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Doss [256]
2 years ago
6

one kilogram of water (V1 = 1003 cm^3*kg-1) in a piston cylinder device at (25°C) and 1 bar is compressed in a mechanically reve

rsible, isothermal process to 1500 bar. Determine Q , W, ΔU , ΔH , and ΔS given that β = 250 x 10-6K-1 and K = 45 x 10^-6 bar-1.
Chemistry
1 answer:
vova2212 [387]2 years ago
4 0

Answer:

Q = -18118.5KJ

W = -18118.5KJ

∆U = 0

∆H = 0

∆S = -60.80KJ/KgK

Explanation:

W = RTln(P1/P2)

P1 = 1bar = 100KN/m^2, P2 = 1500bar = 1500×100 = 150000KN/m^2, T = 23°C = 23 + 273K = 298K

W = 8.314×298ln(100/150000) = 8.314×298×-7.313 = -18118.5KJ ( work is negative because the isothermal process involves compression)

∆U = Cv(T2 - T1)

For an isothermal process, temperature is constant, so T2 = T1

∆U = Cv(T1 - T1) = Cv × 0 = 0

Q = ∆U + W = 0 + (-18118.5) = 0 - 18118.5 = -18118.5KJ

∆H = Cp(T2 - T1)

T2 = T1

∆H = Cp(T1 - T1) = Cp × 0 = 0

∆S = Q/T

Mass of water = 1kg

Heat transferred (Q) per kilogram of water = -18118.5KJ/Kg

∆S = (-18118.5KJ/Kg)/298K = -60.80KJ/KgK

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483.27 minutes

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Each of three identical 15.0-L gas cylinders contains 7.50 mol of gas at 295 K. Cylinder A contains Ne, cylinder B contains NO2,
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Answer:

d) All have identical pressures

Explanation:

The kinetic molecular theory explains how gas molecules behave in a container. By this theory, the gas particles behave like hard, spherical objects in a state of constant, random motion; these particles collide between them and at the walls of the container. Besides, the kinetic energy of the gas depends only on the temperature.

The pressure is the force that the particles are applying under some area, so by the theory, it depends on the number of moles (amount of particles that collides and make the force), the volume of the container and the kinetic energy, or the temperature.

Because all gases have the same number of moles and are at the same temperature and the same volume, they'll have the same pressure.

3 0
2 years ago
How many paired and unpaired electrons are in magnesium?
pychu [463]

Answer:

Paired = 12

Unpaired = 0

Explanation:

Magnesium is alkaline earth metal.

It is present in second group.

Its atomic number is 12 and atomic mass 24 amu.

Electronic configuration:

Mg₁₂ = 1s² 2s² 2p⁶ 3s²

It can seen from electronic configuration that all electrons are paired because s subshell have one orbital and it can accomodate two electrons. Each s subshells in magnesium have two electrons so these are filled and have paired electrons. While p subshell have three orbitals and can accomodate six electrons two by each orbital with opposite spin thus 2p is also filled and have paired electrons.

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The vapor pressure of liquid iodomethane, CH3I, is 100. mm Hg at 266 K. A 0.453 g sample of liquid CH3I is placed in a closed, e
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Explanation:

The vapor pressure is the pressure of the vapor that is in equilibrium with the liquid. At a constant temperature, some molecules of the liquid will vaporize, and then will do pressure at the surface of the liquid.

If the pressure at the container is higher then the vapor pressure, the liquid will evaporate.

a. Let's calculate the pressure at the container by the ideal gas law:

PV = nRT

Where P is the pressure, V is the volume, n is the number of moles, R is the gas constant (62,364 mmHg.mL/mol.K), and T is the temperature.

The molar mass of CH₃I is 142 g/mol

n = mass/ molar mass

n = 0.453/142

n = 0.0032 mol

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P = 143.5 mmHg

So, all the liquid will evaporate.

b. Because all liquid evaporates, when the equilibrium is reached, the pressure is the gas pressure: 143.5 mmHg.

3 0
2 years ago
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