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inessss [21]
1 year ago
15

5.00 g of hydrogen gas and 50.0g of oxygen gas are introduced into an otherwise empty 9.00L steel cylinder, and the hydrogen is

ignitted by an electric spark. if the reaction product is gaseous water and the temperature of the cylinder is maintained at 35Celsius what is the final gas pressure inside the cylinder?
Chemistry
2 answers:
Brrunno [24]1 year ago
4 0
For the limiting reagent  2.48mol of H2O
the excess  3.13mol of H2O...
n=moles m=mass Mr=Relative molecular mass 
n=m/MrsoH2: n1=5/2=40/16=2.5O2: n2=50/32=25/16=1.5625
2 H2 + O2 -> 2 H2O (oxygen is in execess)2.5       1.5625     0-2.5      -1.25       +2.50            0.3125     2.5 there for 0.3125+2.5=2.8125 mole of gas in cylinder
P*V=n*R*TP=7.8925 atm
GenaCL600 [577]1 year ago
3 0
1) Balanced chemical reaction:

2H2 + O2 -> 2H20

Sotoichiometry: 2 moles H2: 1 mol O2 : 2 moles H2O

2) Reactant quantities converted to moles

H2: 5.00 g / 2 g/mol = 2.5 mol

O2: 50.0 g / 32 g/mol = 1.5625 mol

Limitant reactant: H2 (because as per the stoichiometry it will be consumed with 1.25 mol of O2).

3) Products

H2 totally consumed -> 0 mol at the end

O2 = 1.25 mol consumed -> 1.5625 mol - 1.25 mol = 0.3125 mol at the end

H2O: 2.5 mol H2 produces 2.5 mol H2O -> 2.5 mol at the end.

Total number of moles: 0.3125mol + 2.5 mol = 2.8125 mol

4) Pressure

Use pV = nRT
n = 2.8125
V= 9 liters
R = 0.082 atm*lit/K*mol
T = 35 C + 273.15 = 308.15K

p = nRT/V  = 7.9 atm
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Answer:

Solution of isopropanol is 10.25 molal

Explanation:

615 g of isopropanol (C3H7OH) per liter

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Notice we converted the L to mL

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Molality are the moles of solute in 1kg of solvent, so let's convert the moles of isopropanol  → 615 g . 1mol / 60g = 10.25 moles

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1 year ago
Consider a general reaction A ( aq ) enzyme ⇌ B ( aq ) A(aq)⇌enzymeB(aq) The Δ G ° ′ ΔG°′ of the reaction is − 5.980 kJ ⋅ mol −
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Answer : The value of K_{eq} is, 11.2

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The relation between the equilibrium constant and standard Gibbs free energy is:

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\Delta G^o = standard Gibbs free energy  = -5.980 kJ/mol = -5980 J/mol

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K_{eq}  = equilibrium constant  = ?

Now put all the given values in the above formula, we get:

\Delta G^o=-RT\times \ln K_{eq}

-5980J/mol=-(8.314J/K.mol)\times (298K)\times \ln K_{eq}

K_{eq}=11.2

Thus, the value of K_{eq} is, 11.2

Now we have to calculate the \Delta G_{rxn}.

The formula used for \Delta G_{rxn} is:

The given reaction is:

A(aq)\rightleftharpoons B(aq)

\Delta G_{rxn}=\Delta G^o+RT\ln Q

\Delta G_{rxn}=\Delta G^o+RT\ln \frac{[B]}{[A]}    ............(1)

where,

\Delta G_{rxn} = Gibbs free energy for the reaction  = ?

\Delta G_^o =  standard Gibbs free energy  = -30.5 kJ/mol

R = gas constant = 8.314\times 10^{-3}kJ/mole.K

T = temperature = 37.0^oC=273+37.0=310K

Q = reaction quotient

[A] = concentration of A = 1.8 M

[B] = concentration of B = 0.55 M

Now put all the given values in the above formula 1, we get:

\Delta G_{rxn}=(-5980J/mol)+[(8.314J/mole.K)\times (310K)\times \ln (\frac{0.55}{1.8})

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Therefore, the value of \Delta G_{rxn} is -9.04 kJ/mol

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