Answer:
Check explanation
Explanation:
During the Electron Transport System occur in the mitochondrial membrane, oxygen in this reaction is been reduced to water and ATPs are being produced.
The quinone form or the oxidized form of Flavin Adenine Dinucleotide(FAD) is the FADH2. While Nicotinamide adenine dinucleotide is the acronym for NADH. NADH is a good donating substance/agent.
It has been observed that FADH2 produce two(2) ATP while NADH produces three(3) ATP. The reason for this observation is that the production of electron in the FADH2 is at the lower enegy level. Because of this it can not transfer its electron to the first complex .
While;
NADH is at the higher energy level and it can directly transfer its electron to the first complex.
Answer:
The correct answer is option C, that is, ΔS and ΔSsurr for the process H2O (s) ⇒ H2O(l) are equal in magnitude and opposite in sign.
Explanation:
The temperature at which solid state of water get transformed into liquid state is termed as the melting point of 0 °C. It can be shown by the reaction:
H2O (s) ⇒ H2O (l)
The degree of randomness of a molecule is known as entropy. With the transformation of ice into liquid state, there is an increase in randomness. Thus, the value of entropy becomes positive as shown:
Entropy change (ΔSsys) = ΔSproduct - ΔSreactant
= (69.9 - 47.89) J mol/K
= 22.0 J mol/K
Therefore, the value of entropy change is positive.
Now the value of entropy for surrounding ΔSsurr will be,
ΔSsurr = -ΔHfusion/T
= -6012 j/mol/273
= -22.0 J/molK
Hence, the value of ΔSsurr and ΔSsys exhibit same magnitude with opposite sign.
The equilibrium constant is 0.0022.
Explanation:
The values given in the problem is
ΔG° = 1.22 ×10⁵ J/mol
T = 2400 K.
R = 8.314 J mol⁻¹ K⁻¹
The Gibbs free energy should be minimum for a spontaneous reaction and equilibrium state of any reaction is spontaneous reaction. So on simplification, the thermodynamic properties of the equilibrium constant can be obtained as related to Gibbs free energy change at constant temperature.
The relation between Gibbs free energy change with equilibrium constant is ΔG° = -RT ln K
So, here K is the equilibrium constant. Now, substitute all the given values in the corresponding parameters of the above equation.
We get,
So, the equilibrium constant is 0.0022.
N₀ is the number of C-14 atoms per kg of carbon in the original sample at time = Os when its carbon was of the same kind as that present in the atmosphere today. After time ts, due to radioactive decay, the number of C-14 atoms per kg of carbon is the same sample which has decreased to N. λ is the radioactive decay constant.
Therefore N = N₀e-λt which is the radioactive decay equation,
N₀/N = eλt In (N₀.N= λt. This is the equation 1
The mass of carbon which is present in the sample os mc kg. So the sample has a radioactivity of A/mc decay is/kg. r is the mass of C-14 in original sample at t= 0 per total mass of carbon in a sample which is equal to [(total number of C-14 atoms in the sample at t m=m 0) × ma]/ total mass of carbon in the sample.
Now that the total number of C-14 atoms in the sample at t= 0/ total mass of carbon in sample = N₀ then r = N₀×ma
So N₀ = r/ma. this equation 2.
The activity of the radioactive substance is directly proportional to the number of atoms present at the time.
Activity = A number of decays/ sec = dN/dt = λ(number of atoms of C-14 present at time t) =
λ₁(N×mc). By rearranging we get N = A/(λmc) this is equation 3.
By plugging in equation 2 and 3 and solve t to get
t = 1/λ In (rλmc/m₀A).
<span>The angle is less than that of a tetrahedral shape because of the lone pairs from oxygen. Using VESPR theory would show that the lone pairs from oxygen would interfere with the electron shells of the two hydrogen molecules.</span>
