Answer:
a)If concentration of [Sucrose] is changed to 2.5 M than rate will be increased by the factor of 2.5.
b)If concentration of [Sucrose] is changed to 0.5 M than rate will be increased by the factor of 0.5.
c)If concentration of
is changed to 0.0001 M than rate will be increased by the factor of 0.01.
d) If concentration when [sucrose] and
both are changed to 0.1 M than rate will be increased by the factor of 1.
Explanation:
Sucrose +
fructose+ glucose
The rate law of the reaction is given as:
![R=k[H^+][sucrose]](https://tex.z-dn.net/?f=R%3Dk%5BH%5E%2B%5D%5Bsucrose%5D)
![[H^+]=0.01M](https://tex.z-dn.net/?f=%5BH%5E%2B%5D%3D0.01M)
[sucrose]= 1.0 M
..[1]
a)
The rate of the reaction when [Sucrose] is changed to 2.5 M = R'
..[2]
[2] ÷ [1]
![\frac{R'}{R}=\frac{[0.01 M][2.5 M]}{k[0.01M][1.0 M]}](https://tex.z-dn.net/?f=%5Cfrac%7BR%27%7D%7BR%7D%3D%5Cfrac%7B%5B0.01%20M%5D%5B2.5%20M%5D%7D%7Bk%5B0.01M%5D%5B1.0%20M%5D%7D)

If concentration of [Sucrose] is changed to 2.5 M than rate will be increased by the factor of 2.5.
b)
The rate of the reaction when [Sucrose] is changed to 0.5 M = R'
..[2]
[2] ÷ [1]
![\frac{R'}{R}=\frac{[0.01 M][0.5 M]}{k[0.01M][1.0 M]}](https://tex.z-dn.net/?f=%5Cfrac%7BR%27%7D%7BR%7D%3D%5Cfrac%7B%5B0.01%20M%5D%5B0.5%20M%5D%7D%7Bk%5B0.01M%5D%5B1.0%20M%5D%7D)

If concentration of [Sucrose] is changed to 0.5 M than rate will be increased by the factor of 0.5.
c)
The rate of the reaction when
is changed to 0.001 M = R'
..[2]
[2] ÷ [1]
![\frac{R'}{R}=\frac{[0.0001 M][1.0M]}{k[0.01M][1.0 M]}](https://tex.z-dn.net/?f=%5Cfrac%7BR%27%7D%7BR%7D%3D%5Cfrac%7B%5B0.0001%20M%5D%5B1.0M%5D%7D%7Bk%5B0.01M%5D%5B1.0%20M%5D%7D)

If concentration of
is changed to 0.0001 M than rate will be increased by the factor of 0.01.
d)
The rate of the reaction when [sucrose] and
both are changed to 0.1 M = R'
..[2]
[2] ÷ [1]
![\frac{R'}{R}=\frac{[0.1M][0.1M]}{k[0.01M][1.0 M]}](https://tex.z-dn.net/?f=%5Cfrac%7BR%27%7D%7BR%7D%3D%5Cfrac%7B%5B0.1M%5D%5B0.1M%5D%7D%7Bk%5B0.01M%5D%5B1.0%20M%5D%7D)

If concentration when [sucrose] and
both are changed to 0.1 M than rate will be increased by the factor of 1.
The red bottle would have the lowest frequency because red light has the longest wavelengths. The light passing through the violet would have the highest frequency because its wavelengths are the shortest.
As he began to teach inorganic chemistry, Mendeleev could not find a textbook that met his needs. Since he had already published a textbook on organic chemistry in 1861 that had been awarded the prestigious Demidov Prize, he set out to write another one. The result was Osnovy khimii (1868–71; The Principles of Chemistry), which became a classic, running through many editions and many translations. When Mendeleev began to compose the chapter on the halogen elements (chlorine and its analogs) at the end of the first volume, he compared the properties of this group of elements to those of the group of alkali metals such as sodium. Within these two groups of dissimilar elements, he discovered similarities in the progression of atomic weights, and he wondered if other groups of elements exhibited similar properties. After studying the alkaline earths, Mendeleev established that the order of atomic weights could be used not only to arrange the elements within each group but also to arrange the groups themselves. Thus, in his effort to make sense of the extensive knowledge that already existed of the chemical and physical properties of the chemical elements and their compounds, Mendeleev discovered the periodic law.