Answer:
ΔU=-369.2 kJ/mol.
Explanation:
We start from the equation:
Δ(H)=ΔU+Δ(PV), which is an extension of the well known relation: H=U+PV.
If Δ(PV) were calculated by ideal gas law,
PV=nRT
Δ(PV)=RTΔn.
Where Δn is the change of moles due to the reaction; but, this reaction does not give a moles change (Four moles of HCl produced from 4 moles of reactants), so Δ(PV)=0.
So, for this case, ΔH=ΔU.
The enthalpy of reaction given is for one mole of reactant, so the enthalpy of reaction for the reaction of interest must be multiplied by two:
ΔU=-369.2 kJ/mol.
Answer:
Explanation:
Fe⁺² (aq) + 2e⁻ = Fe (s) ; E⁰ = - .44 V
Fe⁺³ (aq) + e⁻ = ® Fe²⁺ (aq) ; E⁰ = + .77 V
Reduction potential of second reaction is more , so it will take place , ie Fe⁺³ will be reduced and Fe will be oxidised .
So reaction in the combined cell will be
2Fe⁺³ + Fe = 3Fe⁺²
cell potential = .77 - ( - .44 )
= 1.21 V .
Answer : The number of moles of oxygen present in a sample are 11.3 moles.
Explanation :
The given compound is, 
By the stoichiometry we can say that, 1 mole of of has 4 moles of CO.
Or we can say that, 1 mole of of has 1 mole of nickel (Ni), 4 moles of carbon (C) and 4 moles of oxygen.
That means,
Number of moles of carbon = Number of moles of oxygen
As we are given that:
Number of moles of carbon = 11.3 moles
So, number of moles of oxygen = number of moles of carbon = 11.3 moles
Therefore, the number of moles of oxygen present in a sample are 11.3 moles.
Answer:
Explanation:
Given:
Initial volume of the balloon V1 = 348 mL
Initial temperature of the balloon T1 = 255C
Final volume of the balloon V2 = 322 mL
Final temperature of the balloon T2 =
To calculate T1 in kelvin
T1= 25+273=298K
Based on Charles law, which states that the volume of a given mass of a ideal gas is directly proportional to the temperature provided that the pressure is constant. It can be applied using the below formula
T2=( V2*T1)/V1
T2=(322*298)/348
Hence, the temperature of the freezer is 276 K
