To solve this problem we will use the following equation:
w = (m of solute) / (m of solution)
w - percentage
It is necessary to mention here that mass of solution is a sum of the mass of solute and mass of water.
<span>w = mass CaCl2/(mass of water + mass of CaCl2)
</span>
mass of water = x
0.35 = 36 / (x + 36)
0.35 × (x + 36) = 36
0.35x + 12.6 = 36
0.35x = 23.4
x = 66.86 g of water is necessary
The molality of a solute is equal to the moles of solute per kg of solvent. We are given the mole fraction of I₂ in CH₂Cl₂ is <em>X</em> = 0.115. If we can an arbitrary sample of 1 mole of solution, we will have:
0.115 mol I₂
1 - 0.115 = 0.885 mol CH₂Cl₂
We need moles of solute, which we have, and must convert our moles of solvent to kg:
0.885 mol x 84.93 g/mol = 75.2 g CH₂Cl₂ x 1 kg/1000g = 0.0752 kg CH₂Cl₂
We can now calculate the molality:
m = 0.115 mol I₂/0.0752 kg CH₂Cl₂
m = 1.53 mol I₂/kg CH₂Cl₂
The molality of the iodine solution is 1.53.
In given data:
maximum absorption wavelength λ = 580 nm = 580 x 10⁻⁹ m
write the equation to find the crystal field splitting energy:
E = hC / λ
Here, E is the crystal field splitting energy, h = 6.63 x 10⁻³⁴ J.sec is Planck's constant and C = 3 x 10⁸ m/sec is speed of light.
substitute in the equation above:
E = (6.64 x 10⁻³⁴ x 3 x 10⁸) / (580 x 10⁻⁹) = 3.43 x 10⁻¹⁹J
This crystal field splitting energy is for 1 ion.
Number of atoms in one mole, NA = 6.023 x 10²³
to calculate the crystal field splitting energy for one mole:
E(total) = E x NA
= (3.43 x 10⁻¹⁹) x (6.023 x 10²³) = 206 kJ/ mole
The correct option is B.
Coal dust refers to the powered form of coal. Because of the high surface area of coal dust it is highly prone to dust explosion, which involves rapid combustion of fine particles that are suspended in the air; this usually occur in an enclosed place. Coal dust in an enclosed place is more explosive than coal dust that is blown outdoor in an open space because the coal dust in an enclosed place is more concentrated due to restricted space, thus it is more liable to explosion.
The Molecule of Sodium Formate along with Formal Charges (in blue) and lone pair electrons (in red) is attached below.
Sodium Formate is an ionic compound made up of a positive part (Sodium Ion) and a polyatomic anion (Formate).
Nomenclature:
In ionic compounds the positive part is named first. As sodium ion is the positive part hence, it is named first followed by the negative part i.e. formate.
Name of Formate:
Formate ion has been derived from formic acid ( the simplest carboxylic acid). When carboxylic acids looses the acidic proton of -COOH, they are converted into Carboxylate ions.
E.g.
HCOOH (formic acid) → HCOO⁻ (formate) + H⁺
H₃CCOOH (acetic acid) → H₃CCOO⁻ (acetate) + H⁺
Formal Charges:
Formal charges are calculated using following formula,
F.C = [# of Valence e⁻] - [e⁻ in lone pairs + 1/2 # of bonding electrons]
For Oxygen:
F.C = [6] - [6 + 2/2]
F.C = [6] - [6 + 1]
F.C = 6 - 7
F.C = -1
For Sodium:
F.C = [1] - [0 + 0/2]
F.C = [1] - [0]
F.C = 1 - 0
F.C = +1
