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2 years ago

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During the lab, you measured the pH of mixtures containing strong acid and strong base. Write net Brønsted equations that show t

he acid-base reactions of common household items. For polyprotic species (such as vitamin C, lemon juice, and washing soda), please show only one proton transfer. Remember that spectator ions are not included. (Use the lowest possible coefficients. Omit states-of-matter in your answer.)
(a) bleach and vinegar (sodium hypochlorite and HC2H3O2)

1 answer:

jasenka [17]2 years ago

7 0

Answer:

ClO⁻ + HC₂H₃O₂ ⇄ HClO + C₂H₃O₂⁻

Explanation:

Sodium hypochlorite is a strong electrolyte that ionizes in sodium cation and hypochlorite anion.

NaClO(aq) ⇒ Na⁺(aq) + ClO⁻(aq)

ClO⁻ is a base that reacts with acetic acid (HC₂H₃O₂) from vinegar (neutralization reaction).

ClO⁻ + HC₂H₃O₂ ⇄ HClO + C₂H₃O₂⁻

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Calculate the amount of heat necessary to raise the temperature of 135.0 g of water from 50.4°F to 85.0°F. The specific heat of

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Here we have to calculate the heat required to raise the temperature of water from 85.0 ⁰F to 50.4 ⁰F.

10.857 kJ heat will be needed to raise the temperature from 50.4 ⁰F to 85.0 ⁰F

The amount of heat required to raise the temperature can be obtained from the equation H = m×s×(t₂-t₁).

Where H = Heat, s =specific gravity = 4.184 J/g.⁰C, m = mass = 135.0 g, t₁ (initial temperature) = 50.4 ⁰F or 10.222 ⁰C and t₂ (final temperature) = 85.0⁰F or 29.444 ⁰C.

On plugging the values we get:

H = 135.0 g × 4.184 J/g.⁰C×(29.444 - 10.222) ⁰C

Or, H = 10857.354 J or 10.857 kJ.

Thus 10857.354 J or 10.857 kJ heat will be needed to raise the temperature.

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A liquid has a volume of 34.6 ml and a mass of 46.0 g. what is the density of the liquid?

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Determine Z and V for steam at 250°C and 1800 kPa by the following: (a) The truncated virial equation [Eq. (3.38)] with the foll

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Answer:

Explanation:

Given that:

the temperature $T_1$ = 250 °C= ( 250+ 273.15 ) K = 523.15 K

Pressure = 1800 kPa

a)

The truncated viral equation is expressed as:

$\frac{PV}{RT} = 1 + \frac{B}{V} + \frac{C}{V^2}$

where; B = - $152.5 \ cm^3 /mol$ C = -5800 $cm^6/mol^2$

R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹

Plugging all our values; we have

$\frac{1800*V}{8.314*10^3*523.15} = 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

$4.138*10^{-4} \ V= 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

Multiplying through with V² ; we have

$4.138*10^4 \ V ^3 = V^2 - 152.5 V - 5800 = 0$

$4.138*10^4 \ V ^3 - V^2 + 152.5 V + 5800 = 0$

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Z = $\frac{1800*2250.06}{8.314*10^3*523.15}$

Z = 0.931

b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].

The generalized Pitzer correlation is :

$T_c = 647.1 \ K \\ \\ P_c = 22055 \ kPa \\ \\ \omega = 0.345$

$T__{\gamma}} = \frac{T}{T_c}$

$T__{\gamma}} = \frac{523.15}{647.1}$

$T__{\gamma}} = 0.808$

$P__{\gamma}} = \frac{P}{P_c}$

$P__{\gamma}} = \frac{1800}{22055}$

$P__{\gamma}} = 0.0816$

$B_o = 0.083 - \frac{0.422}{T__{\gamma}}^{1.6}}$

$B_o = 0.083 - \frac{0.422}{0.808^{1.6}}$

$B_o = 0.51$

$B_1 = 0.139 - \frac{0.172}{T__{\gamma}}^{ \ 4.2}}$

$B_1 = -0.282$

The compressibility is calculated as:

$Z = 1+ (B_o + \omega B_1 ) \frac{P__{\gamma}}{T__{\gamma}}$

$Z = 1+ (-0.51 +(0.345* - 0.282) ) \frac{0.0816}{0.808}$

Z = 0.9386

$V= \frac{ZRT}{P}$

$V= \frac{0.9386*8.314*10^3*523.15}{1800}$

V = 2268.01 cm³ mol⁻¹

c) From the steam tables (App. E).

At $T_1 = 523.15 \ K \ and \ P = 1800 \ k Pa$

V = 0.1249 m³/ kg

M (molecular weight) = 18.015 gm/mol

V = 0.1249 × 10³ × 18.015

V = 2250.07 cm³/mol⁻¹

R = 729.77 J/kg.K

Z = $\frac{PV}{RT}$

Z = $\frac{1800*10^3 *0.1249}{729.77*523.15}$

Z = 0.588

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