Answer:
Explanation:
<u>1) Data:</u>
a) Hypochlorous acid = HClO
b) [HClO} = 0.015
c) pH = 4.64
d) pKa = ?
<u>2) Strategy:</u>
With the pH calculate [H₃O⁺], then use the equilibrium equation to calculate the equilibrium constant, Ka, and finally calculate pKa from the definition.
<u>3) Solution:</u>
a) pH
b) Equilibrium equation: HClO (aq) ⇄ ClO⁻ (aq) + H₃O⁺ (aq)
c) Equilibrium constant: Ka = [ClO⁻] [H₃O⁺] / [HClO]
d) From the stoichiometry: [CLO⁻] = [H₃O⁺] = 2.29 × 10 ⁻⁵ M
e) By substitution: Ka = (2.29 × 10 ⁻⁵ M)² / 0.015M = 3.50 × 10⁻⁸ M
f) By definition: pKa = - log Ka = - log (3.50 × 10 ⁻⁸) = 7.46
Answer:
8.09x10⁻⁵M of Fe³⁺
Explanation:
Using Lambert-Beer law, the absorbance of a sample is proportional to its concentration.
In the problem, the Fe³⁺ is reacting with KSCN to produce Fe(SCN)₃ -The red complex-
The concentration of Fe³⁺ in the reference sample is:
4.80x10⁻⁴M Fe³⁺ × (5.0mL / 50.0mL) = 4.80x10⁻⁵M Fe³⁺
<em>Because reference sample was diluted from 5.0mL to 50.0mL.</em>
<em>That means a solution of 4.80x10⁻⁵M Fe³⁺ gives an absorbance of 0.512</em>
Now, as the sample of the lake gives an absorbance of 0.345, its concentration is:
0.345 × (4.80x10⁻⁵M Fe³⁺ / 0.512) = <em>3.23x10⁻⁵M. </em>
As the solution was diluted from 20.0mL to 50.0mL, the concentration of Fe³⁺ in Jordan lake is:
3.23x10⁻⁵M Fe³⁺ × (50.0mL / 20.0mL) = <em>8.09x10⁻⁵M of Fe³⁺</em>
Helium can be liquefy through a very
low temperature because of the weakness of attractions between the helium
atoms. In addition, helium is a noble gas that has a very weak interatomic London
dispersion forces. Thus, this element would remain liquid at atmospheric pressure
all the way to its liquefaction point going to absolute zero.
<span> </span>
Answer:
ΔH = - 5315 kJ.
Explanation:
The given chemical reaction is as follows -
2C₄H₁₀ (g) + 13 O₂ (g) → 8 CO₂ (g) + 10 H₂O (g) + 5315 kJ
In the above equation , the amount of energy i.e. 5315 kJ is released , i.e. it is in the product side , hence , the reaction is an example of an exothermic reaction .
Hence ,
The value of the change in enthalphy , i.e. , the enthalpy of product minus the enthalpy of the product .
Therefore ,
The value of the change in enthalphy = - ve .
Hence ,
ΔH = - 5315 kJ.