Answer:
k = 1.3 x 10⁻³ s⁻¹
Explanation:
For a first order reaction the integrated rate law is
Ln [A]t/[A]₀ = - kt
where [A] are the concentrations of acetaldehyde in this case, t is the time and k is the rate constant.
We are given the half life for the concentration of acetaldehyde to fall to one half its original value, thus
Ln [A]t/[A]₀ = Ln 1/2[A]₀/[A]₀= Ln 1/2 = - kt
- 0.693 = - k(530s) ⇒ k = 1.3 x 10⁻³ s⁻¹
Answer : The normality of the solution is, 30.006 N
Explanation :
Normality : It is defined as the number of gram equivalent of solute present in one liter of the solution.
Mathematical expression of normality is:

or,

First we have to calculate the equivalent weight of solute.
Molar mass of solute
= 94.97 g/mole

Now we have to calculate the normality of solution.

Therefore, the normality of the solution is, 30.006 N
solution:
Weight of caffeine is W = 0.170 gm.
Volume of water is V= 10 ml
Volume of methylene chloride which extracted caffeine is v= 5ml
No of portions n=3
Distribution co-efficient= 4.6
Total amount of caffeine that can be unextracted is given by
![w_{n}=w\times[\frac{k_{Dx}v}{k_{Dx}v+v}]^n\\w_{3}=0.170[\frac{4.6\times10}{(4.6\times10+5)}]^3\\=0.170[\frac{46}{46+5}]^3\\=0.170[\frac{46}{51}]^3\\=0.170[\frac{97336}{132651}]\\=0.170\times0.734=0.125gms](https://tex.z-dn.net/?f=w_%7Bn%7D%3Dw%5Ctimes%5B%5Cfrac%7Bk_%7BDx%7Dv%7D%7Bk_%7BDx%7Dv%2Bv%7D%5D%5En%5C%5C%3C%2Fp%3E%3Cp%3Ew_%7B3%7D%3D0.170%5B%5Cfrac%7B4.6%5Ctimes10%7D%7B%284.6%5Ctimes10%2B5%29%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B46%2B5%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B46%7D%7B51%7D%5D%5E3%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5B%5Cfrac%7B97336%7D%7B132651%7D%5D%5C%5C%3C%2Fp%3E%3Cp%3E%3D0.170%5Ctimes0.734%3D0.125gms)
amount of caffeine un extracted is 0.125gms
amount of caffeine extracted=0.170-0.125
=0.045 gms
Explanation:
A polymer forms because the hydrocarbon joins with itself in a polymerization reaction.
<span>This is an example of a substance changing state, a physical change, the molecules are changed, but the atoms themselves do not change, just their arrangement, and the mass of the molecules is the same. Therefor energy is absorbed by the molecules, as energy is required to change the state or physicality of a molecule structure.Hope this helps. Let me know if you need additional help!</span>