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andrew-mc [135]
1 year ago
8

identify A and B, isomers of molecular formula C3H4Cl2, from the given 1H NMR data: Compound A exhibits peaks at 1.75 (doublet,

3 H, J = 6.9 Hz) and 5.89 (quartet, 1 H, J = 6.9 Hz) ppm. Compound B exhibits peaks at 4.16 (singlet, 2 H), 5.42 (doublet, 1 H, J = 1.9 Hz), and 5.59 (doublet, 1 H, J = 1.9 Hz) ppm.

Chemistry
1 answer:
siniylev [52]1 year ago
3 0

Answer:

See explaination

Explanation:

please kindly see attachment for the step by step solution of the given problem.

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Determine whether each description applies to electrophilic aromatic substitution or nucleophilic aromatic substitution.
Alborosie

Answer:

a. electrophilic aromatic substitution

b. nucleophilic aromatic substitution

c. nucleophilic aromatic substitution

d. electrophilic aromatic substitution

e. nucleophilic aromatic substitution

f. electrophilic aromatic substitution

Explanation:

Electrophilic aromatic substitution is a type of chemical reaction where a hydrogen atom or a functional group that is attached to the aromatic ring is replaced by an electrophile. Electrophilic aromatic substitutions can be classified into five classes: 1-Halogenation: is the replacement of one or more hydrogen (H) atoms in an organic compound by a halogen such as, for example, bromine (bromination), chlorine (chlorination), etc; 2- Nitration: the replacement of H with a nitrate group (NO2); 3-Sulfonation: the replacement of H with a bisulfite (SO3H); 4-Friedel-CraftsAlkylation: the replacement of H with an alkyl group (R), and 5-Friedel-Crafts Acylation: the replacement of H with an acyl group (RCO). For example, the Benzene undergoes electrophilic substitution to produce a wide range of chemical compounds (chlorobenzene, nitrobenzene, benzene sulfonic acid, etc).

A nucleophilic aromatic substitution is a type of chemical reaction where an electron-rich nucleophile displaces a leaving group (for example, a halide on the aromatic ring). There are six types of nucleophilic substitution mechanisms: 1-the SNAr (addition-elimination) mechanism, whose name is due to the Hughes-Ingold symbol ''SN' and a unimolecular mechanism; 2-the SN1 reaction that produces diazonium salts 3-the benzyne mechanism that produce highly reactive species (including benzyne) derived from the aromatic ring by the replacement of two substituents; 4-the free radical SRN1 mechanism where a substituent on the aromatic ring is displaced by a nucleophile with the formation of intermediary free radical species; 5-the ANRORC (Addition of the Nucleophile, Ring Opening, and Ring Closure) mechanism, involved in reactions of metal amide nucleophiles and substituted pyrimidines; and 6-the Vicarious nucleophilic substitution, where a nucleophile displaces an H atom on the aromatic ring but without leaving groups (such as, for example, halogen substituents).

3 0
2 years ago
Estimate ΔG°rxn for the following reaction at 387 K. HCN (g) + 2 H2 (g) → CH3NH2 (g) ΔH° = −158.0 kJ; ΔS° = −219.9
Lina20 [59]

Answer:

ΔG°rxn = -72.9 kJ

Explanation:

Let's consider the following reaction.

HCN(g) + 2 H₂(g) → CH₃NH₂(g)

We can calculate the standard Gibbs free energy of the reaction (ΔG°rxn) using the following expression:

ΔG°rxn = ΔH° - T.ΔS°

where,

ΔH° is the standard enthalpy of the reaction

T is the absolute temperature

ΔS° is the standard entropy of the reaction

ΔG°rxn = -158.0 KJ - 387 K × (-219.9 × 10⁻³ J/K)

ΔG°rxn = -72.9 kJ

4 0
2 years ago
A 12.0 g sample of a metal is heated to 90.0 ◦C. It is then dropped into 25.0 g of water. The temperature of the water rises fro
Liula [17]

Answer:

The specific heat of the metal is 0.335 J/g°C

Explanation:

<u>Step 1:</u> Data given

Mass of the metal = 12.0 grams

Initial temperature of the metal = 90.0 °C

Mass of the water = 25.0 grams

Initial temperature of water = 22.5 °C

Final temperature of water (and metal) = 25.0 °C

The specific heat of water = 4.18 J/g°C

<u>Step 2:</u> Calculate the specific heat of the metal

Qgained  = -Qlost

Qwater = -Qmetal

Q= m*c*ΔT

m(metal) *c(metal)*ΔT(metal) = -m(water)*c(water)*ΔT(water)

⇒ mass of the metal = 12.0 grams

⇒ c(metal) = TO BE DETERMINED

⇒ ΔT(metal) = T2 - T1 = 25.0 - 90.0 °C = -65.0

⇒ mass of the water = 25.0 grams

⇒ c(water) = the specific heat of water = 4.18 J/g°C

⇒ ΔT(water) = T2 - T1 = 25.0 - 22.5 = 2.5°C

12.0 * c(metal) * -65.0 = -25.0 * 4.18 * 2.5

c(metal) = 0.335 J/g°C

The specific heat of the metal is 0.335 J/g°C

6 0
1 year ago
What fraction of the carbon dioxide exhaled by animals is generated by the reactions of the citric acid cycle
puteri [66]

Answer:

1/3

Explanation:

Pyruvate is produced by the glycolysis in cytoplasm. The oxidation of pyruvate takes place in mitochondrial matrix.  

Pyruvate is converted to acetyl-CoA in the reaction given below:

Pyruvate + NAD⁺ + CoA-SH ⇒ acetyl-CoA + NADH + CO₂

1 molecule of carbon dioxide is eliminated from 1 molecule of pyruvate.

Also,  

2 molecules of carbon dioxide is eliminated from 2 molecules of pyruvate (as glucose on glycolysis yields 2 molecules of pyruvate).

Also, acetyl-CoA further goes into the citric acid cycle and produces 2 molecules of carbon dioxide.

Thus pyruvate produces total 3 molecules of CO₂  and hence glucose produces 6 molecules of CO₂ (as glucose on glycolysis yields 2 molecules of pyruvate)

Thus,

<u>Fraction = 2/6 = 1/3</u>

4 0
2 years ago
The formula of a salt is XCl2. The X-ion in this salt has 26 electrons. The metal X is A) Fe B) V C) Pd D) Ni E) Zn
Sloan [31]

Answer:

whats the question

Explanation:

5 0
2 years ago
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