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erastovalidia [21]
2 years ago
5

gaseous h2 and br2 are added to an evacuated 1.15L container kept at 298K. The intial partial pressurre of H2(g) is 0.782 atm an

d that of Br2 (g) is 0.493 atm. Find the partial pressures of HBr when the system reaches equilibrium
Physics
1 answer:
Nastasia [14]2 years ago
3 0

The partial pressures of HBr when the system reaches equilibrium is 2.4 X 10⁻¹¹ atm

<u>Explanation:</u>

H₂ + Br₂ ⇒ 2HBr

PH₂ = 0.782atm

PBr₂ = 0.493atm

Kp = (PHBr)²/ (PH₂) (PBr₂) = 1.4 X 10⁻²¹

At equilibrium:

Let 2x = pressure of HBr

PH₂ = 0.782 -x

PBr₂ = 0.493 - x

Kp = (2x)^2 / (0.782-x)(0.493-x)

Now, because Kp is very small, x will be very small compared to 0.782 and 0.493.

Then,

Kp = 1.4X10⁻²¹ = (4x²) / (0.782)(0.493)

x = 1.2X10⁻¹¹

PHBr = 2x = 2.4 X 10⁻¹¹ atm

Therefore, the partial pressures of HBr when the system reaches equilibrium is 2.4 X 10⁻¹¹ atm

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The work is therefore:

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2 years ago
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