Answer:
NaI > Na2SO4 > Co Br3
meaning that NaI has the highest freezing point, and Co Br3 has the lowest freezing point.
Explanation:
The freezing point depression is a colligative property.
That means that it depends on the number of solute particles dissolved.
The formula to calculate the freezing point depression of a solution of a non volatile solute is:
ΔTf = i * Kf * m
Where kf is a constant, m is the molality and i is the van't Hoff factor.
Molality, which is number of moles per kg of solvent, counts for the number of moles dissolved and the van't Hoff factor multipllies according for molecules that dissociate.
The higher the number of molecules that dissociate, the higher the van't Hoff, the greater the freezing point depression and the lower the freezing point.
As the question states that you assume equal concentrations (molality) and complete dissociation you just must find the number of ions generated by each solute, in this way:
NH4 I → NH4(+) + I(-) => 2 ions
Co Br3 → Co(+) + 3 Br(-) => 4 ions
Na2SO4 → 2Na(+) + SO4(2-) => 3 ions.
So, Co Br3 is the solute that generate more particles and that solution will exhibit the lowest freezing point among the options given, Na2SO4 is next and the NaI is the third. Ordering the freezing point from higher to lower the rank is NaI > Na2SO4 > CoBr3, which is the answer given.
There is an exact value for the standard volume at standard conditions of 1 atm and 273 K. This standard volume for any ideal gas is 22.4 L/mol. Thus,
Moles SO₂ = 5.9 L * 1 mol/22.4 L = 0.263 mol
The molar mass for SO₂ is 64.066 g/mol. So, the mass is:
Mass = 0.263 mol * 64.066 g/mol = <em>16.87 g SO₂</em>
The concentration of sodium and sulphate ions are [
] = 0.4 M, [
] = 0.2 M
Explanation:
The molar concentration is defined as the number of moles of a molecule or an ion in 1 liter of a solution.
In the given solution, the concentration of the salt sodium sulphate is 0.2M. So, 0.2 moles of sodium sulphate is present in 1 liter of solution.
Assuming 100% dissociation,
1 molecule of sodium sulphate gives 2 ions of sodium and 1 ion of sulphate.
So 0.2 moles of sodium sulphate will give 0.4 moles of sodium ions and 0.2 moles of sulphate ions.
Answer:
(a) Cu²⁺ +2e⁻ ⇌ Cu
(c) 0.07 V
Explanation:
(a) Cu half-reaction
Cu²⁺ + 2e⁻ ⇌ Cu
(c) Cell voltage
The standard reduction potentials for the half-reactions are+
<u> E°/V
</u>
Cu²⁺ + 2e⁻ ⇌ Cu; 0.34
Hg₂Cl₂ + 2e⁻ ⇌ 2Hg + 2Cl⁻; 0.241
The equation for the cell reaction is
E°/V
Cu²⁺(0.1 mol·L⁻¹) + 2e⁻ ⇌ Cu; 0.34
<u>2Hg + 2Cl⁻ ⇌ Hg₂Cl₂ + 2e⁻; </u> <u>-0.241
</u>
Cu²⁺(0.1 mol·L⁻¹) + 2Hg + 2Cl⁻ ⇌ Cu + Hg₂Cl₂; 0.10
The concentration is not 1 mol·L⁻¹, so we must use the Nernst equation
(ii) Calculations:
T = 25 + 273.15 = 298.15 K
![Q = \dfrac{\text{[Cl}^{-}]^{2}}{ \text{[Cu}^{2+}]} = \dfrac{1}{0.1} = 10\\\\E = 0.10 - \left (\dfrac{8.314 \times 298.15 }{2 \times 96485}\right ) \ln(10)\\\\=0.010 -0.01285 \times 2.3 = 0.10 - 0.03 = \textbf{0.07 V}\\\text{The cell potential is }\large\boxed{\textbf{0.07 V}}](https://tex.z-dn.net/?f=Q%20%3D%20%5Cdfrac%7B%5Ctext%7B%5BCl%7D%5E%7B-%7D%5D%5E%7B2%7D%7D%7B%20%5Ctext%7B%5BCu%7D%5E%7B2%2B%7D%5D%7D%20%3D%20%5Cdfrac%7B1%7D%7B0.1%7D%20%3D%2010%5C%5C%5C%5CE%20%3D%200.10%20-%20%5Cleft%20%28%5Cdfrac%7B8.314%20%5Ctimes%20298.15%20%7D%7B2%20%5Ctimes%2096485%7D%5Cright%20%29%20%5Cln%2810%29%5C%5C%5C%5C%3D0.010%20-0.01285%20%5Ctimes%202.3%20%3D%200.10%20-%200.03%20%3D%20%5Ctextbf%7B0.07%20V%7D%5C%5C%5Ctext%7BThe%20cell%20potential%20is%20%7D%5Clarge%5Cboxed%7B%5Ctextbf%7B0.07%20V%7D%7D)
1. I think you chose the right answer, the equation has the states of the reactants and products.
2. I think you chose the right answer.
3. I think you also chose the right answer. Assuming that the Hrxn is written as kJ per mol CH4
4. Heat of solution is the enthalpy change associated with dissolving a solute in a solvent. I think the first choice is the right one.
5. I think you chose the right answer.