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Art [367]
2 years ago
6

When 4.41g of phosphoric acid (H3PO4) react with 9.25g of barium hydroxide, water and insoluble barium phosphate form. [T/I-7] a

. Write and balance the chemical equation.
Chemistry
1 answer:
AnnZ [28]2 years ago
3 0

Answer:

2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + 6 H₂O(l)

Explanation:

Let's consider the unbalanced equation that occurs when phosphoric acid reacts with barium hydroxide to form water and barium phosphate. This is a neutralization reaction.

H₃PO₄(aq) + Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + H₂O(l)

We will balance it using the trial and error method.

First, we will balance Ba atoms by multiplying Ba(OH)₂ by 3 and P atoms by multiplying H₃PO₄ by 2.

2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + H₂O(l)

Finally, we will get the balanced equation by multiplying H₂O by 6.

2 H₃PO₄(aq) + 3 Ba(OH)₂(aq) ⇒ Ba₃(PO₄)₂(s) + 6 H₂O(l)

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<u>Answer:</u> The correct answer is 3Ag^+(aq.)+Cr(s)\rightarrow 3Ag(s)+Cr^{3+}(aq.);E^o_{cell}=+1.53V

<u>Explanation:</u>

We are given:

Cr^{3+}(aq.)+3e^-\rightarrow Cr(s);E^o=-0.73V\\\\Ag^+(aq.)+e^-\rightarrow Ag(s);E^o=+0.80V

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction. Here, silver will always undergo reduction reaction will get reduced.

Chromium will undergo oxidation reaction and will get oxidized.

The half reactions for the above cell is:

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Reduction half reaction: Ag^{+}+e^-\rightarrow Ag(s);E^o_{Ag^{+}/Ag}=0.80V       ( × 3)

Net equation:  3Ag^+(aq.)+Cr(s)\rightarrow 3Ag(s)+Cr^{3+}(aq.)

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To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

E^o_{cell}=0.80-(-0.73)=1.53V

Hence, the correct answer is 3Ag^+(aq.)+Cr(s)\rightarrow 3Ag(s)+Cr^{3+}(aq.);E^o_{cell}=+1.53V

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2 years ago
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