Answer:
b. 186 g
Explanation:
Step 1: Write the balanced equation.
4 NH₃(g) + 6 NO(g) → 5 N₂(g) + 6 H₂O(l)
Step 2: Calculate the moles corresponding to 145 g of N₂
The molar mass of nitrogen is 28.01 g/mol.

Step 3: Calculate the moles of NO required to produce 5.18 moles of N₂
The molar ratio of NO to N₂ is 6:5.

Step 4: Calculate the mass corresponding to 6.22 moles of NO
The molar mass of NO is 30.01 g/mol.

Answer : The correct option is, (a) paramagnetic with two unpaired electrons.
Explanation :
According to the molecular orbital theory, the general molecular orbital configuration will be,
![(\sigma_{1s}),(\sigma_{1s}^*),(\sigma_{2s}),(\sigma_{2s}^*),(\sigma_{2p_z}),[(\pi_{2p_x})=(\pi_{2p_y})],[(\pi_{2p_x}^*)=(\pi_{2p_y}^*)],(\sigma_{2p_z}^*)](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%2C%28%5Csigma_%7B1s%7D%5E%2A%29%2C%28%5Csigma_%7B2s%7D%29%2C%28%5Csigma_%7B2s%7D%5E%2A%29%2C%28%5Csigma_%7B2p_z%7D%29%2C%5B%28%5Cpi_%7B2p_x%7D%29%3D%28%5Cpi_%7B2p_y%7D%29%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29)
As there are 14 electrons present in the given configuration.
The molecular orbital configuration of molecule will be,
![(\sigma_{1s})^2,(\sigma_{1s}^*)^2,(\sigma_{2s})^2,(\sigma_{2s}^*)^2,(\sigma_{2p_z})^2,[(\pi_{2p_x})^1=(\pi_{2p_y})^1],[(\pi_{2p_x}^*)^0=(\pi_{2p_y}^*)^0],(\sigma_{2p_z}^*)^0](https://tex.z-dn.net/?f=%28%5Csigma_%7B1s%7D%29%5E2%2C%28%5Csigma_%7B1s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2s%7D%29%5E2%2C%28%5Csigma_%7B2s%7D%5E%2A%29%5E2%2C%28%5Csigma_%7B2p_z%7D%29%5E2%2C%5B%28%5Cpi_%7B2p_x%7D%29%5E1%3D%28%5Cpi_%7B2p_y%7D%29%5E1%5D%2C%5B%28%5Cpi_%7B2p_x%7D%5E%2A%29%5E0%3D%28%5Cpi_%7B2p_y%7D%5E%2A%29%5E0%5D%2C%28%5Csigma_%7B2p_z%7D%5E%2A%29%5E0)
The number of unpaired electron in the given configuration is, 2. So, this is paramagnetic. That means, more the number of unpaired electrons, more paramagnetic.
Hence, the correct option is, (a) paramagnetic with two unpaired electrons.
Hello!
To solve this problem we are going to use the
Henderson-Hasselbach equation and clear for the molar ratio. Keep in mind that we need the value for Acetic Acid's pKa, which can be found in tables and is
4,76:
![pH=pKa + log ( \frac{[CH_3COONa]}{[CH_3COOH]} )](https://tex.z-dn.net/?f=pH%3DpKa%20%2B%20log%20%28%20%5Cfrac%7B%5BCH_3COONa%5D%7D%7B%5BCH_3COOH%5D%7D%20%29%20)
![\frac{[CH_3COOH]}{[CH_3COONa}= 10^{(pH-pKa)^{-1}}=10^{(4-4,76)^{-1}}=5,75](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BCH_3COOH%5D%7D%7B%5BCH_3COONa%7D%3D%2010%5E%7B%28pH-pKa%29%5E%7B-1%7D%7D%3D10%5E%7B%284-4%2C76%29%5E%7B-1%7D%7D%3D5%2C75%20)
So, the mole ratio of CH₃COOH to CH₃COONa is
5,75Have a nice day!
A. N₂ (g) + 3 H₂ (g) --> 2 NH₃ (g)
B. The value for standard enthalpy of formation is empirical given that the reactants involved were pure elements. So, you can search this on the internet or in any textbook. The Hf for NH₃ is -46.0 kJ/mol.
C. C (s) + O₂ (g) --> CO₂ (g)
D. The Hf for CO₂ is <span>-393.5 kJ/mol
E. 4 Fe (s) + 3 O</span>₂ (g) --> 2 Fe₂O₃ (s)
F. The Hf for solid Fe₂O₃ is -826.0 kJ/mol.
G. C (s) + 2 H₂ (g) --> CH₄ (g)
H. The Hf for methane gas is -74.9 kJ/mol.