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Bond [772]
2 years ago
10

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚C inside a freezer for a night. When he took it out, its new volu

me was 322 milliliters, but its pressure was the same. If the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer?
Chemistry
1 answer:
katrin2010 [14]2 years ago
8 0

Answer:

T2=276K

Explanation:

Given:

Initial volume of the balloon V1 = 348 mL

Initial temperature of the balloon T1 = 255C

Final volume of the balloon V2 = 322 mL

Final temperature of the balloon T2 =

To calculate T1 in kelvin

T1= 25+273=298K

Based on Charles law, which states that the volume of a given mass of a ideal gas is directly proportional to the temperature provided that the pressure is constant. It can be applied using the below formula

(V1/T1)=(V2/T2)

T2=( V2*T1)/V1

T2=(322*298)/348

T2=276K

Hence, the temperature of the freezer is 276 K

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Phosphorous acid, h3po3(aq), is a diprotic oxyacid that is an important compound in industry and agriculture. calculate the ph f
Varvara68 [4.7K]

Answer:

Explanation:

(a)

Before the addition of KOH :-

Given pKa1 of H3PO3 = 1.30

we know , pKa1 = - log10Ka1

Ka1 = 10-pKa1

Ka1 = 10-1.30

Ka1 = 0.0501

similarly pKa2 = 6.70 ,therefore Ka2 = 1.99 x 10-7

because Ka1 >> Ka2 , therefore pH of diprotic acid i.e H3PO3 can be calculated from first dissociation only .

ICE table is :-

H3PO3 (aq) <-------------> H+ (aq) + H2PO3-(aq)

I 2.4 M 0 M 0 M

C - x + x + x

E (2.4 - x )M x M x M

x = degree of dissociation

Now expression of Ka1 is :

Ka1 = [ H+ ] [ H2PO3-] / [ H3PO3]

0.0501 = x2 / 2.4 - x

on solving for x by using quadratic formula , we have

x = 0.32

Now [ H+ ] = [ H2PO3-] = 0.32 M

pH = - log [H+]

pH = - log 0.32

pH = - ( - 0.495)

pH = 0.495

Hence pH before the addition of KOH = 0.495

(b)

After the addition of 25.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.025 L = 0.06 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

Now 0.06 moles of KOH is equal to the half of the moles required for the first equivalent point . therefore pH at this point is equal to pKa1 .

Hence pH = 1.30 M

(c)

After the addition of 50.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.050 L = 0.12 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

because Number of moles of H3PO4 = Number of moles of KOH

therefore , this point is the first equivalence point

and pH = pKa1 + pKa2 / 2

pH = 1.30 + 6.70 / 2

pH = 4.00

Hence pH = 4.00

(d)

After the addition of 75.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.075 L = 0.18 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

This is the half way of the second equivalence point , therefore pH is equal to pKa2 .

Hence pH = 6.70

5 0
2 years ago
What is water's density at 93 ∘C? Assume a constant coefficient of volume expansion. Express your answer with the appropriate un
Ganezh [65]

Answer:

982.5 kg/m³

Explanation:

When the temperature of a fluid increases, it dilates, and because of the variation of the volume, it's density will vary too. The density can be calculated by the expression:

ρ₁ = ρ₀/(1 + β*(t₁ - t₀))

Where ρ₁ is the final density, ρ₀ the initial density, β is the constant coefficient of volume expansion, t₁ the final temperature, and t₀ the initial temperature.

At t₀ = 4°C, the water desity is ρ₀ = 1,000 kg/m³. The value of the constant for water is β = 0.0002 m³/m³ °C, so, for t₁ = 93°C

ρ₁ = 1,000/(1 + 0.0002*(93 - 4))

ρ₁ = 1,000/(1+ 0.0178)

ρ₁ = 982.5 kg/m³

3 0
2 years ago
The researcher performed a follow-up experiment to measure the rate of oxygen consumption by muscle and brain cells. Predict the
Naddik [55]

Answer:

Mitochondria are abundantly present in mammalian cells. Their fraction varies from tissue to tissue, ranging from <1% (volume) in white blood cells to 35% in heart muscle cells. However, mitochondria should not be thought of as single entities, but rather a dynamic network that continuously undergoes fission and fusion processes. In skeletal muscle, mitochondria exist as a reticular membrane network. The subsarcolemmal (SS) and intermyofibrillar (IMF) mitochondria are located in distinct subcellular regions, and they possess subtle differences in biochemical and functional properties that are characterized by their anatomical locations. SS mitochondria lie directly beneath the sarcolemmal membrane and the IMF mitochondria are located in close contact with the myofibril. Their different properties are likely to influence their capacity for adaptation. SS mitochondria account for 10-15% of the mitochondrial volume and this population has been shown to be more susceptible to adaptation than the IMF mitochondria. However, the IMF mitochondria were found to have higher rates of protein synthesises, enzyme activities and respiration (1).

Explanation:

0 0
2 years ago
Read 2 more answers
Rank the following compounds in order of reactivity toward nitration with HNO3:_______. thiophene, benzene, 3-methylthiophene, a
siniylev [52]

Answer:

3-methylthiophene > thiophene > benzene > 2-methylfuran

Explanation:

Primarily, five membered heterocyclic aromatic rings undergo nitration at carbon-2. This is because, nitration at carbon-2 leads to the formation of three resonance structures while attack at carbon-3 yields only two resonance structures, hence it is less stabilized.

The presence of a methyl group which donates electrons promotes the stabilization of the cation formed in the nitration of 3-methylthiophene.

2-methylfuran is the least reactive towards nitration because the 2-position has been blocked by a methyl group.

3 0
2 years ago
According to the quantum-mechanical model for the hydrogen atom, which electron transition produces light with the longer wavele
LekaFEV [45]

Answer:

Explanation:

The main task here is that there are some missing gaps in the above question that needs to be filled with the appropriate answers. So, we are just going to do rewrite the answer below as we indicate the missing gaps by underlining them and making them in bold format.

SO; In the quantum-mechanical model of the hydrogen atom.

As the n level increases. the energy <u>increases</u> and thus levels are <u>closer to </u>each other. Therefore, the transition <u>3p→2s</u> would have a greater energy difference than the transition from <u>4p→3p.</u>

Energy \  and \  wavelength  \ are \  inversely \   proportional , \  so \  the \ \mathbf{ 4p\to 3p} \ transition  \ wouldproduce  \ a  \ longer \ wavelength.

3 0
2 years ago
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