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morpeh [17]
2 years ago
13

The standard heats of combustion (δh∘) per mole of 1,3-butadiene, c4h6(g); butane, c4h10(g); and h2(g) are −2540.2,−2877.6, and

−285.8kj, respectively. Use these data to calculate the heat of hydrogenation of 1,3-butadiene to butane. C4h6(g)+2h2(g)→c4h10(g)
Chemistry
1 answer:
ryzh [129]2 years ago
5 0

solution:

Hydration is the addition of water; hydrogenation is the addition of hydrogen.  

desire rxn: _C4H6(g) + 2 H2(g)-----> C4H10(g)___dHhy = ??  

knowns:  

__________C4H6 + 11/2 O2 --------> 4CO2 + 3H2O______dHox = -2540.2 kJ/mole  

__________4CO2 + 5H2O -----------> C4H10 + 13/2 O2___-dHox = 2877.6 kJ/mole  

___________2(1/2 O2 + H2 -------------> H2O)___________2*dHox = 2(-285.8 kJ/mole)  

Basic mathematics is a prerequisite to chemistry – I just try to help you with the methodology of solving the problem


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Steam initially at 0.3 MPa, 2500 C is cooled at constant volume. (a) At what temperature will steam become saturated vapour? [12
Scilla [17]

Answer:

a. 123.9°C

b.

c.

Explanation:

Hello, I'm attaching a picture with the numerical development of this exercise.

a. Since the steam is overheated vapour, the specific volume is gotten from the corresponding table. Then, as it became a saturated vapour, we look for the interval in which the same volume of state 1 is, then we interpolate and get the temperature.

b. Now, at 80°C, since it is about a rigid tank (constant volume for every thermodynamic process), the specific volume of the mixture is 0.79645 m^3/kg as well, so the specific volume for the liquid and the vapour are taken into account to get the quality of 0.234.

c. Now,since this is an isocoric process, the heat transfer per kg of steam is computed as the difference in the internal energy, considering the initial condition (showed in a. part) and the final one computed here.

** The thermodynamic data were obtained from Cengel's thermodynamics book 7th edition.

Best regards.

7 0
2 years ago
The air bags in cars are inflated when a collision triggers the explosive, highly exothermic decomposition of sodium azide (NaN3
Oksanka [162]

Answer : The mass of NaN_3 required is, 166.4 grams.

Explanation :

First we have to calculate the moles of nitrogen gas.

Using ideal gas equation:

PV=nRT

where,

P = Pressure of N_2 gas = 1.00 atm

V = Volume of N_2 gas = 113 L

n = number of moles N_2 = ?

R = Gas constant = 0.0821L.atm/mol.K

T = Temperature of N_2 gas = 85^oC=273+85=358K

Putting values in above equation, we get:

1.00atm\times 113L=n\times (0.0821L.atm/mol.K)\times 358K

n=3.84mol

Now we have to calculate the moles of sodium azide.

The balanced chemical reaction is,

2NaN_3(s)\rightarrow 2Na(s)+3N_2(g)

From the balanced reaction we conclude that

As, 3 mole of N_2 produced from 2 mole of NaN_3

So, 3.84 moles of N_2 produced from \frac{2}{3}\times 3.84=2.56 moles of NaN_3

Now we have to calculate the mass of NaN_3

\text{ Mass of }NaN_3=\text{ Moles of }NaN_3\times \text{ Molar mass of }NaN_3

Molar mass of NaN_3 = 65 g/mole

\text{ Mass of }NaN_3=(2.56moles)\times (65g/mole)=166.4g

Therefore, the mass of NaN_3 required is, 166.4 grams.

3 0
2 years ago
Find the de Broglie wavelength lambda for an electron moving at a speed of 1.00 \times 10^6 \; {\rm m/s}. (Note that this speed
masya89 [10]

(A) 7.28\cdot 10^{-10} m

The De Broglie wavelength of an electron is given by

\lambda=\frac{h}{p} (1)

where

h is the Planck constant

p is the momentum of the electron

The electron in this problem has a speed of

v=1.00\cdot 10^6 m/s

and its mass is

m=9.11\cdot 10^{-31} kg

So, its momentum is

p=mv=(9.11\cdot 10^{-31} kg)(1.00\cdot 10^6 m/s)=9.11\cdot 10^{-25}kg m/s

And substituting into (1), we find its De Broglie wavelength

\lambda=\frac{6.63\cdot 10^{-34}Js}{9.11\cdot 10^{-25} kg m/s}=7.28\cdot 10^{-10} m

(B) 1.16\cdot 10^{-34}m

In this case we have:

m = 0.143 kg is the mass of the ball

v = 40.0 m/s is the speed of the ball

So, the momentum of the ball is

p=mv=(0.143 kg)(40.0 m/s)=5.72 kg m/s

And so, the De Broglie wavelength of the ball is given by

\lambda=\frac{h}{p}=\frac{6.63\cdot 10^{-34} Js}{5.72 kg m/s}=1.16\cdot 10^{-34}m

(C) 9.02\cdot 10^{-9}m

The location of the first intensity minima is given by

y=\frac{L\lambda}{a}

where in this case we have

y=0.492 cm = 4.92\cdot 10^{-3} m

L = 1.091 is the distance between the detector and the slit

a=2.00\mu m=2.00\cdot 10^{-6}m is the width of the slit

Solving the formula for \lambda, we find the wavelength of the electrons in the beam:

\lambda=\frac{ya}{L}=\frac{(4.92\cdot 10^{-3}m)(2.00\cdot 10^{-6} m)}{1.091 m}=9.02\cdot 10^{-9}m

(D) 7.35\cdot 10^{-26}kg m/s

The momentum of one of these electrons can be found by re-arranging the formula of the De Broglie wavelength:

p=\frac{h}{\lambda}

where here we have

\lambda=9.02\cdot 10^{-9}m is the wavelength

Substituting into the formula, we find

p=\frac{6.63\cdot 10^{-34}Js}{9.02\cdot 10^{-9}m}=7.35\cdot 10^{-26}kg m/s

7 0
1 year ago
If the patient has to be administered a dosage of 2 tablets every 8 hours for 7 days, what is the number of tablets required for
Lilit [14]
If the patient has to take 2 tablets every 8 hours for 7 days.
 24/8=3     3*2=6
this means that he patient will have to take 6 tablets every day. 
6*7=42   And the patient must take 42 tablets in all 7 days
Hope this helps! :)
6 0
1 year ago
Which important change in electronic devices, such as televisions and computers, is a result of the use of metalloids as semicon
nalin [4]

Answer:

option A

Explanation:

correct answer is option A

metalloids are the substances which are not metal and also are not non-metal they have the property of both metals and non-metals.                                                  

metalloids example are silicon, Germanium, Arsenic (As) etc.

Usage of metalloids as semiconductor has  decreases the size of the circuits which leads to the shrink the size of many electronic devices such as TV, mobile etc.

8 0
1 year ago
Read 2 more answers
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