Answer:
Here's what I get.
Explanation:
The frequency of a vibration depends on the strength of the bond (the force constant).
The stronger the bond, the more energy is needed for the vibration, so the frequency (f) and the wavenumber increase.
Acetophenone
Resonance interactions with the aromatic ring give the C=O bond in acetophenone a mix of single- and double-bond character, and the bond frequency = 1685 cm⁻¹.
p-Aminoacetophenone
The +R effect of the amino group increases the single-bond character of the C=O bond. The bond lengthens, so it becomes weaker.
The vibrational energy decreases, so wavenumber decreases to 1652 cm⁻¹.
p-Nitroacetophenone
The nitro group puts a partial positive charge on C-1. The -I effect withdraws electrons from the acetyl group.
As electron density moves toward C-1, the double bond character of the C=O group increases.
The bond length decreases, so the bond becomes stronger, and wavenumber increases to 1693 cm¹.
Answer:
The estimated feed rate of logs is 14.3 logs/min.
Explanation:
The product of the process is 2000 tons/day of dry wood pulp, of 85 wt% of cellulose. That represents (2000*0.85)=1700 tons/day of cellulose.
That cellulose has to be feed by the wood chips, which had 47 wt% of cellulose in its composition. That means you need (1700/0.47)=3617 tons/day of wood chips to provide all that cellulose.
Th entering flow is wood chips with 45 wt% of water. This solution has an specific gravity of 0.640.
To know the specific gravity of the wood chips we have to write a volume balance. We also know that Mw=0.45*M and Mc=0.55*M.
The specific gravity of the wood chips is 0.494.
The average volume of a log is
The weight of one log is
To provide 3617 ton/day of wood chips, we need
The feed rate of logs is 14.3 logs/min.
Mass = mass/molar mass of ch3ch2nh2
the molar mass of CH3CH2NH2 = 12 +(1x3)+12+(1 x2)+14+(1x2) =45 g/mol
moles is therefore = 1.50g /45g/mol = 0.033 moles
Explanation:
The observation of student was that thermometer reading changed from 27°C to 35°C which indicates that temperature of the beaker solution rose after reaction due to release of heat during reaction as a product.
Those chemical reactions which gives heat energy as a product into their surrounding are categorized as exothermic reactions. During the course of these reaction temperature of the surroundings also increased.
So, this means that reaction between silver nitrate and copper wire is an exothermic reaction.
Three ways that the student could speed up the reaction :
- By adding catalyst to the reaction.
- By decreasing the temperature.
- By increasing the concentration of silver nitarte solution.
Answer:
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Explanation:
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<u>1. Dissociation equation</u>
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Assuming 100% dissociation, the equation is:
- Ba(C₂H₃O₂)₂ → Ba²⁺ + 2C₂H₃O₂⁻
↑
acetate ions
<u>2. Molarity</u>
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Calculate the molarity, M, of the solution:
- n = mass in grams / molar mass
- n = 69.g / 255.415g/mol = 0.27015 mol
- M = 0.27015mol / 0.970liter = 0.27850 mol/liter ≈ 0.28M
<u>3. Acetate ions</u>
From the chemical equation, 1 mol of dissolved Ba(C₂H₃O₂)₂ produces 2 acetate ions in solution.
Thus, 0.28 mol/liter × 2 = 0.56 mol/liter = 0.56M ← answer
