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Elis [28]
2 years ago
15

A 62.6-gram piece of heated limestone is placed into 75.0 grams of water at 23.1°C. The limestone and the water come to a final

temperature of 51.9°C. The specific heat capacity of water is 4.186 joules/gram degree Celsius, and the specific heat capacity of limestone is 0.921 joules/gram degree Celsius. What was the initial temperature of the limestone? Express your answer to three significant figures
Chemistry
1 answer:
VMariaS [17]2 years ago
7 0
M₁ = mass of water = 75 g
T₁ = initial temperature of water = 23.1 °C
c₁ = specific heat of water = 4.186 J/g°C

m₂ = mass of limestone = 62.6 g
T₂ = initial temperature of limestone = ?
c₂ = specific heat of limestone = 0.921 J/g°C

T = equilibrium temperature = 51.9 °C
using conservation of heat
Heat lost by limestone = heat gained by water
m₂c₂(T₂ - T) = m₁c₁(T - T₁)
inserting the values
(62.6) (0.921) (T₂ - 51.9) = (75) (4.186) (51.9 - 23.1)
T₂ = 208.73 °C
in three significant figures
T₂ = 209 °C
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Nata [24]

Answer:

22.7

Explanation:

First, find the energy released by the mass of the sample. The heat of combustion is the heat per mole of the fuel:

ΔHC=qrxnn

We can rearrange the equation to solve for qrxn, remembering to convert the mass of sample into moles:

qrxn=ΔHrxn×n=−3374 kJ/mol×(0.500 g×1 mol213.125 g)=−7.916 kJ=−7916 J

The heat released by the reaction must be equal to the sum of the heat absorbed by the water and the calorimeter itself:

qrxn=−(qwater+qbomb)

The heat absorbed by the water can be calculated using the specific heat of water:

qwater=mcΔT

The heat absorbed by the calorimeter can be calculated from the heat capacity of the calorimeter:

qbomb=CΔT

Combine both equations into the first equation and substitute the known values, with ΔT=Tfinal−20.0∘C:

−7916 J=−[(4.184 Jg ∘C)(600. g)(Tfinal–20.0∘C)+(420. J∘C)(Tfinal–20.0∘C)]

Distribute the terms of each multiplication and simplify:

−7916 J=−[(2510.4 J∘C×Tfinal)–(2510.4 J∘C×20.0∘C)+(420. J∘C×Tfinal)–(420. J∘C×20.0∘C)]=−[(2510.4 J∘C×Tfinal)–50208 J+(420. J∘C×Tfinal)–8400 J]

Add the like terms and simplify:

−7916 J=−2930.4 J∘C×Tfinal+58608 J

Finally, solve for Tfinal:

−66524 J=−2930.4 J∘C×Tfinal

Tfinal=22.701∘C

The answer should have three significant figures, so round to 22.7∘C.

8 0
2 years ago
A sample of neon gas at a pressure of 1.08 atm fills a flask with a volume of 250 mL at a temperature of 24.0 °C. If the gas is
musickatia [10]

Answer:

124.91mL

Explanation:

Given parameters:

P₁  = 1.08atm

V₁  = 250mL

T₁  = 24°C

P₂  = 2.25atm

T₂  = 37.2°C

V₂  = ?

Solution:

To solve this problem, we are going to apply the combined gas law;

              \frac{P_{1} V_{1} }{T_{1} }   =  \frac{P_{2} V_{2} }{T_{2} }

P, V and T represents pressure, volume and temperature

1 and 2 delineates initial and final states

Convert the temperature to kelvin;

        T₁  = 24°C,  T₁   = 24 + 273 = 297K

        T₂  = 37.2°C , T₂  = 37.2 + 273  = 310.2K

Input the variables and solve for V₂

        \frac{1.08 x 250}{298} = \frac{2.25 x V_{2} }{310.2}

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6 0
2 years ago
Molecular bromine is 24 percent dissociated at 1600 k and 1.00 bar in the equilibrium br2 (
dlinn [17]
Br2 == 2Br

24% dissociated => n total moles, 0.24 mol*n of Br, and 0.76*n mol of Br2

=> partial pressure of Br, P Br = 0.24 bar, and
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kp = (P Br)^2 / P Br2 = (0.24)^2 / 0.76 = 0.0758


3 0
2 years ago
5. You have 100 kg of gas of the following composition: CH4 - 30% H2 - 10% N2 - 60% What is the average molecular weight of this
Lorico [155]

Answer:

21.8 g/mol

Explanation:

Molecular weight of CH4 = 16g/mol

H2 = 2g/mol

N2 = 28g/mol

(16*30 + 2*10 + 28*60)/100

=2180/100

=21.8g/mol

6 0
1 year ago
Q 11.20: What is the product of the reaction between t-BuCl and MeOH? A : t-BuOH B : MeOCl C : t-BuOMe D : (CH3)2CCH2
Sholpan [36]

Answer:

C : t-BuOMe

Explanation:

The tert -butanol is a tertiary alcohol and when chloride ion attacks the carbocation, it forms t-BuCl.

The reaction of tert-butyl chloride or t-BuCl ((CH3)3C−Cl) with methanol and MeOH (CH3−OH) gives the product tert-Butyl methyl ether or t-BuOMe (CH3)3C−OCH3:

                   (CH3)3C−Cl + CH3−OH => (CH3)3C−OCH3 + HCl

Hence, the correct asnwer is C : t-BuOMe

5 0
1 year ago
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