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marishachu [46]
2 years ago
7

A chemist mixes 500 g of lead at 500°c with 1,200 g of water at 20°c. she then mixes 500 g of copper at 500°c with 1,200 g of wa

ter at 20°c. the specific heat capacity of lead is 0.1276 j/g°c and the specific heat capacity of copper is 0.3845 j/g°c. what will be true about the final temperatures of the two systems?
Chemistry
1 answer:
Artemon [7]2 years ago
8 0
The final temperature of the lead-water system will be lower than the final temperature of the copper-water system.
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Phosphorous acid, h3po3(aq), is a diprotic oxyacid that is an important compound in industry and agriculture. calculate the ph f
Varvara68 [4.7K]

Answer:

Explanation:

(a)

Before the addition of KOH :-

Given pKa1 of H3PO3 = 1.30

we know , pKa1 = - log10Ka1

Ka1 = 10-pKa1

Ka1 = 10-1.30

Ka1 = 0.0501

similarly pKa2 = 6.70 ,therefore Ka2 = 1.99 x 10-7

because Ka1 >> Ka2 , therefore pH of diprotic acid i.e H3PO3 can be calculated from first dissociation only .

ICE table is :-

H3PO3 (aq) <-------------> H+ (aq) + H2PO3-(aq)

I 2.4 M 0 M 0 M

C - x + x + x

E (2.4 - x )M x M x M

x = degree of dissociation

Now expression of Ka1 is :

Ka1 = [ H+ ] [ H2PO3-] / [ H3PO3]

0.0501 = x2 / 2.4 - x

on solving for x by using quadratic formula , we have

x = 0.32

Now [ H+ ] = [ H2PO3-] = 0.32 M

pH = - log [H+]

pH = - log 0.32

pH = - ( - 0.495)

pH = 0.495

Hence pH before the addition of KOH = 0.495

(b)

After the addition of 25.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.025 L = 0.06 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

Now 0.06 moles of KOH is equal to the half of the moles required for the first equivalent point . therefore pH at this point is equal to pKa1 .

Hence pH = 1.30 M

(c)

After the addition of 50.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.050 L = 0.12 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

because Number of moles of H3PO4 = Number of moles of KOH

therefore , this point is the first equivalence point

and pH = pKa1 + pKa2 / 2

pH = 1.30 + 6.70 / 2

pH = 4.00

Hence pH = 4.00

(d)

After the addition of 75.0 mL of 2.4 M KOH :-

Number of moles of KOH = 2.4 M x 0.075 L = 0.18 mol

Number of moles of H3PO3 = 2.4 M x 0.050 L = 0.12 mol

This is the half way of the second equivalence point , therefore pH is equal to pKa2 .

Hence pH = 6.70

5 0
2 years ago
If an equal number of moles of reactants are used, do the following equilibrium mixtures contain primarily reactants or products
puteri [66]

<u>Answer:</u>

<u>For a:</u> The equilibrium mixture contains primarily reactants.

<u>For b:</u> The equilibrium mixture contains primarily products.

<u>Explanation:</u>

There are 3 conditions:

  • When K_{eq}>1; the reaction is product favored.
  • When K_{eq}; the reaction is reactant favored.
  • When K_{e}=1; the reaction is in equilibrium.

For the given chemical reactions:

  • <u>For a:</u>

The chemical equation follows:

HCN(aq.)+H_2O(l)\rightleftharpoons CN^-(aq.)+H_3O^+(aq.);K_{eq}=6.2\times 10^{-10}

The expression of K_{eq} for above reaction follows:

K_{eq}=\frac{[CN^-][H_3O^+]}{[HCN][H_2O]}=6.2\times 10^{-10}

As, K_{eq}, the reaction will be favored on the reactant side.

Hence, the equilibrium mixture contains primarily reactants.

  • <u>For b:</u>

The chemical equation follows:

H_2(g)+Cl_2(g)\rightleftharpoons 2HCl(g);K_{eq}=2.51\times 10^{4}

The expression of K_{eq} for above reaction follows:

K_{eq}=\frac{[HCl]^2}{[H_2][Cl_2]}=2.51\times 10^{4}

As, K_{eq}>1, the reaction will be favored on the product side.

Hence, the equilibrium mixture contains primarily products.

4 0
2 years ago
If the concentration of a saturated solution at 0∘C is 12.5 gCuSO4/100 g soln, what mass of CuSO4⋅5H2O would be obtained? [Hint:
Andrew [12]

Answer:

Mass of CuSO4.H2O obtained: m_{total}=19.52 g

Explanation:

The molecular weight of the salt is: M=159.5 g/mol

<u>In the solution</u>: 12.5 g of CuSO4

In moles: n=\frac{12.5 g}{159.5 g/mol}=0.078 mol

<u>Mass of wate</u>r:

5 moles of water per mol of salt: m=\frac{5mol}{1mol}*0.078mol*\frac{18g}{mol}=7.02 g

Mass of CuSO4.H2O obtained: m_{total}=12.5 g + 7.02 g=19.52 g

7 0
2 years ago
Red blood cells are placed in a solution and neither hemolysis nor crenation occurs. therefore the solution is
Len [333]

The answer is isotonic solution. These are solutions where the solute concentration in the solution and inside the cells are levelled and consequently water flows consistently. When red blood cells are positioned in an isotonic solution the cells would always stay the same.

3 0
2 years ago
How many valance are transferred from the nitrogen atom to potassium in the formation of the compound potassium nitride?
never [62]
3 valence electrons are transferred in the formation of the compound potassium nitride because nitrogen needs 3 valence electron to become stable, or to have the electron configuration of noble Gases. 
5 0
2 years ago
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