for the final step of the copper cycle, zinc, Zn(s), is added to copper sulfate, CuSO4(aq). Elemental copper appears as a solid.
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Explanation:
It is known that efficiency is denoted by .
The given data is as follows.
= 0.82,
= (21 + 273) K = 294 K
= 200 kPa,
= 1000 kPa
Therefore, calculate the final temperature as follows.
0.82 =
= 1633 K
Final temperature in degree celsius =
=
Now, we will calculate the entropy as follows.
For 1 mole,
It is known that for the value of
= 0.028 kJ/mol.
Therefore, putting the given values into the above formula as follows.
=
= 0.0346 kJ/mol
or, = 34.6 J/mol (as 1 kJ = 1000 J)
Therefore, entropy change of ammonia is 34.6 J/mol.
First, let's write down the balanced chemical reaction between the given reactants:
NO₂ + NO → N₂O + O₂
The Lewis structure of the main product is shown in the attached picture. To determine the formal charge of each element, the formula is as follows:
Formal Charge = Valence electrons - Non-bonding valence electrons - (Bonding electrons/2)
For the leftmost N:
Formal charge = 5 - 2 - 6/2 = 0
For the middle N:
Formal charge = 5 - 0 - 8/2 = 1
For O:
Formal charge = 6 - 6 - 2/2 = -1
NO₂ + NO → N₂O + O₂
The Lewis structure of the main product is shown in the attached picture. To determine the formal charge of each element, the formula is as follows:
Formal Charge = Valence electrons - Non-bonding valence electrons - (Bonding electrons/2)
For the leftmost N:
Formal charge = 5 - 2 - 6/2 = 0
For the middle N:
Formal charge = 5 - 0 - 8/2 = 1
For O:
Formal charge = 6 - 6 - 2/2 = -1