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Vaselesa [24]
2 years ago
11

A 0.56 M solution of AlCl₃ is determined to have a concentration of particles of 1.79 M. What is the van't Hoff factor for AlCl₃

?
Chemistry
1 answer:
Crank2 years ago
3 0

Answer:

Van't Hoff factor for AlCl₃ = 3 (Approx)

Explanation:

Given:

Number of observed particular = 1.79 M

Number of theoretical particular = 0.56 M

Find:

Van't Hoff factor for AlCl₃

Computation:

Van't Hoff factor for AlCl₃ = Number of observed particular / Number of theoretical particular

Van't Hoff factor for AlCl₃ = 1.79 M / 0.56 M

Van't Hoff factor for AlCl₃ = 3.19

Van't Hoff factor for AlCl₃ = 3 (Approx)

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Given the following data, determine the rate constant of the reaction 2NO(g) +Cl2(g) --> 2NOCl(g) Experiment [NO] (M) [Cl2] (
andrew-mc [135]

Answer:

k = 2.647 x 10-2 M-2 s-1

Explanation:

2NO(g) +Cl2(g) --> 2NOCl(g)

Experiment [NO] (M) [Cl2] (M) Rate (M/s)

1 0.0300 0.0100 3.4 x 10-4

2 0.0150 0.0100 8.5 x 10-5

3 0.0150 0.0400 3.4 x 10-4

Frrom experiments 1 and 3;

Reducing the concentration of NO by a factor of 2 decreases the rate of the reaction by a factor of 4. This means the reaction is second order with respect to NO.

From experiments 2 and 3:

Increasing the concentration of Cl2 by a factor of 4 increases the rate by a factor of 4. This means the reaction is first order with respect to Cl2

The rate equation is given as;

Rate = k [NO]² [Cl2]

From experiment 1;

k =  [NO]² [Cl2] / Rate

k = 0.0300² * 0.0100 / 3.4 x 10-4

k = 2.647 x 10-2 M-2 s-1

7 0
2 years ago
400 mL of hydrogen are collected over water at 18 C and a total pressure of 740 mm of mercury. (Vapor pressure of H2O at 18 C=15
MrRa [10]

Answer:

a)15.5 mmHg is the partial pressure of water vapor.

b) 724.5 mmHg is the partial pressure of hydrogen gas.

Explanation:

Total pressure of gases = T = P = 740 mmHg

Vapor pressure of the water = p_1=15.5 mmHg

Partial pressure of the hydrogen gas = p_2=?

Partial pressure of the water = p_1=15.5 mmHg

15.5 mmHg is the partial pressure of water vapor.

Using Dalton's law of partial pressure:

P=p_1+p_2

740 mmHg=15.5 mmHg+p_2

p_2=740 mmHg-15.5mmHg =724.5 mmHg

724.5 mmHg is the partial pressure of hydrogen gas.

6 0
2 years ago
In the manufacture of paper, logs are cut into small chips, which are stirred into an alkaline solution that dissolves several o
Kitty [74]

Answer:

The estimated feed rate of logs is 14.3 logs/min.

Explanation:

The product of the process is 2000 tons/day of dry wood pulp, of 85 wt% of cellulose. That represents (2000*0.85)=1700 tons/day of cellulose.

That cellulose has to be feed by the wood chips, which had 47 wt% of cellulose in its composition. That means you need (1700/0.47)=3617 tons/day of wood chips to provide all that cellulose.

Th entering flow is wood chips with 45 wt% of water. This solution has an specific gravity of 0.640.

To know the specific gravity of the wood chips we have to write a volume balance. We also know that Mw=0.45*M and Mc=0.55*M.

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The specific gravity of the wood chips is 0.494.

The average volume of a log is

V_l=(\pi*D^{2} /4)*L=(3.1416*\frac{8^{2}  \, in^{2} }{4} )*9ft*(\frac{12 in}{1ft})= 21714 in^{3}=12.57 ft^{3}

The weight of one log is

M=\rho*V=0.494*\rho_w*12.57  ft^{3}\\\\M=0.494*62.4\frac{lbm}{ft^{3} }*12.57ft^{3}\\\\M=387.5lbm

To provide 3617 ton/day of wood chips, we need

n=\frac{supply}{M_{log}}=\frac{3617 tons/day}{387.5 lbm}*\frac{2204lbm}{1ton}\\\\n=20573 logs/day=14.3 logs/min

The feed rate of logs is 14.3 logs/min.

7 0
2 years ago
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4 0
2 years ago
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5 0
2 years ago
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