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2 years ago

Write the quantum numbers of the last electron of Neptunium.

Chemistry

1 answer:

olganol [36]2 years ago

5 0

Answer:

Explanation:

quantum number of neptunium is

$L_{11/2}$

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Determine Z and V for steam at 250°C and 1800 kPa by the following: (a) The truncated virial equation [Eq. (3.38)] with the foll

makvit [3.9K]

Answer:

Explanation:

Given that:

the temperature $T_1$ = 250 °C= ( 250+ 273.15 ) K = 523.15 K

Pressure = 1800 kPa

The truncated viral equation is expressed as:

$\frac{PV}{RT} = 1 + \frac{B}{V} + \frac{C}{V^2}$

where; B = - $152.5 \ cm^3 /mol$ C = -5800 $cm^6/mol^2$

R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹

Plugging all our values; we have

$\frac{1800*V}{8.314*10^3*523.15} = 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

$4.138*10^{-4} \ V= 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

Multiplying through with V² ; we have

$4.138*10^4 \ V ^3 = V^2 - 152.5 V - 5800 = 0$

$4.138*10^4 \ V ^3 - V^2 + 152.5 V + 5800 = 0$

V = 2250.06 cm³ mol⁻¹

Z = $\frac{PV}{RT}$

Z = $\frac{1800*2250.06}{8.314*10^3*523.15}$

Z = 0.931

b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].

The generalized Pitzer correlation is :

$T_c = 647.1 \ K \\ \\ P_c = 22055 \ kPa \\ \\ \omega = 0.345$

$T__{\gamma}} = \frac{T}{T_c}$

$T__{\gamma}} = \frac{523.15}{647.1}$

$T__{\gamma}} = 0.808$

$P__{\gamma}} = \frac{P}{P_c}$

$P__{\gamma}} = \frac{1800}{22055}$

$P__{\gamma}} = 0.0816$

$B_o = 0.083 - \frac{0.422}{T__{\gamma}}^{1.6}}$

$B_o = 0.083 - \frac{0.422}{0.808^{1.6}}$

$B_o = 0.51$

$B_1 = 0.139 - \frac{0.172}{T__{\gamma}}^{ \ 4.2}}$

$B_1 = -0.282$

The compressibility is calculated as:

$Z = 1+ (B_o + \omega B_1 ) \frac{P__{\gamma}}{T__{\gamma}}$

$Z = 1+ (-0.51 +(0.345* - 0.282) ) \frac{0.0816}{0.808}$

Z = 0.9386

$V= \frac{ZRT}{P}$

$V= \frac{0.9386*8.314*10^3*523.15}{1800}$

V = 2268.01 cm³ mol⁻¹

c) From the steam tables (App. E).

At $T_1 = 523.15 \ K \ and \ P = 1800 \ k Pa$

V = 0.1249 m³/ kg

M (molecular weight) = 18.015 gm/mol

V = 0.1249 × 10³ × 18.015

V = 2250.07 cm³/mol⁻¹

R = 729.77 J/kg.K

Z = $\frac{PV}{RT}$

Z = $\frac{1800*10^3 *0.1249}{729.77*523.15}$

Z = 0.588

3 0

2 years ago

The number of p atoms in 1.0 g of ba3(po4)2 is:

marta [7]

First, we determine the number of moles of barium phosphate. This is done using:

Moles = mass / Mr
Moles = 1 / 602
Moles = 0.002

Now, we see from the formula of the compound that each mole of barium phosphate has 2 moles of phosphorus (P). Therefore, the moles of phosphorus are:
0.002 * 2 = 0.004

The number of particles in one mole of substance is 6.02 x 10²³. The number of phosphorus atoms will be:
0.004 * 6.02 x 10²³

2.41 x 10²¹ atoms of phosphorus are present

3 0

2 years ago

A mysterious white powder could be powdered sugar (C12H22O11), cocaine (C17H21NO4), codeine (C18H21NO3), norfenefrine (C8H11NO2)

rodikova [14]

Norfenefrine (C₈H₁₁NO₂).

<h3>Further explanation</h3>

We will solve a case related to one of the colligative properties, namely freezing point depression.

The freezing point of the solution is the temperature at which the solution begins to freeze. The difference between the freezing point of the solvent and the freezing point of the solution is called freezing point depression.

$\boxed{ \ \Delta T_f = T_f(solvent) - T_f(solution) \ } \rightarrow \boxed{ \ \Delta T_f = K_f \times molality \ }$

<u>Given:</u>

A mysterious white powder could be,

powdered sugar (C₁₂H₂₂O₁₁) with a molar mass of 342.30 g/moles,
cocaine (C₁₇H₂₁NO₄) with a molar mass of 303.35 g/moles,
codeine (C₁₈H₂₁NO₃) with a molar mass of 299.36 g/moles,
norfenefrine (C₈H₁₁NO₂) with a molar mass of 153.18 g/moles, or
fructose (C₆H₁₂O₆) with a molar mass of 180.16 g/moles.

When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

The solute = the powder
The solvent = ethanol
The freezing point of the solvent = −114.6°C
The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

Mass of solute = 82 mg = 0.082 g
Mass of solvent = density x volume, i.e., $\boxed{ \ 0.789 \ \frac{g}{cm^3} \times 1.50 \ cm^3 = 1.1835 \ g = 0.00118 \ kg \ }$

We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

$\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }$

Now we combine it with the formula of freezing point depression.

$\boxed{ \ \Delta T_f = K_f \times \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }$

It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

$\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }$

$\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }$

$\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }$

We get $\boxed{ \ Mr = 153.65 \ }$

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>

The molality and mole fraction of water brainly.com/question/10861444
About the mass and density of ethylene glycol as an antifreeze brainly.com/question/4053884
About the solution as a homogeneous mixture brainly.com/question/637791

Keywords: a mysterious white powder, sugar, cocaine, codeine, norfenefrine, fructose, the solute, the solvent, dissolved, ethanol, normal freezing point, the freezing point depression, the identity

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Write the quantum numbers of the last electron of Neptunium.​

Write the quantum numbers of the last electron of Neptunium.