Dalton's Law of Partial Pressures, commonly applied to ideal gases, explains that the partial pressures of individual, non-reacting gases are equal to the total pressure exerted by the gas mixture. The given gas mixture composed of 90% argon and 10% carbon dioxide has the following partial pressures: 3.6 atm for argon and 0.4 atm for carbon dioxide (answer).
Boyle's law of ideal gas: This law states that the volume of a gas is inversely proportional to its pressure at a constant temperature. Acc to this law we can write the relation of pressure and volume as:
That means:
From that equation we can calculate Volume of gas at a certain pressure:
P₁=Initial pressure
V₁=Initial volume
P₂=Final pressure
V₂= Final volume
Here P₁, initial pressure is given as 85.0 kPa
V₁, initial volume is given as 525 mL
P₂, final pressure is 65.0 kPa
so,
V_{2}=85\times 525\div 65
=686 mL
Volume of gas will be 686 mL.
NH4I (aq) + KOH (aq) in chemical equation gives
NH4I (aq) + KOH (aq) = KI (aq) + H2O(l) + NH3 (l)
Ki is in aqueous state H2o is in liquid state while NH3 is in liquid state
from the equation above 1 mole of NH4I (aq) react with 1 mole of KOH(aq) to form 1mole of KI(aq) , 1mole of H2O(l) and 1 Mole of NH3(l)
Basis: 100 mL solution
From the given density, we calculate for the mass of the solution.
density = mass / volume
mass = density x volume
mass = (1.83 g/mL) x (100 mL) = 183 grams
Then, we calculate for the mass H2SO4 given the percentage.
mass of H2SO4 = (183 grams) x (0.981) = 179.523 grams
Calculate for the number of moles of H2SO4,
moles H2SO4 = (179.523 grams) / (98.079 g/mol)
moles H2SO4 = 1.83 moles
Molarity:
M = moles H2SO4 / volume solution (in L)
= 1.83 moles / (0.1L ) = 18.3 M
Molality:
m = moles of H2SO4 / kg of solvent
= 1.83 moles / (183 g)(1-0.983)(1 kg/ 1000 g) = 588.24 m
Here we will use the general formula of Nernst equation:
Ecell = E°Cell - [(RT/nF)] *㏑Q
when E cell is cell potential at non - standard state conditions
E°Cell is standard state cell potential = - 0.87 V
and R is a constant = 8.314 J/mol K
and T is the temperature in Kelvin = 73 + 273 = 346 K
and F is Faraday's constant = 96485 C/mole
and n is the number of moles of electron transferred in the reaction=2
and Q is the reaction quotient for the reaction
SO42-2(aq) + 4H+(aq) +2Br-(aq) ↔ Br2(aq) + SO2(g) +2H2O(l)
so by substitution :
0 = -0.87 - [(8.314*346K)/(2* 96485)*㏑Q → solve for Q
∴ Q = 4.5 x 10^-26
