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nekit [7.7K]
2 years ago
12

Calculate the pressure exerted by 66.0 g of CO2 gas at -14.5°C that occupies a volume of 50.0 L

Chemistry
1 answer:
Anestetic [448]2 years ago
5 0

Answer:

Pressure = 0.64 atm

Explanation:

Use Ideal Gas Law PV = nRT => P = nRT/V

n = moles CO₂(g) = 66g/44g/mol = 1.5 mol CO₂

R = Gas Constant = 0.08206 L·atm/mol·K

T = Temperature = -14.5°C = (-14.5 + 273)K = 258.5 K

V = 50.0 Liters

P = (1.5 mol)(0.08206 L·atm/mol·K)(258.5 K)/(50.0 L) = 0.64 atm

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Using the data, which of the following is the rate constant for the rearrangement of methyl isonitrile at 320 ∘C? (HINT: the act
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Explanation:

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3 0
2 years ago
The values used in the scale of pH and pOH are derived from a system designed by ______. Gordonsen Sorenson Curie Dalton
yaroslaw [1]

Sorenson

Explanation:

The values used in the scale of pH and pOH are derived from a system designed by Sorenson. Søren Peter Lauritz Sørensen, a Danish chemist introduced the system of pH and pOH for describing the alkalinity and acidity of substances.

  • The pH and pOH scale is logarithmic scale that ranks the acidity and bascity of compounds.
  • pH is the negative logarithm of the concentration of  hydrogen/hydroxonium ions in solution i.e

              pH = -log₁₀{H⁺]

  • pOH is the negative log of the concentration of the hydroxyl ions in a solution i.e

             pOH = -log₁₀{OH⁻]

Learn more:

calculating pH: brainly.com/question/12985875

pH scale: brainly.com/question/11063271

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3 0
2 years ago
If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th
fredd [130]

Answer:

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be  the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

 [Pb²⁺] =   s

Then [I⁻] = 2s

K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} =  4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of  }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

B)

The Concentration of Pb²⁺  in water is calculated as :

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}

\mathbf{s} =\sqrt[3]{1.75*10^{-9}}

\mathbf{s} =\mathbf{1.21*10^{-3}  \ mol/L }

The Concentration of Pb²⁺  in 1.0 mol·L⁻¹ NaI

\mathbf{PbCl{_2}}  \leftrightharpoons    \ \ \ \ \ \ \  \mathbf{Pb^{2+}}   \ \ \ \  \ +   \ \  \ \ \ \ \ \mathbf{2 I^-}

                             \ \ \ \ \ \ \  \ \   \ \  \ \ \ \ \ \ \  \mathbf0}   \ \ \ \  \ \ \ \ \ \   \ \ \ \ \ \mathbf{1.0}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{+2x}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{1.0+2x}

The equilibrium constant:

K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \  m/L

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the  common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

3 0
2 years ago
The highest energy occupied molecular orbital in the f-f bond of the f2 molecule is _____
Morgarella [4.7K]
The basis of finding the answer to this problem is to know the electronic configuration of Fluorine. That would be: <span>[He] 2s</span>²<span> 2p</span>⁵. The valence electrons, which are the outermost electrons of the atom, are the ones that participate in bonding. <em>Since the highest orbital for F is 2p, that means the highest energy occupied would be 2.</em>
3 0
2 years ago
Picric acid has been used in the leather industry and in etching copper. However, its laboratory use has been restricted because
olchik [2.2K]

Answer:

0.3023 M

Explanation:

Let Picric acid = H_{picric}

So,  H_{picric}     +       H_2}O          ⇄      H_3}O^+     +     Picric^-

The ICE table can be given as:

                          H_{picric}     +       H_2}O          ⇄      H_3}O^+     +     Picric^-

Initial:                0.52                                               0                  0

Change:             - x                                                 + x                 + x

Equilibrium:      0.52 - x                                        + x                 + x

Given that;

acid dissociation constant  (K_a) = 0.42

K_a = \frac{[H_3O^+][Picric^-]}{H_{picric}}

0.42 = \frac{[x][x]}{0.52-x}}

0.42 = \frac{[x]^2}{0.52-x}}

0.42(0.52-x) = x²

0.2184 - 0.42x = x²

x²  + 0.42x - 0.2184 = 0                   -------------------- (quadratic equation)

Using the quadratic formula;

\frac{-b+/-\sqrt{b^2-4ac} }{2a}    ;     ( where +/-  represent ± )

= \frac{-0.42+/-\sqrt{(0.42)^2-4(1)(-0.2184)} }{2*1}

= \frac{-0.42+/-\sqrt {0.1764+0.8736} }{2}

= \frac{-0.42+\sqrt {1.0496} }{2}     OR   \frac{-0.42-\sqrt {1.0496} }{2}

= \frac{-0.42+1.0245}{2}       OR    \frac{-0.42-1.0245}{2}

= \frac{0.6045}{2}                 OR    -\frac{1.4445}{2}

= 0.30225          OR     - 0.72225

So, we go by the +ve integer that says:

x =  0.30225

x = [ H_3}O^+ ] = [   Picric^- ] =  0.3023  M

∴  the value of  [H3O+] for an 0.52 M solution of picric acid  = 0.3023 M     (to 4 decimal places).

6 0
2 years ago
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