Answer: The workdone W = 505J
Explanation:
Applying the pressure-volume relationship
W= - PΔV
Where negative sign indicates the power is being delivered to the surrounding
W = - 1.0atm * ( 5.88 - 0.9)L
= - 1.0atm * (4.98)
W = -4.98 atmL
Converting to Joules
1atmL = 101.325J
-4.98atmL = x joules.
Work done in J = -4.98 * 101.325
W= -505J
Therefore the workdone is -505J
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Answer:
0.3023 M
Explanation:
Let Picric acid = 
So,
+
⇄
+ 
The ICE table can be given as:
+
⇄
+ 
Initial: 0.52 0 0
Change: - x + x + x
Equilibrium: 0.52 - x + x + x
Given that;
acid dissociation constant (
) = 0.42
![K_a = \frac{[H_3O^+][Picric^-]}{H_{picric}}](https://tex.z-dn.net/?f=K_a%20%3D%20%5Cfrac%7B%5BH_3O%5E%2B%5D%5BPicric%5E-%5D%7D%7BH_%7Bpicric%7D%7D)
![0.42 = \frac{[x][x]}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5Bx%5D%7D%7B0.52-x%7D%7D)
![0.42 = \frac{[x]^2}{0.52-x}}](https://tex.z-dn.net/?f=0.42%20%3D%20%5Cfrac%7B%5Bx%5D%5E2%7D%7B0.52-x%7D%7D)
0.42(0.52-x) = x²
0.2184 - 0.42x = x²
x² + 0.42x - 0.2184 = 0 -------------------- (quadratic equation)
Using the quadratic formula;
; ( where +/- represent ± )
= 
= 
=
OR 
=
OR 
=
OR 
= 0.30225 OR - 0.72225
So, we go by the +ve integer that says:
x = 0.30225
x = [
] = [
] = 0.3023 M
∴ the value of [H3O+] for an 0.52 M solution of picric acid = 0.3023 M (to 4 decimal places).