Explanation:
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Sorenson
Explanation:
The values used in the scale of pH and pOH are derived from a system designed by Sorenson. Søren Peter Lauritz Sørensen, a Danish chemist introduced the system of pH and pOH for describing the alkalinity and acidity of substances.
- The pH and pOH scale is logarithmic scale that ranks the acidity and bascity of compounds.
- pH is the negative logarithm of the concentration of hydrogen/hydroxonium ions in solution i.e
pH = -log₁₀{H⁺]
- pOH is the negative log of the concentration of the hydroxyl ions in a solution i.e
pOH = -log₁₀{OH⁻]
Learn more:
calculating pH: brainly.com/question/12985875
pH scale: brainly.com/question/11063271
#learnwithBrainly
Answer:
![\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
Less than the concentration of Pb2+(aq) in the solution in part ( a )
Explanation:
From the question:
A)
We assume that s to be the solubility of PbI₂.
The equation of the reaction is given as :
PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹
[Pb²⁺] = s
Then [I⁻] = 2s
![K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} = 4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BPb%24%5E%7B2%2B%7D%24%5D%5BI%24%5E%7B-%7D%24%5D%7D%5E%7B2%7D%20%3D%20s%5Ctimes%20%282s%29%5E%7B2%7D%20%3D%20%204s%5E%7B3%7D%5C%5Cs%5E%7B3%7D%20%3D%20%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%5C%5C%5C%5Cs%20%3D%5Cmathbf%7B%20%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D%5C%5C%5C%5C%5Ctext%7BThe%20mathematical%20expressionthat%20can%20be%20used%20to%20determine%20the%20value%20of%20%20%7D%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
B)
The Concentration of Pb²⁺ in water is calculated as :
![\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
![\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7B7%2A10%5E%7B-9%7D%7D%7B4%7D%7D%7D)
![\mathbf{s} =\sqrt[3]{1.75*10^{-9}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%7D%20%3D%5Csqrt%5B3%5D%7B1.75%2A10%5E%7B-9%7D%7D)

The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI




The equilibrium constant:
![K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \ m/L](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5BPb%5E%7B2%2B%7D%7D%5D%5BI%5E-%5D%5E2%20%5C%5C%20%5C%5C%20K_%7Bsp%7D%20%3D%20s%2A%281.0%2A2s%29%5E2%20%3D7%2A1.0%5E%7B-9%7D%20%5C%5C%20%5C%5C%20s%20%3D%207%2A10%5E%7B-9%7D%20%5C%20%5C%20%20m%2FL)
It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.
The basis of finding the answer to this problem is to know the electronic configuration of Fluorine. That would be: <span>[He] 2s</span>²<span> 2p</span>⁵. The valence electrons, which are the outermost electrons of the atom, are the ones that participate in bonding. <em>Since the highest orbital for F is 2p, that means the highest energy occupied would be 2.</em>
Answer:
0.3023 M
Explanation:
Let Picric acid = 
So,
+
⇄
+ 
The ICE table can be given as:
+
⇄
+ 
Initial: 0.52 0 0
Change: - x + x + x
Equilibrium: 0.52 - x + x + x
Given that;
acid dissociation constant (
) = 0.42
![K_a = \frac{[H_3O^+][Picric^-]}{H_{picric}}](https://tex.z-dn.net/?f=K_a%20%3D%20%5Cfrac%7B%5BH_3O%5E%2B%5D%5BPicric%5E-%5D%7D%7BH_%7Bpicric%7D%7D)
![0.42 = \frac{[x][x]}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5Bx%5D%7D%7B0.52-x%7D%7D)
![0.42 = \frac{[x]^2}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5E2%7D%7B0.52-x%7D%7D)
0.42(0.52-x) = x²
0.2184 - 0.42x = x²
x² + 0.42x - 0.2184 = 0 -------------------- (quadratic equation)
Using the quadratic formula;
; ( where +/- represent ± )
= 
= 
=
OR 
=
OR 
=
OR 
= 0.30225 OR - 0.72225
So, we go by the +ve integer that says:
x = 0.30225
x = [
] = [
] = 0.3023 M
∴ the value of [H3O+] for an 0.52 M solution of picric acid = 0.3023 M (to 4 decimal places).