Answer:
The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>
Explanation:
Given: The base dissociation constant: 
= 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M
Also, water dissociation constant: 
= 1 × 10⁻¹⁴
<em><u>The acid dissociation constant </u></em>(
)<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>
<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>
Reaction involved: BH⁺ + H₂O ⇌ B + H₃O+
Initial: 0.1 M x x
Change: -x +x +x
Equilibrium: 0.1 - x x x
<u>The acid dissociation constant: </u>![K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5Cleft%20%5BB%20%5Cright%20%5D%20%5Cleft%20%5BH_%7B3%7DO%5E%7B%2B%7D%5Cright%20%5D%7D%7B%5Cleft%20%5BBH%5E%7B%2B%7D%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B%28x%29%28x%29%7D%7B%280.1%20-%20x%29%7D%20%3D%20%5Cfrac%7Bx%5E%7B2%7D%7D%7B0.1%20-%20x%7D)
<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>
Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44
<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>
<u>Answer:</u> The enthalpy of the reaction for the production of 
is coming out to be -74.9 kJ
<u>Explanation:</u>
Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as 
The equation used to calculate enthalpy change is of a reaction is:
![\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28reactant%29%7D%5D)
For the given chemical reaction:
The equation for the enthalpy change of the above reaction is:
![\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(CH_4(g))})]-[(1\times \Delta H^o_f_{(C(s))})+(2\times \Delta H^o_f_{(H_2(g))})]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28CH_4%28g%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28C%28s%29%29%7D%29%2B%282%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28H_2%28g%29%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![\Delta H^o_{rxn}=[(1\times (-74.9))]-[1\times 0)+(2\times 0)]\\\\\Delta H^o_{rxn}=-74.9kJ](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%28-74.9%29%29%5D-%5B1%5Ctimes%200%29%2B%282%5Ctimes%200%29%5D%5C%5C%5C%5C%5CDelta%20H%5Eo_%7Brxn%7D%3D-74.9kJ)
Hence, the enthalpy of the reaction for the production of is coming out to be -74.9 kJ
Check the attached file for the answer.
To determine the pOH assuming water is the universal solvent take the value of 10 ^ -14 and then divide it by the hydronium concentration and then take the negative logarithm of the final answer that is the solution to the hydroxide ion concentration in the solution.
The solubility of NaCl in water at 100 C is 40%, meaning that we can dissolve 40 g NaCl in 100 g water. Assuming that dissolving NaCl does not add any volume to the solution, 600 mL of water is approximately equal to 600 g of water. By ratio and proportion: 40 g NaCl/100 g H2O = x g NaCl/600 g H2O
x = 240 g NaCl
So 240 g of NaCl must be dissolved to form a saturated solution.
