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hammer [34]
1 year ago
4

A 6.00 g sample of an optically pure compound was dissolved in 40.0 mL of CCl4. The observed rotation was +3.30 °, measured in a

10.0 cm (1.00 dm) polarimeter tube.
Chemistry
1 answer:
sattari [20]1 year ago
8 0

The question is incomplete, the complete question is:

If a 6.00 g sample of an optically pure compound was dissolved in 40.0 mL of CCl_4 and the observed rotation was +3.30°, measured in a 10.0 cm (1.00 dm) polarimeter tube, how would one determine the specific rotation of the pure compound?

<u>Answer: </u>The specific rotation of the pure compound is +22^o

<u>Explanation:</u>

To calculate the specific rotation of a pure compound, we use the equation:

[\alpha]=\frac{\alpha_{\text{observed}}}{C\times l\text{( in dm)}}

where,

[\alpha] = specific rotation of a pure compound

\alpha_{\text{observed}} = observed rotation of the compound = [ex]+3.30^o[/tex]

C = concentration in g/mL = 6.00 g/40 mL = 0.15 g/mL

l = path length = 1.00 dm

Putting values in above equation, we get:

[\alpha]=\frac{+3.30^o}{0.15\times 1.0}

[\alpha]=+22^o

Hence, the specific rotation of the pure compound is +22^o

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When the reaction CO2(g) + H2(g) ⇄ H2O(g) + CO(g) is at equilibrium at 1800◦C, the equilibrium concentrations are found to be [C
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Answer:

The new molar concentration of CO at equilibrium will be  :[CO]=1.16 M.

Explanation:

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Equilibrium constant of the reaction :

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K = 4

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Concentration at eq'm:

0.24 M          0.24 M                 0.48 M            0.48 M

After addition of 0.34 moles per liter of CO_2 and H_2 are added.

(0.24+0.34) M    (0.24+0.34) M  (0.48+x)M         (0.48+x)M

Equilibrium constant of the reaction after addition of more carbon dioxide and water:

K=4=\frac{(0.48+x)M\times (0.48+x)M}{(0.24+0.34)\times (0.24+0.34) M}

4=\frac{(0.48+x)^2}{(0.24+0.34)^2}

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The new molar concentration of CO at equilibrium will be:

[CO]= (0.48+x)M = (0.48+0.68 )M = 1.16 M

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As energy is absorbed as a photon. Hence, frequency will be calculated will be as follows.

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And, according to De-Broglie equation \lambda = \frac{h}{p}

as,        p = m \times \nu

So,          \lambda = \frac{h}{m \times \nu}

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So,           m \times \nu^{2} = \frac{12.96 \times 10^{-52}}{m}

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Thus, we can conclude that kinetic energy acquired by the electron in hydrogen atom is 7.1 \times 10^{-22} J.

4 0
2 years ago
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