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crimeas [40]
2 years ago
10

This is the chemical formula for nickel tetracarbonyl (a powerfully poisonous liquid used in nickel refining) Ni(CO)4 A chemical

engineer has determined by measurements that there are 11.3 moles of carbon in a sample of nickel tetracarbonyl. How many moles of oxygen ar in the sample?
Chemistry
1 answer:
OverLord2011 [107]2 years ago
7 0

Answer : The number of moles of oxygen present in a sample are 11.3 moles.

Explanation :

The given compound is, Ni(CO)_4

By the stoichiometry we can say that, 1 mole of of Ni(CO)_4 has 4 moles of CO.

Or we can say that, 1 mole of of Ni(CO)_4 has 1 mole of nickel (Ni), 4 moles of carbon (C) and 4 moles of oxygen.

That means,

Number of moles of carbon = Number of moles of oxygen

As we are given that:

Number of moles of carbon = 11.3 moles

So, number of moles of oxygen = number of moles of carbon = 11.3 moles

Therefore, the number of moles of oxygen present in a sample are 11.3 moles.

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Assuming equal concentrations and complete dissociation, rank these aqueous solutions by their freezing points. NH4l, CoBr3, Na2
seraphim [82]
Answer:

NaI > Na2SO4 > Co Br3

meaning that NaI has the highest freezing point, and Co Br3 has the lowest freezing point.

Explanation:

The freezing point depression is a colligative property.

That means that it depends on the number of solute particles dissolved.

The formula to calculate the freezing point depression of a solution of a non volatile solute is:

ΔTf = i * Kf * m

Where kf is a constant, m is the molality and i is the van't Hoff factor.

Molality, which is number of moles per kg of solvent, counts for the number of moles dissolved and the van't Hoff factor multipllies according for molecules that dissociate.

The higher the number of molecules that dissociate, the higher the van't Hoff, the greater the freezing point depression and the lower the freezing point.

As the question states that you assume equal concentrations (molality) and complete dissociation you just must find the number of ions generated by each solute, in this way:

NH4 I → NH4(+) + I(-) => 2 ions

Co Br3 → Co(+) + 3 Br(-) => 4 ions

Na2SO4 → 2Na(+) + SO4(2-) => 3 ions.

So, Co Br3 is the solute that generate more particles and that solution will exhibit the lowest freezing point among the options given, Na2SO4 is next and the NaI is the third. Ordering the freezing point from higher to lower the rank is NaI > Na2SO4 > CoBr3, which is the answer given.
4 0
1 year ago
Calculate the grams of so2 gas present at stp in a 5.9 l container. (r = 0.0821 l·atm/k·mol)
Neko [114]
There is an exact value for the standard volume at standard conditions of 1 atm and 273 K. This standard volume for any ideal gas is 22.4 L/mol. Thus,

Moles SO₂ = 5.9 L * 1 mol/22.4 L = 0.263 mol

The molar mass for SO₂ is 64.066 g/mol. So, the mass is:

Mass = 0.263 mol * 64.066 g/mol = <em>16.87 g SO₂</em>
6 0
2 years ago
A beaker has 0.2 M of Na2SO4. What will be the concentration of sodium and sulfate ions?
netineya [11]

The concentration of sodium and sulphate ions are [Na^+] = 0.4 M, [SO_4^2-] = 0.2 M

Explanation:

The molar concentration is defined as the number of moles of a molecule or an ion in 1 liter of a solution.

In the given solution, the concentration of the salt sodium sulphate is 0.2M. So, 0.2 moles of sodium sulphate is present in 1 liter of solution.

Assuming 100% dissociation,

1 molecule of sodium sulphate gives 2 ions of sodium and 1 ion of sulphate.

So 0.2 moles of sodium sulphate will give 0.4 moles of sodium ions and 0.2 moles of sulphate ions.

7 0
2 years ago
A cell was prepared by dipping a Cu wire and a saturated calomel electrode into 0.10 M CuSO4 solution. The Cu wire was attached
Rashid [163]

Answer:

(a)  Cu²⁺ +2e⁻ ⇌ Cu

(c) 0.07 V  

Explanation:

(a) Cu half-reaction

Cu²⁺ + 2e⁻ ⇌ Cu

(c) Cell voltage

The standard reduction potentials for the half-reactions are+

                                             <u> E°/V </u>

Cu²⁺ + 2e⁻ ⇌ Cu;                  0.34  

Hg₂Cl₂ + 2e⁻ ⇌ 2Hg + 2Cl⁻; 0.241

The equation for the cell reaction is

                                                                            E°/V

Cu²⁺(0.1 mol·L⁻¹) + 2e⁻ ⇌ Cu;                               0.34  

<u>2Hg + 2Cl⁻ ⇌ Hg₂Cl₂ + 2e⁻;                             </u> <u>-0.241 </u>

Cu²⁺(0.1 mol·L⁻¹) + 2Hg + 2Cl⁻ ⇌ Cu + Hg₂Cl₂;   0.10

The concentration is not 1 mol·L⁻¹, so we must use the Nernst equation

(ii) Calculations:  

T = 25 + 273.15 = 298.15 K

Q = \dfrac{\text{[Cl}^{-}]^{2}}{ \text{[Cu}^{2+}]} = \dfrac{1}{0.1} = 10\\\\E = 0.10 - \left (\dfrac{8.314 \times 298.15 }{2 \times 96485}\right ) \ln(10)\\\\=0.010 -0.01285 \times 2.3 = 0.10 - 0.03 = \textbf{0.07 V}\\\text{The cell potential is }\large\boxed{\textbf{0.07 V}}

 

3 0
1 year ago
Check my answers please? 1. Which of the following is a correctly written thermochemical equation? NH4Cl NH4+ + Cl 2C8H18 + 25O2
snow_tiger [21]
1. I think you chose the right answer, the equation has the states of the reactants and products. 2. I think you chose the right answer. 3. I think you also chose the right answer. Assuming that the Hrxn is written as kJ per mol CH4 4. Heat of solution is the enthalpy change associated with dissolving a solute in a solvent. I think the first choice is the right one. 5. I think you chose the right answer.
4 0
1 year ago
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